ΜΕΛΕΤΗ ΑΝΤΙΔΡΑΣΕΩΝ ΔΙΑΡΥΛΟΙΩΔΩΝΙΑΚΩΝ ΚΑΙ ΦΑΙΝΥΛΟ(Β-ΑΡΥΛΟΑΙΘΙΝΥΛΟ) ΙΩΔΩΝΙΑΚΩΝ ΑΛΑΤΩΝ

A SERIES OF NEW IODANES WITH AN IODINE-SULPHUR BOND HAVE BEEN PREPARED. THEIR PHYSICAL PROPERTIES SUGGEST COVALENT CHARACTER FOR THE IODINE-SULPHUR BOND, AND THE MOST INTERESTING PROPERTY OF THESE COMPOUNDS IS THEIR DECOMPOSITION. PHENYL(ARYLETHYNYL) IODONIUM SALTS REACT AS 1,3-DIPOLAROPHILES WITH NITRILOXIDES TO AFFORD PHENYL (SUBSTITUTED ISOXAZOLYL) IODONIUM SALTS. THE CHEMICAL PROPERTIES OF THE CYCLOADDITION PRODUCTS IS BRIEFLY EXAMINED. PHENYL (ARYLETHYNYL) IODONIUM SALTS REACT ALSO WITH NITRONES BUT THE RESULTING PHENYL (SUBSTITUTED ISOXAZOLINYL) IODONIUM SALTS WITH ONE EXCEPTION ARE DIFFICULT TO ISOLATE BECAUSE OF READY HYDROLYSIS.

Grantor dc:publisher

Aristotle University Of Thessaloniki (AUTH)

Year dc:date

1988

Authors dc:creator

• Κόταλη, Ελβίρα
• Kotali, Elvira

• 1,3 ΚΥΚΛΟΠΡΟΣΘΗΚΗ
• ΑΛΚΙΝΥΛΟΙΩΔΩΝΙΑΚΑ ΑΛΑΤΑ
• ΔΙΑΡΥΛΟΙΩΔΩΝΙΑΚΑ ΑΛΑΤΑ
• ΙΩΔΑΝΙΑ
• ΠΟΛΥΣΘΕΝΕΣ ΙΩΔΙΟ
• 1,3 CYCLOADDITION
• ALKYNYLIODONIUM SALTS
• DIARYLIODONIUM SALTS
• Hypervalent iodine
• IODONES
• Φυσικές Επιστήμες
• Χημεία
• Natural Sciences
• Chemical Sciences

Language dc:language

gre

Identifier

10.12681/eadd/0683

OAI identifier oai:identifier

oai:10442/0683