ΜΕΛΕΤΗ ΦΩΤΟΧΗΜΙΚΩΝ ΑΝΤΙΔΡΑΣΕΩΝ 1-(Ν-1,2,3-ΤΡΙΑΖΟΛΥΛΟ)-ΙΜΙΔΙΩΝ

THE PHOTOCHEMICAL BEHAVIOUR OF THE 1-(N-1,2,3-TRIAZOLYL)-IMIDES WAS EXAMINED UNDER VARIOUS IRRADIATION CONDITIONS. THE 1-(N,N-BIS -BENZOYLAMINO)-4,5- DISUBSTITUTED-1,2,3-TRIAZIDES WHEN IRRIDATED THROUGH A PYREX FILTER UNDERWENT EITHER ANINTRAMOLECULAR OR AN INTERMOLECULAR HYDROGEN ATOM ABSTRACTION, FOLLOWED BY A B- CLEAVAGE OF THE WEAK N-N BOND, WHICH LED TO THE FORMATION OF THE 1(2)H-1,2,3-TRIAZOLES AND DIBENZAMIDE. IRRADIATION OF THE 1- (N,1,2,3-TRIAZOLYL)-IMIDES THROUGH A QUARTZ FILTED LED TO THE SAME PRODUCTS, AS PREVIOUSLY MENTIONED, VIA A Π*-ASSISTED B- CLEAVAGE OF THE N-N BOND. THE TRIAZOLES WERE ALSO IRRADIATED IN THE PRESENCE OF TRIETHYLAMINE AND THE SAME PRODUCTS WERE OBTAINED, ALBEIT VIA A SPONTANEOUSLY PROCEEDINGS, ELECTRON TRANSFER MECHANISM.

Grantor dc:publisher

Αριστοτέλειο Πανεπιστήμιο Θεσσαλονίκης (ΑΠΘ)

Year dc:date

1990

Authors dc:creator

• Καλαμπόκης, Ηλίας
• Kalambokis, Elias

• 1,2,3,-TRIAZOLYL RADICAL
• 1,2,3-TRIAZOLES
• 1,2,3-ΤΡΙΑΖΟΛΙΑ
• 1,2,3-ΤΡΙΑΖΟΛΥΛΟ ΡΙΖΑ
• 1-(N-1,2,3-TRIAZOLYL)-IMIDES
• 1-(Ν-1,2,3-ΤΡΙΑΖΟΛΥΛΟ)-ΙΜΙΔΙΑ
• B-CLEAVAGE
• Irradiation
• PHOTOCHEMICAL BEHAVIOUR
• PHOTOCHEMICAL REACTIONS
• Ακτινοβόληση
• Β-ΣΧΑΣΗ
• ΦΩΤΟΧΗΜΙΚΗ ΣΥΜΠΕΡΙΦΟΡΑ
• Φυσικές Επιστήμες
• Natural Sciences
• Χημεία
• Chemical Sciences

Language dc:language

gre

Identifier

10.12681/eadd/1294

OAI identifier oai:identifier

oai:10442/1294