{"id":{"repo_id":"lethbridge","oai_identifier":"oai:opus.uleth.ca:10133/191"},"canonical_url":"https://search.dev.ndltd.org/etd/lethbridge/oai:opus.uleth.ca:10133/191","repository":{"repo_id":"lethbridge","name":"University of Lethbridge","base_url":"https://opus.uleth.ca/server/oai/request"},"display":{"title":"The monophosphaamidine functional group","abstract":"The synthesis and characterization of two new bulky N,P-monophosphaamidines (also known as C-aminophosphaalkenes) are described. These phosphorus analogues to amidines are shown to exhibit isomerism and tautomerism in solution that is characteristic tothe amidine functional group. In addition, the nature of the P=C-N system is examined using DFT techniques. Metal complexes of the title compounds with Group 6 metal carbonyls (L-M(CO)5, M=Cr,Mo,W) are also described. A new primary phosphane is reported that contains the sterically bulky, 2,6-diisoropylphenyl (Dip) group, along with mono and disilylated derivatives. 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Faculty of Arts and Science"],"institution":"Lethbridge, Alta. : University of Lethbridge, Faculty of Arts and Science, 2002","degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":[],"advisors":["Boeré, René T."],"committee_chairs":[],"committee_members":[],"year":2002,"date_issued":"2002","date_published":"2002","updated_at":"2026-08-21T16:45:58Z","subjects":["Phosphorus compounds","Amidines","Dissertations, Academic"],"languages":["en_US"],"rights":[],"rights_urls":[],"identifier_entries":[{"key":"dc:identifier","label":"Identifier","values":["hdl:10133/191"],"render_values":[{"text":"hdl:10133/191","href":null,"code":true}]}]},"links":{"outbound_url":"https://hdl.handle.net/10133/191","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"source_record":{"url":"https://opus.uleth.ca/server/oai/request?verb=GetRecord&metadataPrefix=dim&identifier=oai%3Aopus.uleth.ca%3A10133%2F191","prefix":"dim"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.supervisor","label":"Supervisor","values":["Boeré, René T."]},{"key":"dc:creator","label":"Author","values":["Masuda, Jason D.","University of Lethbridge. 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These phosphorus analogues to amidines are shown to exhibit isomerism and tautomerism in solution that is characteristic tothe amidine functional group. In addition, the nature of the P=C-N system is examined using DFT techniques. Metal complexes of the title compounds with Group 6 metal carbonyls (L-M(CO)5, M=Cr,Mo,W) are also described. A new primary phosphane is reported that contains the sterically bulky, 2,6-diisoropylphenyl (Dip) group, along with mono and disilylated derivatives. Also included is the synthesis and characterization of a new bulky N,N',P-monophosphaguanidine."]},{"key":"dc:description.other","label":"Dc Description Other","values":["The synthesis and characterization of two new bulky N,P-monophosphaamidines (also known as C-aminophosphaalkenes) are described. These phosphorus analogues to amidines are shown to exhibit isomerism and tautomerism in solution that is characteristic tothe amidine functional group. In addition, the nature of the P=C-N system is examined using DFT techniques. Metal complexes of the title compounds with Group 6 metal carbonyls (L-M(CO)5, M=Cr,Mo,W) are also described. A new primary phosphane is reported that contains the sterically bulky, 2,6-diisoropylphenyl (Dip) group, along with mono and disilylated derivatives. Also included is the synthesis and characterization of a new bulky N,N',P-monophosphaguanidine."]},{"key":"dc:title","label":"Title","values":["The monophosphaamidine functional group"]}]}],"canonical_facts":{"dc:contributor.supervisor":["Boeré, René T."],"dc:creator":["Masuda, Jason D.","University of Lethbridge. 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Also included is the synthesis and characterization of a new bulky N,N',P-monophosphaguanidine."],"dc:description.other":["The synthesis and characterization of two new bulky N,P-monophosphaamidines (also known as C-aminophosphaalkenes) are described. These phosphorus analogues to amidines are shown to exhibit isomerism and tautomerism in solution that is characteristic tothe amidine functional group. In addition, the nature of the P=C-N system is examined using DFT techniques. Metal complexes of the title compounds with Group 6 metal carbonyls (L-M(CO)5, M=Cr,Mo,W) are also described. A new primary phosphane is reported that contains the sterically bulky, 2,6-diisoropylphenyl (Dip) group, along with mono and disilylated derivatives. Also included is the synthesis and characterization of a new bulky N,N',P-monophosphaguanidine."],"dc:identifier":["hdl:10133/191"],"dc:identifier.uri":["https://hdl.handle.net/10133/191"],"dc:language.iso":["en_US"],"dc:publisher":["Lethbridge, Alta. : University of Lethbridge, Faculty of Arts and Science, 2002"],"dc:publisher.department":["Department of Chemistry and Biochemistry"],"dc:subject":["Phosphorus compounds","Amidines","Dissertations, Academic"],"dc:title":["The monophosphaamidine functional group"],"dc:type":["Thesis"]},"updated_at":"2026-08-21T16:45:58Z"}