{"id":{"repo_id":"greece","oai_identifier":"oai:10442/0583"},"canonical_url":"https://search.dev.ndltd.org/etd/greece/oai:10442/0583","repository":{"repo_id":"greece","name":"Greek National Archive of PhD Theses","base_url":"https://phdtheses.ekt.gr/eadd_oai/request"},"display":{"title":"ΜΕΛΕΤΗ ΤΗΣ ΣΤΑΘΕΡΟΤΗΤΑΣ ΚΑΙ ΥΠΟΛΕΙΜΜΑΤΙΚΟΤΗΤΑΣ ΤΟΥ ΝΕΟΥ ΕΝΤΟΜΟΚΤΟΝΟΥ \"ΔΙΑΙΘΥΛΟΦΩΣΦΟΡΙΚΟΣ ΕΣΤΕΡΑΣ ΤΗΣ ΔΙΚΥΚΛΟΠΡΟΠΥΛΟΚΕΤΟΞΙΜΗΣ\"","abstract":"IN THIS DISSERTATION, THE STABILITY AND THE RESIDUE BEHAVIOUR OF THE NEW (CURRENTLY UNDER STUDY) INSECTICIDE \"DIETHYL PHOSPHORIC ESTER OF THE DICYCLOPROPYLOKETOXIME\" WAS INVESTIGATED IN RELATION WITH THE STRUCTURAL ORIGINALITY OF THE COMPOUND. THE CHEMICAL REACTIONS OF THE ESTER, MAINLY TAKE PLACE THROUGH AN INTRAMOLECULAR BECKMANN- TYPE REARRANGEMENT AND OTHER ORGANOPHOSPHOROUS PEPTIDES. IN THIS RESEARCH METHOD WERE DEVELOPED FOR THE ISOLATION OF PEPTICIDE RESIDUES FROM PLANT PRODUCTS AND FOR THE OPTIMIZATION OF HPLC SYSTEMS (NORMAL ADREVERSE PHASE). FOR THE OPTIMIZATION OF HPLC, TERNARY MOBILE PHASES WERE USED ACCORDING TOTHEIR SNYDER SOLVENT SELECTIVITY PARAMETERS. IN VITRO AND IN VIVO DEGRADATION OF THE COMPOUND IN PLANT PRODUCTS WAS ALSO STUDIED AND DIFFERENCES IN RESIDUE BEHAVIOUR AMONG PLANT SPECIES WERE INVESTIGATED AND ATTRIBUTED TO DIFFERENT MORPHOLOGICALLY AND PHYSICOCHEMICALLY ARTICLES AND/OR TO THE DIFFERENT BIOCHEMICAL CHARACTER OF THE FRUIT. .","abstract_html":"IN THIS DISSERTATION, THE STABILITY AND THE RESIDUE BEHAVIOUR OF THE NEW (CURRENTLY UNDER STUDY) INSECTICIDE "DIETHYL PHOSPHORIC ESTER OF THE DICYCLOPROPYLOKETOXIME" WAS INVESTIGATED IN RELATION WITH THE STRUCTURAL ORIGINALITY OF THE COMPOUND. THE CHEMICAL REACTIONS OF THE ESTER, MAINLY TAKE PLACE THROUGH AN INTRAMOLECULAR BECKMANN- TYPE REARRANGEMENT AND OTHER ORGANOPHOSPHOROUS PEPTIDES. IN THIS RESEARCH METHOD WERE DEVELOPED FOR THE ISOLATION OF PEPTICIDE RESIDUES FROM PLANT PRODUCTS AND FOR THE OPTIMIZATION OF HPLC SYSTEMS (NORMAL ADREVERSE PHASE). FOR THE OPTIMIZATION OF HPLC, TERNARY MOBILE PHASES WERE USED ACCORDING TOTHEIR SNYDER SOLVENT SELECTIVITY PARAMETERS. IN VITRO AND IN VIVO DEGRADATION OF THE COMPOUND IN PLANT PRODUCTS WAS ALSO STUDIED AND DIFFERENCES IN RESIDUE BEHAVIOUR AMONG PLANT SPECIES WERE INVESTIGATED AND ATTRIBUTED TO DIFFERENT MORPHOLOGICALLY AND PHYSICOCHEMICALLY ARTICLES AND/OR TO THE DIFFERENT BIOCHEMICAL CHARACTER OF THE FRUIT. .","abstract_has_math":false,"creators":["Μιχαηλίδου-Καννά, Στέλλα"],"institution":"Εθνικό και Καποδιστριακό Πανεπιστήμιο Αθηνών (ΕΚΠΑ)","degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":[],"advisors":[],"committee_chairs":[],"committee_members":[],"year":1987,"date_issued":"1987","date_published":"1987","updated_at":"2026-07-24T02:25:21Z","subjects":["Beckmann rearrangement","ORGANOPHOSPHOROUS ESTERS","PESTICIDESDEGRADATION CURVES","PHOSPHOROUS ESTERS OF OXIMES","STABILITY OF PESTICIDES","ΚΑΜΠΥΛΕΣ ΥΠΟΒΙΒΑΣΜΟΥ ΦΥΤΟΦΑΡΜΑΚΩΝ","ΜΕΤΑΘΕΣΗ BECKMANN","ΟΞΙΜΟΦΩΣΦΟΡΙΚΟΙ ΕΣΤΕΡΕΣ","ΟΡΓΑΝΟΦΩΣΦΟΡΙΚΟΙ ΕΣΤΕΡΕΣ","ΣΤΑΘΕΡΟΤΗΤΑ ΦΥΤΟΦΑΡΜΑΚΩΝ","Φυσικές Επιστήμες","Natural Sciences","Χημεία","Chemical Sciences"],"languages":["gre"],"rights":[],"rights_urls":[],"identifier_entries":[{"key":"dc:identifier","label":"Identifier","values":["10.12681/eadd/0583"],"render_values":[{"text":"10.12681/eadd/0583","href":"https://doi.org/10.12681/eadd/0583","code":true}]}]},"links":{"outbound_url":"http://hdl.handle.net/10442/hedi/0583","outbound_label":"Handle","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:creator","label":"Author","values":["Μιχαηλίδου-Καννά, Στέλλα"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["1987"]},{"key":"dc:publisher","label":"Institution","values":["Εθνικό και Καποδιστριακό Πανεπιστήμιο Αθηνών (ΕΚΠΑ)","National and Kapodistrian University of Athens"]},{"key":"dc:type","label":"Dc Type","values":["PhD Thesis"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Beckmann rearrangement","ORGANOPHOSPHOROUS ESTERS","PESTICIDESDEGRADATION CURVES","PHOSPHOROUS ESTERS OF OXIMES","STABILITY OF PESTICIDES","ΚΑΜΠΥΛΕΣ ΥΠΟΒΙΒΑΣΜΟΥ ΦΥΤΟΦΑΡΜΑΚΩΝ","ΜΕΤΑΘΕΣΗ BECKMANN","ΟΞΙΜΟΦΩΣΦΟΡΙΚΟΙ ΕΣΤΕΡΕΣ","ΟΡΓΑΝΟΦΩΣΦΟΡΙΚΟΙ ΕΣΤΕΡΕΣ","ΣΤΑΘΕΡΟΤΗΤΑ ΦΥΤΟΦΑΡΜΑΚΩΝ","Φυσικές Επιστήμες","Natural Sciences","Χημεία","Chemical Sciences"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["gre"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["10.12681/eadd/0583","http://hdl.handle.net/10442/hedi/0583"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["IN THIS DISSERTATION, THE STABILITY AND THE RESIDUE BEHAVIOUR OF THE NEW (CURRENTLY UNDER STUDY) INSECTICIDE \"DIETHYL PHOSPHORIC ESTER OF THE DICYCLOPROPYLOKETOXIME\" WAS INVESTIGATED IN RELATION WITH THE STRUCTURAL ORIGINALITY OF THE COMPOUND. THE CHEMICAL REACTIONS OF THE ESTER, MAINLY TAKE PLACE THROUGH AN INTRAMOLECULAR BECKMANN- TYPE REARRANGEMENT AND OTHER ORGANOPHOSPHOROUS PEPTIDES. IN THIS RESEARCH METHOD WERE DEVELOPED FOR THE ISOLATION OF PEPTICIDE RESIDUES FROM PLANT PRODUCTS AND FOR THE OPTIMIZATION OF HPLC SYSTEMS (NORMAL ADREVERSE PHASE). FOR THE OPTIMIZATION OF HPLC, TERNARY MOBILE PHASES WERE USED ACCORDING TOTHEIR SNYDER SOLVENT SELECTIVITY PARAMETERS. IN VITRO AND IN VIVO DEGRADATION OF THE COMPOUND IN PLANT PRODUCTS WAS ALSO STUDIED AND DIFFERENCES IN RESIDUE BEHAVIOUR AMONG PLANT SPECIES WERE INVESTIGATED AND ATTRIBUTED TO DIFFERENT MORPHOLOGICALLY AND PHYSICOCHEMICALLY ARTICLES AND/OR TO THE DIFFERENT BIOCHEMICAL CHARACTER OF THE FRUIT. .","ΣΤΗ ΔΙΑΤΡΙΒΗ ΑΥΤΗ ΜΕΛΕΤΗΘΗΚΕ Η ΥΠΟΛΕΙΜΜΑΤΙΚΟΤΗΤΑ ΚΑΙ ΣΤΑΘΕΡΟΤΗΤΑ ΤΟΥ ΝΕΟΥ (ΥΠΟ ΔΟΚΙΜΑΣΙΑ) ΕΝΤΟΜΟΚΤΟΝΟΥ \"ΔΙΑΙΘΥΛΟΦΩΣΦΟΡΙΚΟΣ ΕΣΤΕΡΑΣ\" ΤΗΣ ΔΙΚΥΚΛΟΠΡΟΠΥΛΟΚΕΤΟΞΙΜΗΣ ΣΕ ΣΧΕΣΗ ΜΕ ΤΗΝ ΔΟΜΙΚΗ ΙΔΙΟΜΟΡΦΙΑ ΠΟΥ ΠΑΡΟΥΣΙΑΖΕΙ ΕΝΕΚΑ ΤΗΣ ΠΑΡΟΥΣΙΑΣ ΚΑΙ ΘΕΣΗΣ ΤΩΝ ΔΥΟ ΚΥΚΛΟΠΡΟΠΑΝΙΚΩΝ ΔΑΚΤΥΛΙΩΝ ΣΤΟ ΜΟΡΙΟ ΟΞΙΜΟΦΩΣΦΟΡΙΚΟΥ ΕΣΤΕΡΑ. ΛΟΓΩ ΤΗΣΔΟΜΗΣ ΑΥΤΗΣ, ΟΙ ΑΝΤΙΔΡΑΣΕΙΣ ΤΗΣ ΕΝΩΣΗΣ ΛΑΜΒΑΝΕΙ ΧΩΡΑ ΚΥΡΙΩΣ ΜΕΣΩ ΕΝΔΟΜΟΡΙΑΚΟΥ ΤΥΠΟΥ BECKMANN ΜΕΤΑΘΕΣΗΣ 'Η ΕΝΩΣΗΣ ΧΑΡΑΚΤΗΡΙΖΕΤΑΙ ΑΠΟ ΜΙΚΡΟ ΧΡΟΝΟ ΗΜΙΖΩΗΣ (+1/2) ΚΑΙ ΜΕΙΩΜΕΝΗ ΥΠΟΛΕΙΜΜΑΤΙΚΟΤΗΤΑ ΣΕ ΣΥΓΚΡΙΣΗ ΜΕ ΑΛΛΟΥΣ ΟΡΓΑΝΟΦΩΣΦΟΡΙΚΟΥΣ ΕΣΤΕΡΕΣ . ΣΤΗΝ ΕΡΓΑΣΙΑ ΑΥΤΗ ΑΝΑΠΤΥΧΘΗΚΑΝ ΜΕΘΟΔΟΙ ΑΠΟΜΟΝΩΣΗΣ ΤΗΣ ΕΝΩΣΗΣ ΑΠΟ ΦΥΤΙΚΑ ΠΡΟΙΟΝΤΑ ΚΑΙ ΕΓΙΝΕ ΑΡΙΣΤΟΠΟΙΗΣΗ ΣΥΝΘΗΜΑΤΩΝ HPLC ΚΑΝΟΝΙΚΗΣ ΚΑΙ ΑΝΤΙΣΤΡΟΦΗΣ ΦΑΣΗΣ ΜΕΧΡΗΣΗ ΤΡΙΑΔΙΚΩΝ ΔΙΑΛΥΜΑΤΩΝ ΕΚΛΟΥΣΗΣ ΚΑΙ ΤΩΝ ΠΑΡΑΜΕΤΡΩΝ ΕΚΛΕΚΤΙΚΟΤΗΤΑΣ ΤΩΝ ΔΙΑΛΥΤΩΝ ΚΑΤΑ SNYDER. ΜΕΛΕΤΗΘΗΚΕ ΕΠΙΣΗΣ Ο \"ΙN VITRO\" KAI \"IN VIVO\" ΥΠΟΒΙΒΑΣΜΟΣ ΤΗΣ ΕΝΩΣΗΣ ΣΕ 2 ΦΥΤΙΚΑ ΠΡΟΙΟΝΤΑ ΚΑΙ Η ΔΙΑΦΟΡΟΠΟΙΗΣΗ ΤΗΣ ΥΠΟΛΕΙΜΜΑΤΙΚΟΤΗΤΑΣ ΑΠΟΤΕΛΕΣΜΑ ΦΥΣΙΚΟΧΗΜΙΚΩΝ ΚΑΙ ΜΟΡΦΟΛΟΓΙΚΩΝ ΔΙΑΦΟΡΩΝ ΤΗΣ ΕΞΩΤΕΡΙΚΗΣ ΕΠΙΔΕΡΜΙΔΑΣ ΤΩΝ ΦΥΤΙΚΩΝ ΠΡΟΙΟΝΤΩΝ 'Η/ΚΑΙ ΤΩΝ ΒΙΟΜΗΧΑΝΙΚΩΝ ΔΙΑΦΟΡΩΝ ΤΩΝ ΚΑΡΠΩΝ."]},{"key":"dc:title","label":"Title","values":["ΜΕΛΕΤΗ ΤΗΣ ΣΤΑΘΕΡΟΤΗΤΑΣ ΚΑΙ ΥΠΟΛΕΙΜΜΑΤΙΚΟΤΗΤΑΣ ΤΟΥ ΝΕΟΥ ΕΝΤΟΜΟΚΤΟΝΟΥ \"ΔΙΑΙΘΥΛΟΦΩΣΦΟΡΙΚΟΣ ΕΣΤΕΡΑΣ ΤΗΣ ΔΙΚΥΚΛΟΠΡΟΠΥΛΟΚΕΤΟΞΙΜΗΣ\"","INVESTIGATION OF THE STABILITY AND THE \"RESIDUE BEHAVIOUR\" OF THE NEW INSECTICIDE \"DIETHYLPHOSPHORIC ESTER OF THE DICYCLOPROPYLOKETOXIME\""]}]}],"canonical_facts":{"dc:creator":["Μιχαηλίδου-Καννά, Στέλλα"],"dc:date":["1987"],"dc:description":["IN THIS DISSERTATION, THE STABILITY AND THE RESIDUE BEHAVIOUR OF THE NEW (CURRENTLY UNDER STUDY) INSECTICIDE \"DIETHYL PHOSPHORIC ESTER OF THE DICYCLOPROPYLOKETOXIME\" WAS INVESTIGATED IN RELATION WITH THE STRUCTURAL ORIGINALITY OF THE COMPOUND. THE CHEMICAL REACTIONS OF THE ESTER, MAINLY TAKE PLACE THROUGH AN INTRAMOLECULAR BECKMANN- TYPE REARRANGEMENT AND OTHER ORGANOPHOSPHOROUS PEPTIDES. IN THIS RESEARCH METHOD WERE DEVELOPED FOR THE ISOLATION OF PEPTICIDE RESIDUES FROM PLANT PRODUCTS AND FOR THE OPTIMIZATION OF HPLC SYSTEMS (NORMAL ADREVERSE PHASE). FOR THE OPTIMIZATION OF HPLC, TERNARY MOBILE PHASES WERE USED ACCORDING TOTHEIR SNYDER SOLVENT SELECTIVITY PARAMETERS. IN VITRO AND IN VIVO DEGRADATION OF THE COMPOUND IN PLANT PRODUCTS WAS ALSO STUDIED AND DIFFERENCES IN RESIDUE BEHAVIOUR AMONG PLANT SPECIES WERE INVESTIGATED AND ATTRIBUTED TO DIFFERENT MORPHOLOGICALLY AND PHYSICOCHEMICALLY ARTICLES AND/OR TO THE DIFFERENT BIOCHEMICAL CHARACTER OF THE FRUIT. .","ΣΤΗ ΔΙΑΤΡΙΒΗ ΑΥΤΗ ΜΕΛΕΤΗΘΗΚΕ Η ΥΠΟΛΕΙΜΜΑΤΙΚΟΤΗΤΑ ΚΑΙ ΣΤΑΘΕΡΟΤΗΤΑ ΤΟΥ ΝΕΟΥ (ΥΠΟ ΔΟΚΙΜΑΣΙΑ) ΕΝΤΟΜΟΚΤΟΝΟΥ \"ΔΙΑΙΘΥΛΟΦΩΣΦΟΡΙΚΟΣ ΕΣΤΕΡΑΣ\" ΤΗΣ ΔΙΚΥΚΛΟΠΡΟΠΥΛΟΚΕΤΟΞΙΜΗΣ ΣΕ ΣΧΕΣΗ ΜΕ ΤΗΝ ΔΟΜΙΚΗ ΙΔΙΟΜΟΡΦΙΑ ΠΟΥ ΠΑΡΟΥΣΙΑΖΕΙ ΕΝΕΚΑ ΤΗΣ ΠΑΡΟΥΣΙΑΣ ΚΑΙ ΘΕΣΗΣ ΤΩΝ ΔΥΟ ΚΥΚΛΟΠΡΟΠΑΝΙΚΩΝ ΔΑΚΤΥΛΙΩΝ ΣΤΟ ΜΟΡΙΟ ΟΞΙΜΟΦΩΣΦΟΡΙΚΟΥ ΕΣΤΕΡΑ. ΛΟΓΩ ΤΗΣΔΟΜΗΣ ΑΥΤΗΣ, ΟΙ ΑΝΤΙΔΡΑΣΕΙΣ ΤΗΣ ΕΝΩΣΗΣ ΛΑΜΒΑΝΕΙ ΧΩΡΑ ΚΥΡΙΩΣ ΜΕΣΩ ΕΝΔΟΜΟΡΙΑΚΟΥ ΤΥΠΟΥ BECKMANN ΜΕΤΑΘΕΣΗΣ 'Η ΕΝΩΣΗΣ ΧΑΡΑΚΤΗΡΙΖΕΤΑΙ ΑΠΟ ΜΙΚΡΟ ΧΡΟΝΟ ΗΜΙΖΩΗΣ (+1/2) ΚΑΙ ΜΕΙΩΜΕΝΗ ΥΠΟΛΕΙΜΜΑΤΙΚΟΤΗΤΑ ΣΕ ΣΥΓΚΡΙΣΗ ΜΕ ΑΛΛΟΥΣ ΟΡΓΑΝΟΦΩΣΦΟΡΙΚΟΥΣ ΕΣΤΕΡΕΣ . ΣΤΗΝ ΕΡΓΑΣΙΑ ΑΥΤΗ ΑΝΑΠΤΥΧΘΗΚΑΝ ΜΕΘΟΔΟΙ ΑΠΟΜΟΝΩΣΗΣ ΤΗΣ ΕΝΩΣΗΣ ΑΠΟ ΦΥΤΙΚΑ ΠΡΟΙΟΝΤΑ ΚΑΙ ΕΓΙΝΕ ΑΡΙΣΤΟΠΟΙΗΣΗ ΣΥΝΘΗΜΑΤΩΝ HPLC ΚΑΝΟΝΙΚΗΣ ΚΑΙ ΑΝΤΙΣΤΡΟΦΗΣ ΦΑΣΗΣ ΜΕΧΡΗΣΗ ΤΡΙΑΔΙΚΩΝ ΔΙΑΛΥΜΑΤΩΝ ΕΚΛΟΥΣΗΣ ΚΑΙ ΤΩΝ ΠΑΡΑΜΕΤΡΩΝ ΕΚΛΕΚΤΙΚΟΤΗΤΑΣ ΤΩΝ ΔΙΑΛΥΤΩΝ ΚΑΤΑ SNYDER. ΜΕΛΕΤΗΘΗΚΕ ΕΠΙΣΗΣ Ο \"ΙN VITRO\" KAI \"IN VIVO\" ΥΠΟΒΙΒΑΣΜΟΣ ΤΗΣ ΕΝΩΣΗΣ ΣΕ 2 ΦΥΤΙΚΑ ΠΡΟΙΟΝΤΑ ΚΑΙ Η ΔΙΑΦΟΡΟΠΟΙΗΣΗ ΤΗΣ ΥΠΟΛΕΙΜΜΑΤΙΚΟΤΗΤΑΣ ΑΠΟΤΕΛΕΣΜΑ ΦΥΣΙΚΟΧΗΜΙΚΩΝ ΚΑΙ ΜΟΡΦΟΛΟΓΙΚΩΝ ΔΙΑΦΟΡΩΝ ΤΗΣ ΕΞΩΤΕΡΙΚΗΣ ΕΠΙΔΕΡΜΙΔΑΣ ΤΩΝ ΦΥΤΙΚΩΝ ΠΡΟΙΟΝΤΩΝ 'Η/ΚΑΙ ΤΩΝ ΒΙΟΜΗΧΑΝΙΚΩΝ ΔΙΑΦΟΡΩΝ ΤΩΝ ΚΑΡΠΩΝ."],"dc:identifier":["10.12681/eadd/0583","http://hdl.handle.net/10442/hedi/0583"],"dc:language":["gre"],"dc:publisher":["Εθνικό και Καποδιστριακό Πανεπιστήμιο Αθηνών (ΕΚΠΑ)","National and Kapodistrian University of Athens"],"dc:subject":["Beckmann rearrangement","ORGANOPHOSPHOROUS ESTERS","PESTICIDESDEGRADATION CURVES","PHOSPHOROUS ESTERS OF OXIMES","STABILITY OF PESTICIDES","ΚΑΜΠΥΛΕΣ ΥΠΟΒΙΒΑΣΜΟΥ ΦΥΤΟΦΑΡΜΑΚΩΝ","ΜΕΤΑΘΕΣΗ BECKMANN","ΟΞΙΜΟΦΩΣΦΟΡΙΚΟΙ ΕΣΤΕΡΕΣ","ΟΡΓΑΝΟΦΩΣΦΟΡΙΚΟΙ ΕΣΤΕΡΕΣ","ΣΤΑΘΕΡΟΤΗΤΑ ΦΥΤΟΦΑΡΜΑΚΩΝ","Φυσικές Επιστήμες","Natural Sciences","Χημεία","Chemical Sciences"],"dc:title":["ΜΕΛΕΤΗ ΤΗΣ ΣΤΑΘΕΡΟΤΗΤΑΣ ΚΑΙ ΥΠΟΛΕΙΜΜΑΤΙΚΟΤΗΤΑΣ ΤΟΥ ΝΕΟΥ ΕΝΤΟΜΟΚΤΟΝΟΥ \"ΔΙΑΙΘΥΛΟΦΩΣΦΟΡΙΚΟΣ ΕΣΤΕΡΑΣ ΤΗΣ ΔΙΚΥΚΛΟΠΡΟΠΥΛΟΚΕΤΟΞΙΜΗΣ\"","INVESTIGATION OF THE STABILITY AND THE \"RESIDUE BEHAVIOUR\" OF THE NEW INSECTICIDE \"DIETHYLPHOSPHORIC ESTER OF THE DICYCLOPROPYLOKETOXIME\""],"dc:type":["PhD Thesis"]},"updated_at":"2026-07-24T02:25:21Z"}