{"id":{"repo_id":"greece","oai_identifier":"oai:10442/1091"},"canonical_url":"https://search.dev.ndltd.org/etd/greece/oai:10442/1091","repository":{"repo_id":"greece","name":"Greek National Archive of PhD Theses","base_url":"https://phdtheses.ekt.gr/eadd_oai/request"},"display":{"title":"ΜΕΛΕΤΗ ΤΗΣ ΗΛΕΚΤΡΟΝΙΚΗΣ ΔΟΜΗΣ, ΤΗΣ ΓΕΩΜΕΤΡΙΑΣ ΚΑΙ ΤΗΣ ΔΡΑΣΤΙΚΟΤΗΤΑΣ ΥΠΕΡΣΘΕΝΩΝ ΟΡΓΑΝΟΑΛΟΓΟΝΟΥΧΩΝ ΕΝΩΣΕΩΝ","abstract":"IN THE PRESENT STUDY, THE MOLECULAR GEOMETRY AND THE PARTICULAR ELECTRONIC EFFECTS OF HYPERVALENT ORGANOHALOGEN COMPOUNDS OF THE FORMULA PHXX'2 WAS EXAMINED AND THEIR ABILITY TO FORM ADDITION PRODUCTS WITH ETHYLENE DOUBLE BONDS VIA A SYNCHRONOUS MOLECULAR ADDITION MECHANISM. THE NATURE OF THE X-X' BONDS WAS ALSO ANALYZED AND VERIFIED IN TERMS OF DIFFERENT ATOMIC ORBITAL BASIS SETS. FINALLY, THE ISOLOBAL ANALOGY BETWEEN THESE COMPOUNDS AND ANALOGOUS COMPOUNDS OF TELLURIUM WAS VERIFIED.","abstract_html":"IN THE PRESENT STUDY, THE MOLECULAR GEOMETRY AND THE PARTICULAR ELECTRONIC EFFECTS OF HYPERVALENT ORGANOHALOGEN COMPOUNDS OF THE FORMULA PHXX'2 WAS EXAMINED AND THEIR ABILITY TO FORM ADDITION PRODUCTS WITH ETHYLENE DOUBLE BONDS VIA A SYNCHRONOUS MOLECULAR ADDITION MECHANISM. THE NATURE OF THE X-X' BONDS WAS ALSO ANALYZED AND VERIFIED IN TERMS OF DIFFERENT ATOMIC ORBITAL BASIS SETS. FINALLY, THE ISOLOBAL ANALOGY BETWEEN THESE COMPOUNDS AND ANALOGOUS COMPOUNDS OF TELLURIUM WAS VERIFIED.","abstract_has_math":false,"creators":["Μυλωνάς, Βασίλειος"],"institution":"Αριστοτέλειο Πανεπιστήμιο Θεσσαλονίκης (ΑΠΘ)","degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":[],"advisors":[],"committee_chairs":[],"committee_members":[],"year":1989,"date_issued":"1989","date_published":"1989","updated_at":"2026-07-24T02:24:43Z","subjects":["DIFFUSED AND LOCALIZED MOLECULARORBITALS","ELECTRONIC STRUCTURE OF HYPERVALENT MOLECULES","HYPERVALENT MOLECULES","ISOLOBAL ANALOGY","Quantum chemical calculations","REACTIVITY OF HYPERVALENT MOLECULES","ΔΡΑΣΤΙΚΟΤΗΤΑ ΥΠΕΡΣΘΕΝΩΝΕΝΩΣΕΩΝ","ΗΛΕΚΤΡΟΝΙΚΗ ΔΟΜΗ ΥΠΕΡΣΘΕΝΩΝ ΕΝΩΣΕΩΝ","ΙΣΟΛΟΒΙΚΗ ΑΝΑΛΟΓΙΑ","Κβαντοχημικοί υπολογισμοί","ΥΠΕΡΣΘΕΝΕΙΣ ΕΝΩΣΕΙΣ","Φυσικές Επιστήμες","Natural Sciences","Χημεία","Chemical Sciences"],"languages":["gre"],"rights":[],"rights_urls":[],"identifier_entries":[{"key":"dc:identifier","label":"Identifier","values":["10.12681/eadd/1091"],"render_values":[{"text":"10.12681/eadd/1091","href":"https://doi.org/10.12681/eadd/1091","code":true}]}]},"links":{"outbound_url":"http://hdl.handle.net/10442/hedi/1091","outbound_label":"Handle","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:creator","label":"Author","values":["Μυλωνάς, Βασίλειος"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["1989"]},{"key":"dc:publisher","label":"Institution","values":["Αριστοτέλειο Πανεπιστήμιο Θεσσαλονίκης (ΑΠΘ)","Aristotle University Of Thessaloniki (AUTH)"]},{"key":"dc:type","label":"Dc Type","values":["PhD Thesis"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["DIFFUSED AND LOCALIZED MOLECULARORBITALS","ELECTRONIC STRUCTURE OF HYPERVALENT MOLECULES","HYPERVALENT MOLECULES","ISOLOBAL ANALOGY","Quantum chemical calculations","REACTIVITY OF HYPERVALENT MOLECULES","ΔΡΑΣΤΙΚΟΤΗΤΑ ΥΠΕΡΣΘΕΝΩΝΕΝΩΣΕΩΝ","ΗΛΕΚΤΡΟΝΙΚΗ ΔΟΜΗ ΥΠΕΡΣΘΕΝΩΝ ΕΝΩΣΕΩΝ","ΙΣΟΛΟΒΙΚΗ ΑΝΑΛΟΓΙΑ","Κβαντοχημικοί υπολογισμοί","ΥΠΕΡΣΘΕΝΕΙΣ ΕΝΩΣΕΙΣ","Φυσικές Επιστήμες","Natural Sciences","Χημεία","Chemical Sciences"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["gre"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["10.12681/eadd/1091","http://hdl.handle.net/10442/hedi/1091"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["IN THE PRESENT STUDY, THE MOLECULAR GEOMETRY AND THE PARTICULAR ELECTRONIC EFFECTS OF HYPERVALENT ORGANOHALOGEN COMPOUNDS OF THE FORMULA PHXX'2 WAS EXAMINED AND THEIR ABILITY TO FORM ADDITION PRODUCTS WITH ETHYLENE DOUBLE BONDS VIA A SYNCHRONOUS MOLECULAR ADDITION MECHANISM. THE NATURE OF THE X-X' BONDS WAS ALSO ANALYZED AND VERIFIED IN TERMS OF DIFFERENT ATOMIC ORBITAL BASIS SETS. FINALLY, THE ISOLOBAL ANALOGY BETWEEN THESE COMPOUNDS AND ANALOGOUS COMPOUNDS OF TELLURIUM WAS VERIFIED.","ΣΤΗΝ ΠΑΡΟΥΣΑ ΜΕΛΕΤΗ ΕΞΕΤΑΣΤΗΚΑΝ Η ΜΟΡΙΑΚΗ ΔΟΜΗ ΚΑΙ ΤΑ ΙΔΙΑΙΤΕΡΑ ΗΛΕΚΤΡΟΝΙΚΑ ΧΑΡΑΚΤΗΡΙΣΤΙΚΑ ΤΩΝ ΥΠΕΡΣΘΕΝΩΝ ΟΡΓΑΝΟΑΛΟΓΟΝΟΥΧΩΝ ΕΝΩΣΕΩΝ ΤΟΥ ΤΥΠΟΥ PHXX'2 ΚΑΙ ΕΠΙΒΕΒΑΙΩΘΗΚΕ Η ΔΥΝΑΤΟΤΗΤΑ ΤΟΥΣ ΝΑ ΠΡΟΚΑΛΟΥΝ ΑΝΟΡΘΩΣΗ ΔΙΠΛΩΝ ΔΕΣΜΩΝ ΜΕΣΩ ΕΝΟΣ ΣΥΓΧΡΟΝΟΥ ΜΗΧΑΝΙΣΜΟΥ ΜΟΡΙΑΚΗΣ ΠΡΟΣΘΗΚΗΣ. ΑΝΑΛΥΘΗΚΕ ΚΑΙ ΔΙΕΥΚΡΙΝΗΣΤΗΚΕ Η ΦΥΣΗ ΤΟΥ ΔΕΣΜΟΥ Χ-Χ' ΣΕ ΣΧΕΣΗ ΜΕ ΔΙΑΦΟΡΕΤΙΚΑ ΣΥΝΟΛΑ ΒΑΣΗΣ ΑΤΟΜΙΚΩΝ ΤΡΟΧΙΑΚΩΝ. ΕΠΙΠΛΕΟΝ ΔΕΧΘΗΚΕ Ο ΙΣΟΛΟΒΙΣΜΟΣ ΤΩΝ ΕΝΩΣΕΩΝ ΑΥΤΩΝ ΜΕ ΑΝΑΛΟΓΕΣ ΕΝΩΣΕΙΣ ΤΟΥ ΤΕΛΛΟΥΡΙΟΥ."]},{"key":"dc:title","label":"Title","values":["ΜΕΛΕΤΗ ΤΗΣ ΗΛΕΚΤΡΟΝΙΚΗΣ ΔΟΜΗΣ, ΤΗΣ ΓΕΩΜΕΤΡΙΑΣ ΚΑΙ ΤΗΣ ΔΡΑΣΤΙΚΟΤΗΤΑΣ ΥΠΕΡΣΘΕΝΩΝ ΟΡΓΑΝΟΑΛΟΓΟΝΟΥΧΩΝ ΕΝΩΣΕΩΝ","STUDY OF THE ELECTRONIC STRUCTURE, GEOMETRY AND REACTIVITY OF HYPERVALENT ORGANOHALOGE �COMPOUNDS"]}]}],"canonical_facts":{"dc:creator":["Μυλωνάς, Βασίλειος"],"dc:date":["1989"],"dc:description":["IN THE PRESENT STUDY, THE MOLECULAR GEOMETRY AND THE PARTICULAR ELECTRONIC EFFECTS OF HYPERVALENT ORGANOHALOGEN COMPOUNDS OF THE FORMULA PHXX'2 WAS EXAMINED AND THEIR ABILITY TO FORM ADDITION PRODUCTS WITH ETHYLENE DOUBLE BONDS VIA A SYNCHRONOUS MOLECULAR ADDITION MECHANISM. THE NATURE OF THE X-X' BONDS WAS ALSO ANALYZED AND VERIFIED IN TERMS OF DIFFERENT ATOMIC ORBITAL BASIS SETS. FINALLY, THE ISOLOBAL ANALOGY BETWEEN THESE COMPOUNDS AND ANALOGOUS COMPOUNDS OF TELLURIUM WAS VERIFIED.","ΣΤΗΝ ΠΑΡΟΥΣΑ ΜΕΛΕΤΗ ΕΞΕΤΑΣΤΗΚΑΝ Η ΜΟΡΙΑΚΗ ΔΟΜΗ ΚΑΙ ΤΑ ΙΔΙΑΙΤΕΡΑ ΗΛΕΚΤΡΟΝΙΚΑ ΧΑΡΑΚΤΗΡΙΣΤΙΚΑ ΤΩΝ ΥΠΕΡΣΘΕΝΩΝ ΟΡΓΑΝΟΑΛΟΓΟΝΟΥΧΩΝ ΕΝΩΣΕΩΝ ΤΟΥ ΤΥΠΟΥ PHXX'2 ΚΑΙ ΕΠΙΒΕΒΑΙΩΘΗΚΕ Η ΔΥΝΑΤΟΤΗΤΑ ΤΟΥΣ ΝΑ ΠΡΟΚΑΛΟΥΝ ΑΝΟΡΘΩΣΗ ΔΙΠΛΩΝ ΔΕΣΜΩΝ ΜΕΣΩ ΕΝΟΣ ΣΥΓΧΡΟΝΟΥ ΜΗΧΑΝΙΣΜΟΥ ΜΟΡΙΑΚΗΣ ΠΡΟΣΘΗΚΗΣ. ΑΝΑΛΥΘΗΚΕ ΚΑΙ ΔΙΕΥΚΡΙΝΗΣΤΗΚΕ Η ΦΥΣΗ ΤΟΥ ΔΕΣΜΟΥ Χ-Χ' ΣΕ ΣΧΕΣΗ ΜΕ ΔΙΑΦΟΡΕΤΙΚΑ ΣΥΝΟΛΑ ΒΑΣΗΣ ΑΤΟΜΙΚΩΝ ΤΡΟΧΙΑΚΩΝ. ΕΠΙΠΛΕΟΝ ΔΕΧΘΗΚΕ Ο ΙΣΟΛΟΒΙΣΜΟΣ ΤΩΝ ΕΝΩΣΕΩΝ ΑΥΤΩΝ ΜΕ ΑΝΑΛΟΓΕΣ ΕΝΩΣΕΙΣ ΤΟΥ ΤΕΛΛΟΥΡΙΟΥ."],"dc:identifier":["10.12681/eadd/1091","http://hdl.handle.net/10442/hedi/1091"],"dc:language":["gre"],"dc:publisher":["Αριστοτέλειο Πανεπιστήμιο Θεσσαλονίκης (ΑΠΘ)","Aristotle University Of Thessaloniki (AUTH)"],"dc:subject":["DIFFUSED AND LOCALIZED MOLECULARORBITALS","ELECTRONIC STRUCTURE OF HYPERVALENT MOLECULES","HYPERVALENT MOLECULES","ISOLOBAL ANALOGY","Quantum chemical calculations","REACTIVITY OF HYPERVALENT MOLECULES","ΔΡΑΣΤΙΚΟΤΗΤΑ ΥΠΕΡΣΘΕΝΩΝΕΝΩΣΕΩΝ","ΗΛΕΚΤΡΟΝΙΚΗ ΔΟΜΗ ΥΠΕΡΣΘΕΝΩΝ ΕΝΩΣΕΩΝ","ΙΣΟΛΟΒΙΚΗ ΑΝΑΛΟΓΙΑ","Κβαντοχημικοί υπολογισμοί","ΥΠΕΡΣΘΕΝΕΙΣ ΕΝΩΣΕΙΣ","Φυσικές Επιστήμες","Natural Sciences","Χημεία","Chemical Sciences"],"dc:title":["ΜΕΛΕΤΗ ΤΗΣ ΗΛΕΚΤΡΟΝΙΚΗΣ ΔΟΜΗΣ, ΤΗΣ ΓΕΩΜΕΤΡΙΑΣ ΚΑΙ ΤΗΣ ΔΡΑΣΤΙΚΟΤΗΤΑΣ ΥΠΕΡΣΘΕΝΩΝ ΟΡΓΑΝΟΑΛΟΓΟΝΟΥΧΩΝ ΕΝΩΣΕΩΝ","STUDY OF THE ELECTRONIC STRUCTURE, GEOMETRY AND REACTIVITY OF HYPERVALENT ORGANOHALOGE �COMPOUNDS"],"dc:type":["PhD Thesis"]},"updated_at":"2026-07-24T02:24:43Z"}