{"id":{"repo_id":"greece","oai_identifier":"oai:10442/1254"},"canonical_url":"https://search.dev.ndltd.org/etd/greece/oai:10442/1254","repository":{"repo_id":"greece","name":"Greek National Archive of PhD Theses","base_url":"https://phdtheses.ekt.gr/eadd_oai/request"},"display":{"title":"ΦΑΣΜΑΤΟΣΚΟΠΙΚΗ ΜΕΛΕΤΗ ΑΕΡΙΩΝ ΣΥΜΠΛΟΚΩΝ ΣΕ ΥΨΗΛΕΣ ΘΕΡΜΟΚΡΑΣΙΕΣ ΣΕ ΣΥΣΤΗΜΑΤΑ ΧΛΩΡΙΟΥΧΩΝ ΑΛΑΤΩΝ ΤΩΝ ΣΙΔΗΡΟΥ, ΧΡΥΣΟΥ ΚΑΙ ΑΛΟΥΜΙΝΙΟΥ","abstract":"RAMAN SPECTROSCOPY AND UV-VIS ABSORPTION SPECTROPHOTOMETRY HAVE BEEN USED IN ORDER TO STUDY TWO COLORED VAPORS SYSTEMS, THOSE OF IRON (III) CHLORIDE-ALUMINUM CHLORIDE AND GOLD (III) CHLORIDE- ALUMINUM CHLORIDE. IN BOTH SYSTEMS, COMPLEX MOLECULES ARE FORMED IN THE VAPOR PHASE. THE TECHNIC OF HIGH TEMPERATURE ROTATING RAMAN CELL WAS DEVELOPED AND USED IN ORDER TO BE ABLE TO OBTAIN RAMAN SPECTRAFROM THE COLORED VAPORS. IN THIS WAY THE EFFECTS OF \"LASER INDUCED DISSOCIATION\" LEADING TO SOLID DEPOSITION ON THE CELL WALLS AND DUE TO THE LASER BEAM ABSORPTION FROM THE COLORED VAPORS WERE DEMINISHED. IN THE IRON (III) CHLORIDE-ALUMINUM CHLORIDE SYSTEM, THE VIBRATIONAL FREQUENCIES OF THE FE2CL6(9), FECL3(9) AND FEA MOLECULES WERE MEASURED FROM THE RAMAN SPECTRA. VIBRATIONAL ANALYSIS WAS PERFORMED FOR THE ABOVE MOLECULES BY MEANS OF \"NORMAL COORDINATE ANALYSIS\". THETHERMODYNAMIC FUNCTIONS OF ALL THE VAPOR SPECIES WERE CALCULATED, BASED ON THESPECTROSCOPIC DATA, IN THE FORM OF JANAF TYPE TABLES. IN THE GOLD (III) CHLORIDE-ALUMINUM CHLORIDE SYSTEM, THE VAPOR PRESSURE OF AUCL3 AND THE THERMODYNAMICSOF THE COMPLEX AUALCL6(9) FORMATION WERE DETERMINED BY UV-VIS ABSORPTION MEASUREMENTS. THE VIBRATIONAL FREQUENCIES OF THE AU2CL6(9) AND AUALCL6(9) VAPOR MOLECULES WERE MEASURED FROM RESONANCE RAMAN SPECTRA. VIBRATIONAL ANALYSIS WAS PERFORMED FOR BOTH MOLECULES AND THE THERMODYNAMIC FUNCTIONS OF THE SAME VAPOR SPECIES WERE CALCULATED IN THE FORM OF JANAF TYPE TABLES.","abstract_html":"RAMAN SPECTROSCOPY AND UV-VIS ABSORPTION SPECTROPHOTOMETRY HAVE BEEN USED IN ORDER TO STUDY TWO COLORED VAPORS SYSTEMS, THOSE OF IRON (III) CHLORIDE-ALUMINUM CHLORIDE AND GOLD (III) CHLORIDE- ALUMINUM CHLORIDE. IN BOTH SYSTEMS, COMPLEX MOLECULES ARE FORMED IN THE VAPOR PHASE. THE TECHNIC OF HIGH TEMPERATURE ROTATING RAMAN CELL WAS DEVELOPED AND USED IN ORDER TO BE ABLE TO OBTAIN RAMAN SPECTRAFROM THE COLORED VAPORS. IN THIS WAY THE EFFECTS OF "LASER INDUCED DISSOCIATION" LEADING TO SOLID DEPOSITION ON THE CELL WALLS AND DUE TO THE LASER BEAM ABSORPTION FROM THE COLORED VAPORS WERE DEMINISHED. IN THE IRON (III) CHLORIDE-ALUMINUM CHLORIDE SYSTEM, THE VIBRATIONAL FREQUENCIES OF THE FE2CL6(9), FECL3(9) AND FEA MOLECULES WERE MEASURED FROM THE RAMAN SPECTRA. VIBRATIONAL ANALYSIS WAS PERFORMED FOR THE ABOVE MOLECULES BY MEANS OF "NORMAL COORDINATE ANALYSIS". THETHERMODYNAMIC FUNCTIONS OF ALL THE VAPOR SPECIES WERE CALCULATED, BASED ON THESPECTROSCOPIC DATA, IN THE FORM OF JANAF TYPE TABLES. IN THE GOLD (III) CHLORIDE-ALUMINUM CHLORIDE SYSTEM, THE VAPOR PRESSURE OF AUCL3 AND THE THERMODYNAMICSOF THE COMPLEX AUALCL6(9) FORMATION WERE DETERMINED BY UV-VIS ABSORPTION MEASUREMENTS. THE VIBRATIONAL FREQUENCIES OF THE AU2CL6(9) AND AUALCL6(9) VAPOR MOLECULES WERE MEASURED FROM RESONANCE RAMAN SPECTRA. VIBRATIONAL ANALYSIS WAS PERFORMED FOR BOTH MOLECULES AND THE THERMODYNAMIC FUNCTIONS OF THE SAME VAPOR SPECIES WERE CALCULATED IN THE FORM OF JANAF TYPE TABLES.","abstract_has_math":false,"creators":["Ναλμπαντιάν, ΛΩΡΗ-ΧΡΙΠΣΙΜΕ","Nalbandian, Lori"],"institution":"Πανεπιστήμιο Πατρών","degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":[],"advisors":[],"committee_chairs":[],"committee_members":[],"year":1990,"date_issued":"1990","date_published":"1990","updated_at":"2026-07-24T02:24:49Z","subjects":["ALUMINUM CHLORIDE","COLORED VAPORS","GOLD (III) CHLORIDE","IRON (III) CHLORIDE","NORMAL COORDINATE ANALYSIS","Raman spectroscopy","THERMODYNAMIC FUNCTIONS","UV-VIS ABSORPTION SPECTROSCOPY","VAPOR COMPLEXES","VIBRATIONAL FREQUENCIES","ΑΕΡΙΑ ΣΥΜΠΛΟΚΑ","ΑΝΑΛΥΣΗ ΚΑΝΟΝΙΚΩΝ ΣΥΝΤΕΤΑΓΜΕΝΩΝ","ΕΓΧΡΩΜΟΙ ΑΤΜΟΙ","ΘΕΡΜΟΔΥΝΑΜΙΚΕΣ ΣΥΝΑΡΤΗΣΕΙΣ","ΣΥΧΝΟΤΗΤΕΣ ΔΟΝΗΣΗΣ","Τριχλωριούχος σίδηρος","ΤΡΙΧΛΩΡΙΟΥΧΟΣ ΧΡΥΣΟΣ","Φασματοσκοπία Raman","ΦΑΣΜΑΤΟΦΩΤΟΜΕΤΡΙΑ ΑΠΟΡΡΟΦΗΣΗΣ ΥΠΕΡΙΩΔΟΥΣ-ΟΡΑΤΟΥ","ΧΛΩΡΙΟΥΧΟ ΑΛΟΥΜΙΝΙΟ","Engineering and Technology","Chemical Engineering","Επιστήμες Μηχανικού και Τεχνολογία","Επιστήμη Χημικού Μηχανικού"],"languages":["gre"],"rights":[],"rights_urls":[],"identifier_entries":[{"key":"dc:identifier","label":"Identifier","values":["10.12681/eadd/1254"],"render_values":[{"text":"10.12681/eadd/1254","href":"https://doi.org/10.12681/eadd/1254","code":true}]}]},"links":{"outbound_url":"http://hdl.handle.net/10442/hedi/1254","outbound_label":"Handle","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:creator","label":"Author","values":["Ναλμπαντιάν, ΛΩΡΗ-ΧΡΙΠΣΙΜΕ","Nalbandian, Lori"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["1990"]},{"key":"dc:publisher","label":"Institution","values":["Πανεπιστήμιο Πατρών","University of Patras"]},{"key":"dc:type","label":"Dc Type","values":["PhD Thesis"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["ALUMINUM CHLORIDE","COLORED VAPORS","GOLD (III) CHLORIDE","IRON (III) CHLORIDE","NORMAL COORDINATE ANALYSIS","Raman spectroscopy","THERMODYNAMIC FUNCTIONS","UV-VIS ABSORPTION SPECTROSCOPY","VAPOR COMPLEXES","VIBRATIONAL FREQUENCIES","ΑΕΡΙΑ ΣΥΜΠΛΟΚΑ","ΑΝΑΛΥΣΗ ΚΑΝΟΝΙΚΩΝ ΣΥΝΤΕΤΑΓΜΕΝΩΝ","ΕΓΧΡΩΜΟΙ ΑΤΜΟΙ","ΘΕΡΜΟΔΥΝΑΜΙΚΕΣ ΣΥΝΑΡΤΗΣΕΙΣ","ΣΥΧΝΟΤΗΤΕΣ ΔΟΝΗΣΗΣ","Τριχλωριούχος σίδηρος","ΤΡΙΧΛΩΡΙΟΥΧΟΣ ΧΡΥΣΟΣ","Φασματοσκοπία Raman","ΦΑΣΜΑΤΟΦΩΤΟΜΕΤΡΙΑ ΑΠΟΡΡΟΦΗΣΗΣ ΥΠΕΡΙΩΔΟΥΣ-ΟΡΑΤΟΥ","ΧΛΩΡΙΟΥΧΟ ΑΛΟΥΜΙΝΙΟ","Engineering and Technology","Chemical Engineering","Επιστήμες Μηχανικού και Τεχνολογία","Επιστήμη Χημικού Μηχανικού"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["gre"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["10.12681/eadd/1254","http://hdl.handle.net/10442/hedi/1254"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["RAMAN SPECTROSCOPY AND UV-VIS ABSORPTION SPECTROPHOTOMETRY HAVE BEEN USED IN ORDER TO STUDY TWO COLORED VAPORS SYSTEMS, THOSE OF IRON (III) CHLORIDE-ALUMINUM CHLORIDE AND GOLD (III) CHLORIDE- ALUMINUM CHLORIDE. IN BOTH SYSTEMS, COMPLEX MOLECULES ARE FORMED IN THE VAPOR PHASE. THE TECHNIC OF HIGH TEMPERATURE ROTATING RAMAN CELL WAS DEVELOPED AND USED IN ORDER TO BE ABLE TO OBTAIN RAMAN SPECTRAFROM THE COLORED VAPORS. IN THIS WAY THE EFFECTS OF \"LASER INDUCED DISSOCIATION\" LEADING TO SOLID DEPOSITION ON THE CELL WALLS AND DUE TO THE LASER BEAM ABSORPTION FROM THE COLORED VAPORS WERE DEMINISHED. IN THE IRON (III) CHLORIDE-ALUMINUM CHLORIDE SYSTEM, THE VIBRATIONAL FREQUENCIES OF THE FE2CL6(9), FECL3(9) AND FEA MOLECULES WERE MEASURED FROM THE RAMAN SPECTRA. VIBRATIONAL ANALYSIS WAS PERFORMED FOR THE ABOVE MOLECULES BY MEANS OF \"NORMAL COORDINATE ANALYSIS\". THETHERMODYNAMIC FUNCTIONS OF ALL THE VAPOR SPECIES WERE CALCULATED, BASED ON THESPECTROSCOPIC DATA, IN THE FORM OF JANAF TYPE TABLES. IN THE GOLD (III) CHLORIDE-ALUMINUM CHLORIDE SYSTEM, THE VAPOR PRESSURE OF AUCL3 AND THE THERMODYNAMICSOF THE COMPLEX AUALCL6(9) FORMATION WERE DETERMINED BY UV-VIS ABSORPTION MEASUREMENTS. THE VIBRATIONAL FREQUENCIES OF THE AU2CL6(9) AND AUALCL6(9) VAPOR MOLECULES WERE MEASURED FROM RESONANCE RAMAN SPECTRA. VIBRATIONAL ANALYSIS WAS PERFORMED FOR BOTH MOLECULES AND THE THERMODYNAMIC FUNCTIONS OF THE SAME VAPOR SPECIES WERE CALCULATED IN THE FORM OF JANAF TYPE TABLES.","ΜΕ ΦΑΣΜΑΤΟΣΚΟΠΙΑ RAMAN ΚΑΙ ΦΑΣΜΑΤΟΦΩΤΟΜΕΤΡΙΑ ΥΠΕΡΙΩΔΟΥΣ ΟΡΑΤΟΥ ΜΕΛΕΤΗΘΗΚΑΝ ΟΙ ΕΓΧΡΩΜΟΙ ΑΤΜΟΙ ΔΥΟ ΣΥΣΤΗΜΑΤΩΝ ΤΩΝ ΧΛΩΡΙΟΥΧΟΥ ΣΙΔΗΡΟΥ-ΧΛΩΡΙΟΥΧΟΥ ΑΛΟΥΜΙΝΙΟΥ ΚΑΙ ΧΛΩΡΙΟΥΧΟΥ ΧΡΥΣΟΥ-ΧΛΩΡΙΟΥΧΟΥ ΑΛΟΥΜΙΝΙΟΥ. ΔΙΑΠΙΣΤΩΘΗΚΕ ΚΑΙ ΣΤΑ ΔΥΟ ΣΥΣΤΗΜΑΤΑ Ο ΣΧΗΜΑΤΙΣΜΟΣ ΣΥΜΠΛΟΚΩΝ ΜΟΡΙΩΝ ΣΤΗΝ ΑΕΡΙΑ ΦΑΣΗ. ΓΙΑ ΤΗΝ ΛΗΨΗ ΤΩΝ ΦΑΣΜΑΤΩΝ RAMAN ΑΠΟΤΟΥΣ ΕΓΧΡΩΜΟΥΣ ΑΤΜΟΥΣ ΑΝΑΠΤΥΧΘΗΚΕ ΚΑΙ ΧΡΗΣΙΜΟΠΟΙΗΘΗΚΕ Η ΤΕΧΝΙΚΗ ΤΗΣ ΠΕΡΙΣΤΡΟΦΗΣ ΤΗΣ ΚΥΨΕΛΛΙΔΑΣ ΣΕ ΥΨΗΛΗ ΘΕΡΜΟΚΡΑΣΙΑ. ΕΤΣΙ ΕΛΑΧΙΣΤΟΠΟΙΗΘΗΚΕ ΤΟ ΠΡΟΒΛΗΜΑ ΤΗΣ \"ΕΠΑΓΟΜΕΝΗΣ ΑΠΟ ΤΟ LASER ΔΙΑΣΠΑΣΗΣ\" ΤΩΝ ΑΤΜΩΝ ΠΟΥ ΟΦΕΙΛΕΤΑΙ ΣΤΗΝ ΑΠΟΡΡΟΦΗΣΗ ΤΗΣ ΑΚΤΙΝΟΒΟΛΙΑΣ ΑΠΟ ΤΟΥΣ ΕΓΧΡΩΜΟΥΣ ΑΤΜΟΥΣ. ΣΤΟ ΣΥΣΤΗΜΑ FECL3-ALCL3, ΜΕΤΡΗΘΗΚΑΝ ΑΠΟ ΤΑ ΦΑΣΜΑΤΑ RAMAN ΟΙ ΣΥΧΝΟΤΗΤΕΣ ΔΟΝΗΣΗΣ ΤΩΝ ΜΟΡΙΩΝ FE2CL6(9), FECL3(9) KAI FEALCL6(9). ΓΙΑ ΤΑ ΙΔΙΑ ΜΟΡΙΑ ΕΓΙΝΕ ΔΟΝΗΤΙΚΗ ΑΝΑΛΥΣΗ ΜΕ ΤΗΝ ΜΕΘΟΔΟ ΤΗΣ \"ΑΝΑΛΥΣΗΣ ΚΑΝΟΝΙΚΩΝ ΣΥΝΤΕΤΑΓΜΕΝΩΝ\". ΟΙ ΘΕΡΜΟΔΥΝΑΜΙΚΕΣ ΣΥΝΑΡΤΗΣΕΙΣ ΤΩΝ ΜΟΡΙΩΝ ΑΥΤΩΝ ΥΠΟΛΟΓΙΣΤΗΚΑΝ ΥΠΟ ΤΗΝ ΜΟΡΦΗ ΠΙΝΑΚΩΝ JANAF ΜΕ ΒΑΣΗ ΤΑ ΦΑΣΜΑΤΟΣΚΟΠΙΚΑ ΔΕΔΟΜΕΝΑ. ΣΤΟ ΣΥΣΤΗΜΑ ΧΛΩΡΙΟΥΧΟΥ ΧΡΥΣΟΥ-ΧΛΩΡΙΟΥΧΟΥ ΑΛΟΥΜΙΝΙΟΥ ΜΕΤΡΗΘΗΚΑΝ ΜΕ ΦΑΣΜΑΤΟΦΩΤΟΜΕΤΡΙΑ UV-VIS, Η ΤΑΣΗ ΑΤΜΩΝ ΤΟΥ AUCL3 ΚΑΙ ΟΙ ΘΕΡΜΟΔΥΝΑΜΙΚΕΣ ΣΥΝΑΡΤΗΣΕΙΣ ΤΗΣ ΑΝΤΙΔΡΑΣΗΣ ΣΧΗΜΑΤΙΣΜΟΥ ΤΟΥ ΣΥΜΠΛΟΚΟΥ AUALCL6(9). ΟΙ ΣΥΧΝΟΤΗΤΕΣ ΔΟΝΗΣΗΣ ΤΩΝ ΜΟΡΙΩΝ AU2CL6(9) KAI AUALCL6(9) ΜΕΤΡΗΘΗΚΑΝ ΑΠΟ ΦΑΣΜΑΤΑ RAMAN ΣΥΝΤΟΝΙΣΜΟΥ. ΓΙΑ ΤΑ ΙΔΙΑ ΜΟΡΙΑ ΕΓΙΝΕ ΔΟΝΗΤΙΚΗ ΑΝΑΛΥΣΗ ΚΑΙ ΥΠΟΛΟΓΙΣΤΗΚΑΝ ΟΙ ΘΕΡΜΟΔΥΝΑΜΙΚΕΣ ΣΥΝΑΡΤΗΣΕΙΣ ΥΠΟ ΜΟΡΦΗ ΠΙΝΑΚΩΝ JANAF."]},{"key":"dc:title","label":"Title","values":["ΦΑΣΜΑΤΟΣΚΟΠΙΚΗ ΜΕΛΕΤΗ ΑΕΡΙΩΝ ΣΥΜΠΛΟΚΩΝ ΣΕ ΥΨΗΛΕΣ ΘΕΡΜΟΚΡΑΣΙΕΣ ΣΕ ΣΥΣΤΗΜΑΤΑ ΧΛΩΡΙΟΥΧΩΝ ΑΛΑΤΩΝ ΤΩΝ ΣΙΔΗΡΟΥ, ΧΡΥΣΟΥ ΚΑΙ ΑΛΟΥΜΙΝΙΟΥ","SPECTROSCOPIC STUDY OF VAPOR COMPLEXES AT HIGH TEMPERATURES IN SYSTEMS OF IRON,GOLD AND ALUMINUM CHLORIDES"]}]}],"canonical_facts":{"dc:creator":["Ναλμπαντιάν, ΛΩΡΗ-ΧΡΙΠΣΙΜΕ","Nalbandian, Lori"],"dc:date":["1990"],"dc:description":["RAMAN SPECTROSCOPY AND UV-VIS ABSORPTION SPECTROPHOTOMETRY HAVE BEEN USED IN ORDER TO STUDY TWO COLORED VAPORS SYSTEMS, THOSE OF IRON (III) CHLORIDE-ALUMINUM CHLORIDE AND GOLD (III) CHLORIDE- ALUMINUM CHLORIDE. IN BOTH SYSTEMS, COMPLEX MOLECULES ARE FORMED IN THE VAPOR PHASE. THE TECHNIC OF HIGH TEMPERATURE ROTATING RAMAN CELL WAS DEVELOPED AND USED IN ORDER TO BE ABLE TO OBTAIN RAMAN SPECTRAFROM THE COLORED VAPORS. IN THIS WAY THE EFFECTS OF \"LASER INDUCED DISSOCIATION\" LEADING TO SOLID DEPOSITION ON THE CELL WALLS AND DUE TO THE LASER BEAM ABSORPTION FROM THE COLORED VAPORS WERE DEMINISHED. IN THE IRON (III) CHLORIDE-ALUMINUM CHLORIDE SYSTEM, THE VIBRATIONAL FREQUENCIES OF THE FE2CL6(9), FECL3(9) AND FEA MOLECULES WERE MEASURED FROM THE RAMAN SPECTRA. VIBRATIONAL ANALYSIS WAS PERFORMED FOR THE ABOVE MOLECULES BY MEANS OF \"NORMAL COORDINATE ANALYSIS\". THETHERMODYNAMIC FUNCTIONS OF ALL THE VAPOR SPECIES WERE CALCULATED, BASED ON THESPECTROSCOPIC DATA, IN THE FORM OF JANAF TYPE TABLES. IN THE GOLD (III) CHLORIDE-ALUMINUM CHLORIDE SYSTEM, THE VAPOR PRESSURE OF AUCL3 AND THE THERMODYNAMICSOF THE COMPLEX AUALCL6(9) FORMATION WERE DETERMINED BY UV-VIS ABSORPTION MEASUREMENTS. THE VIBRATIONAL FREQUENCIES OF THE AU2CL6(9) AND AUALCL6(9) VAPOR MOLECULES WERE MEASURED FROM RESONANCE RAMAN SPECTRA. VIBRATIONAL ANALYSIS WAS PERFORMED FOR BOTH MOLECULES AND THE THERMODYNAMIC FUNCTIONS OF THE SAME VAPOR SPECIES WERE CALCULATED IN THE FORM OF JANAF TYPE TABLES.","ΜΕ ΦΑΣΜΑΤΟΣΚΟΠΙΑ RAMAN ΚΑΙ ΦΑΣΜΑΤΟΦΩΤΟΜΕΤΡΙΑ ΥΠΕΡΙΩΔΟΥΣ ΟΡΑΤΟΥ ΜΕΛΕΤΗΘΗΚΑΝ ΟΙ ΕΓΧΡΩΜΟΙ ΑΤΜΟΙ ΔΥΟ ΣΥΣΤΗΜΑΤΩΝ ΤΩΝ ΧΛΩΡΙΟΥΧΟΥ ΣΙΔΗΡΟΥ-ΧΛΩΡΙΟΥΧΟΥ ΑΛΟΥΜΙΝΙΟΥ ΚΑΙ ΧΛΩΡΙΟΥΧΟΥ ΧΡΥΣΟΥ-ΧΛΩΡΙΟΥΧΟΥ ΑΛΟΥΜΙΝΙΟΥ. ΔΙΑΠΙΣΤΩΘΗΚΕ ΚΑΙ ΣΤΑ ΔΥΟ ΣΥΣΤΗΜΑΤΑ Ο ΣΧΗΜΑΤΙΣΜΟΣ ΣΥΜΠΛΟΚΩΝ ΜΟΡΙΩΝ ΣΤΗΝ ΑΕΡΙΑ ΦΑΣΗ. ΓΙΑ ΤΗΝ ΛΗΨΗ ΤΩΝ ΦΑΣΜΑΤΩΝ RAMAN ΑΠΟΤΟΥΣ ΕΓΧΡΩΜΟΥΣ ΑΤΜΟΥΣ ΑΝΑΠΤΥΧΘΗΚΕ ΚΑΙ ΧΡΗΣΙΜΟΠΟΙΗΘΗΚΕ Η ΤΕΧΝΙΚΗ ΤΗΣ ΠΕΡΙΣΤΡΟΦΗΣ ΤΗΣ ΚΥΨΕΛΛΙΔΑΣ ΣΕ ΥΨΗΛΗ ΘΕΡΜΟΚΡΑΣΙΑ. ΕΤΣΙ ΕΛΑΧΙΣΤΟΠΟΙΗΘΗΚΕ ΤΟ ΠΡΟΒΛΗΜΑ ΤΗΣ \"ΕΠΑΓΟΜΕΝΗΣ ΑΠΟ ΤΟ LASER ΔΙΑΣΠΑΣΗΣ\" ΤΩΝ ΑΤΜΩΝ ΠΟΥ ΟΦΕΙΛΕΤΑΙ ΣΤΗΝ ΑΠΟΡΡΟΦΗΣΗ ΤΗΣ ΑΚΤΙΝΟΒΟΛΙΑΣ ΑΠΟ ΤΟΥΣ ΕΓΧΡΩΜΟΥΣ ΑΤΜΟΥΣ. ΣΤΟ ΣΥΣΤΗΜΑ FECL3-ALCL3, ΜΕΤΡΗΘΗΚΑΝ ΑΠΟ ΤΑ ΦΑΣΜΑΤΑ RAMAN ΟΙ ΣΥΧΝΟΤΗΤΕΣ ΔΟΝΗΣΗΣ ΤΩΝ ΜΟΡΙΩΝ FE2CL6(9), FECL3(9) KAI FEALCL6(9). ΓΙΑ ΤΑ ΙΔΙΑ ΜΟΡΙΑ ΕΓΙΝΕ ΔΟΝΗΤΙΚΗ ΑΝΑΛΥΣΗ ΜΕ ΤΗΝ ΜΕΘΟΔΟ ΤΗΣ \"ΑΝΑΛΥΣΗΣ ΚΑΝΟΝΙΚΩΝ ΣΥΝΤΕΤΑΓΜΕΝΩΝ\". ΟΙ ΘΕΡΜΟΔΥΝΑΜΙΚΕΣ ΣΥΝΑΡΤΗΣΕΙΣ ΤΩΝ ΜΟΡΙΩΝ ΑΥΤΩΝ ΥΠΟΛΟΓΙΣΤΗΚΑΝ ΥΠΟ ΤΗΝ ΜΟΡΦΗ ΠΙΝΑΚΩΝ JANAF ΜΕ ΒΑΣΗ ΤΑ ΦΑΣΜΑΤΟΣΚΟΠΙΚΑ ΔΕΔΟΜΕΝΑ. ΣΤΟ ΣΥΣΤΗΜΑ ΧΛΩΡΙΟΥΧΟΥ ΧΡΥΣΟΥ-ΧΛΩΡΙΟΥΧΟΥ ΑΛΟΥΜΙΝΙΟΥ ΜΕΤΡΗΘΗΚΑΝ ΜΕ ΦΑΣΜΑΤΟΦΩΤΟΜΕΤΡΙΑ UV-VIS, Η ΤΑΣΗ ΑΤΜΩΝ ΤΟΥ AUCL3 ΚΑΙ ΟΙ ΘΕΡΜΟΔΥΝΑΜΙΚΕΣ ΣΥΝΑΡΤΗΣΕΙΣ ΤΗΣ ΑΝΤΙΔΡΑΣΗΣ ΣΧΗΜΑΤΙΣΜΟΥ ΤΟΥ ΣΥΜΠΛΟΚΟΥ AUALCL6(9). ΟΙ ΣΥΧΝΟΤΗΤΕΣ ΔΟΝΗΣΗΣ ΤΩΝ ΜΟΡΙΩΝ AU2CL6(9) KAI AUALCL6(9) ΜΕΤΡΗΘΗΚΑΝ ΑΠΟ ΦΑΣΜΑΤΑ RAMAN ΣΥΝΤΟΝΙΣΜΟΥ. ΓΙΑ ΤΑ ΙΔΙΑ ΜΟΡΙΑ ΕΓΙΝΕ ΔΟΝΗΤΙΚΗ ΑΝΑΛΥΣΗ ΚΑΙ ΥΠΟΛΟΓΙΣΤΗΚΑΝ ΟΙ ΘΕΡΜΟΔΥΝΑΜΙΚΕΣ ΣΥΝΑΡΤΗΣΕΙΣ ΥΠΟ ΜΟΡΦΗ ΠΙΝΑΚΩΝ JANAF."],"dc:identifier":["10.12681/eadd/1254","http://hdl.handle.net/10442/hedi/1254"],"dc:language":["gre"],"dc:publisher":["Πανεπιστήμιο Πατρών","University of Patras"],"dc:subject":["ALUMINUM CHLORIDE","COLORED VAPORS","GOLD (III) CHLORIDE","IRON (III) CHLORIDE","NORMAL COORDINATE ANALYSIS","Raman spectroscopy","THERMODYNAMIC FUNCTIONS","UV-VIS ABSORPTION SPECTROSCOPY","VAPOR COMPLEXES","VIBRATIONAL FREQUENCIES","ΑΕΡΙΑ ΣΥΜΠΛΟΚΑ","ΑΝΑΛΥΣΗ ΚΑΝΟΝΙΚΩΝ ΣΥΝΤΕΤΑΓΜΕΝΩΝ","ΕΓΧΡΩΜΟΙ ΑΤΜΟΙ","ΘΕΡΜΟΔΥΝΑΜΙΚΕΣ ΣΥΝΑΡΤΗΣΕΙΣ","ΣΥΧΝΟΤΗΤΕΣ ΔΟΝΗΣΗΣ","Τριχλωριούχος σίδηρος","ΤΡΙΧΛΩΡΙΟΥΧΟΣ ΧΡΥΣΟΣ","Φασματοσκοπία Raman","ΦΑΣΜΑΤΟΦΩΤΟΜΕΤΡΙΑ ΑΠΟΡΡΟΦΗΣΗΣ ΥΠΕΡΙΩΔΟΥΣ-ΟΡΑΤΟΥ","ΧΛΩΡΙΟΥΧΟ ΑΛΟΥΜΙΝΙΟ","Engineering and Technology","Chemical Engineering","Επιστήμες Μηχανικού και Τεχνολογία","Επιστήμη Χημικού Μηχανικού"],"dc:title":["ΦΑΣΜΑΤΟΣΚΟΠΙΚΗ ΜΕΛΕΤΗ ΑΕΡΙΩΝ ΣΥΜΠΛΟΚΩΝ ΣΕ ΥΨΗΛΕΣ ΘΕΡΜΟΚΡΑΣΙΕΣ ΣΕ ΣΥΣΤΗΜΑΤΑ ΧΛΩΡΙΟΥΧΩΝ ΑΛΑΤΩΝ ΤΩΝ ΣΙΔΗΡΟΥ, ΧΡΥΣΟΥ ΚΑΙ ΑΛΟΥΜΙΝΙΟΥ","SPECTROSCOPIC STUDY OF VAPOR COMPLEXES AT HIGH TEMPERATURES IN SYSTEMS OF IRON,GOLD AND ALUMINUM CHLORIDES"],"dc:type":["PhD Thesis"]},"updated_at":"2026-07-24T02:24:49Z"}