Study of Si(Al)CN functionalized carbon nanotube composite as a high temperature thermal absorber coating material

Carbon nanotubes (CNT) and polymer-derived ceramics (PDC) have gained considerable research attention due to their unique structure and physical properties. Carbon nanotubes are known for their exceptional mechanical (Young’s modulus= 1 TPa) and thermal properties (thermal conductivity = 4000 W/m.K). However, CNTs tend to lose their unique -sp2 carbon structure and cylindrical geometry at temperatures close 400°C in air. PDC, which are obtained by the controlled degradation of certain organosilicon polymers however exhibit high temperature stability (upto approx. 1400 °C). To this end, a hybrid composite material consisting of PDC functionalized CNT is of interest as it can combine the unique physical properties of the two materials for applications requiring operation under harsh conditions. Here, we report synthesis and chemical characterization of an Al-modified polysilazane polymer, which was later utilized to functionalize the outer surfaces of four commercially available CNTs. This polymer-CNT composite upon heating in nitrogen environment resulted in Si(Al)CN-CNT ceramic composite. The composite was characterized using a variety of spectroscopic methods such Raman, FTIR and electron microscopy. The thermal stability of the ceramic composite was studied by use of Thermogravimetric analysis (TGA) that showed an improvement in the thermal stability compared to bare nanotubes. Further, we also demonstrate that a stable dispersion of the composite in organic solvents such as toluene can be spray coated on a variety of substrates such as copper disks and foils. Such coatings have application in high energy laser power meters. This research opens new avenues for future applications of this novel material as coatings on surfaces that require both good thermal properties and protection against degradation in high temperature environments. We also suggest the future use of this material as an electrode material in high electrochemical capacity rechargeable batteries.

Grantor dc:publisher

Kansas State University

Year dc:date.issued

2013

Author dc:creator

• Asok, Deepu

• Polymer derived ceramics
• Carbon nanotubes
• Composite
• Coating

Statement dc:rights

• © the author. This Item is protected by copyright and/or related rights. You are free to use this Item in any way that is permitted by the copyright and related rights legislation that applies to your use. For other uses you need to obtain permission from the rights-holder(s).

Licence dc:rights.uri

• http://rightsstatements.org/vocab/InC/1.0/

Language dc:language.iso

en_US

Handle dc:identifier.uri

http://hdl.handle.net/2097/16876

OAI record oai:identifier

https://krex.k-state.edu/server/oai/request?verb=GetRecord&metadataPrefix=dim&identifier=oai%3Akrex.k-state.edu%3A2097%2F16876