{"id":{"repo_id":"greece","oai_identifier":"oai:10442/0581"},"canonical_url":"https://search.dev.ndltd.org/etd/greece/oai:10442/0581","repository":{"repo_id":"greece","name":"Greek National Archive of PhD Theses","base_url":"https://phdtheses.ekt.gr/eadd_oai/request"},"display":{"title":"ΑΝΤΙΔΡΑΣΕΙΣ ΕΝΩΣΕΩΝ ΜΕ ΠΟΛΛΑΠΛΟΥΣ ΔΕΣΜΟΥΣ ΜΟΛΥΒΔΑΙΝΙΟΥ-ΜΟΛΥΒΔΑΙΝΙΟΥ","abstract":"A KINETIC AND MECHANISTIC STUDY OF THE PROTON OXIDATION ADDITION REACTION OF MO2CL8 4- TO MO2CL8H3- HAS BEEN CARRIED OUT IN 6M HCL . THE KINETICS ARE FIRST ORDER IN THE CONCENTRATION OF THE ACID AND FIRST ORDER IN THE MO2 4+ REACTANT. THE ACTIVATION ENERGY IN 6M HCL IS 49,3 KJ MOLE-1. THE RATE IS STRONGLY AFFECTED BY AXIAL COORDINATION AT LOWER (< 6M HCL) ACID CONCENTRATIONS THE REACTION IS COMPLICATED BY HYDROLYSIS. (SHORTENED)","abstract_html":"A KINETIC AND MECHANISTIC STUDY OF THE PROTON OXIDATION ADDITION REACTION OF MO2CL8 4- TO MO2CL8H3- HAS BEEN CARRIED OUT IN 6M HCL . THE KINETICS ARE FIRST ORDER IN THE CONCENTRATION OF THE ACID AND FIRST ORDER IN THE MO2 4+ REACTANT. THE ACTIVATION ENERGY IN 6M HCL IS 49,3 KJ MOLE-1. THE RATE IS STRONGLY AFFECTED BY AXIAL COORDINATION AT LOWER (&lt; 6M HCL) ACID CONCENTRATIONS THE REACTION IS COMPLICATED BY HYDROLYSIS. (SHORTENED)","abstract_has_math":false,"creators":["Kravaritou, Myrsini","Κραββαρίτου, Μυρσίνη"],"institution":"National and Kapodistrian University of Athens","degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":[],"advisors":[],"committee_chairs":[],"committee_members":[],"year":1987,"date_issued":"1987","date_published":"1987","updated_at":"2026-07-24T02:25:21Z","subjects":["ΑΝΑΓΩΓΙΚΕΣ ΑΝΤΙΔΡΑΣΕΙΣ CR","Οξειδωτική προσθήκη","ΠΟΛΛΑΠΛΟΙ ΔΕΣΜΟΙ ΜΟΛΥΒΔΑΙΝΙΟΥ-ΜΟΛΥΒΔΑΙΝΙΟΥ","MOLYBDENUM-MOLYBDENUM MULTIPLE BONDS","OXIDATION ADDITION","REDUCTION REACTIONS CR","Φυσικές Επιστήμες","Χημεία","Natural Sciences","Chemical Sciences"],"languages":["gre"],"rights":[],"rights_urls":[],"identifier_entries":[{"key":"dc:identifier","label":"Identifier","values":["10.12681/eadd/0581"],"render_values":[{"text":"10.12681/eadd/0581","href":"https://doi.org/10.12681/eadd/0581","code":true}]}]},"links":{"outbound_url":"http://hdl.handle.net/10442/hedi/0581","outbound_label":"Handle","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:creator","label":"Author","values":["Kravaritou, Myrsini","Κραββαρίτου, Μυρσίνη"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["1987"]},{"key":"dc:publisher","label":"Institution","values":["National and Kapodistrian University of Athens","Εθνικό και Καποδιστριακό Πανεπιστήμιο Αθηνών (ΕΚΠΑ)"]},{"key":"dc:type","label":"Dc Type","values":["PhD Thesis"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["ΑΝΑΓΩΓΙΚΕΣ ΑΝΤΙΔΡΑΣΕΙΣ CR","Οξειδωτική προσθήκη","ΠΟΛΛΑΠΛΟΙ ΔΕΣΜΟΙ ΜΟΛΥΒΔΑΙΝΙΟΥ-ΜΟΛΥΒΔΑΙΝΙΟΥ","MOLYBDENUM-MOLYBDENUM MULTIPLE BONDS","OXIDATION ADDITION","REDUCTION REACTIONS CR","Φυσικές Επιστήμες","Χημεία","Natural Sciences","Chemical Sciences"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["gre"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["10.12681/eadd/0581","http://hdl.handle.net/10442/hedi/0581"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["A KINETIC AND MECHANISTIC STUDY OF THE PROTON OXIDATION ADDITION REACTION OF MO2CL8 4- TO MO2CL8H3- HAS BEEN CARRIED OUT IN 6M HCL . THE KINETICS ARE FIRST ORDER IN THE CONCENTRATION OF THE ACID AND FIRST ORDER IN THE MO2 4+ REACTANT. THE ACTIVATION ENERGY IN 6M HCL IS 49,3 KJ MOLE-1. THE RATE IS STRONGLY AFFECTED BY AXIAL COORDINATION AT LOWER (< 6M HCL) ACID CONCENTRATIONS THE REACTION IS COMPLICATED BY HYDROLYSIS. (SHORTENED)","ΕΓΙΝΑΝ ΚΙΝΗΤΙΚΕΣ ΜΕΤΡΗΣΕΙΣ ΚΑΙ ΜΕΛΕΤΗ ΤΟΥ ΜΗΧΑΝΙΣΜΟΥ ΤΗΣ ΑΝΤΙΔΡΑΣΗΣ ΟΞΕΙΔΩΤΙΚΗΣΠΡΟΣΘΗΚΗΣ ΠΡΩΤΟΝΙΟΥ ΣΤΟΝ ΤΕΤΡΑΠΛΟ ΔΕΣΜΟ ΤΟΥ ΑΝΙΟΝΤΟΣ MO2CL8 4- ΠΡΟΣ MO2CL8H3-.ΟΙ ΚΙΝΗΤΙΚΕΣ ΜΕΤΡΗΣΕΙΣ ΣΕ 6-ΙΟΜ HCL ΔΕΙΧΝΟΥΝ ΑΝΤΙΔΡΑΣΗ ΠΡΩΤΗΣ ΤΑΞΕΩΣ ΩΣ ΠΡΟΣ ΤΗ ΣΥΓΚΕΝΤΡΩΣΗ ΤΟΥ ΟΞΕΟΣ ΚΑΙ ΕΠΙΣΗΣ ΠΡΩΤΗΣ ΤΑΞΕΩΣ ΩΣ ΠΡΟΣ ΤΟ ΑΝΤΙΔΡΟΝ MO24+. Η ΕΝΕΡΓΕΙΑ ΕΝΕΡΓΟΠΟΙΗΣΗΣ ΣΕ 6Μ HCL ΕΙΝΑΙ 49,3 KJ MOLE-1. Η ΤΑΧΥΤΗΤΑ ΕΞΑΡΤΑΤΑΙ ΑΠΟ ΤΟΥΣ ΑΞΟΝΙΚΟΥΣ ΥΠΟΚΑΤΑΣΤΑΤΕΣ ΣΕ ΜΙΚΡΟΤΕΡΕΣ ΣΥΓΚΕΝΤΡΩΣΕΙΣ ΟΞΕΟΣ (6M HCL) Η ΑΝΤΙΔΡΑΣΗ ΕΙΝΑΙ ΠΕΡΙΠΛΟΚΗ ΛΟΓΩ ΥΔΡΟΛΥΣΕΩΣ. (ΠΕΡΙΚΟΠΗ)"]},{"key":"dc:title","label":"Title","values":["ΑΝΤΙΔΡΑΣΕΙΣ ΕΝΩΣΕΩΝ ΜΕ ΠΟΛΛΑΠΛΟΥΣ ΔΕΣΜΟΥΣ ΜΟΛΥΒΔΑΙΝΙΟΥ-ΜΟΛΥΒΔΑΙΝΙΟΥ","REACTIONS OF COMPOUNDS WITH MOLYBDENUM-MOLYBDENUM MULTIPLE BONDS"]}]}],"canonical_facts":{"dc:creator":["Kravaritou, Myrsini","Κραββαρίτου, Μυρσίνη"],"dc:date":["1987"],"dc:description":["A KINETIC AND MECHANISTIC STUDY OF THE PROTON OXIDATION ADDITION REACTION OF MO2CL8 4- TO MO2CL8H3- HAS BEEN CARRIED OUT IN 6M HCL . THE KINETICS ARE FIRST ORDER IN THE CONCENTRATION OF THE ACID AND FIRST ORDER IN THE MO2 4+ REACTANT. THE ACTIVATION ENERGY IN 6M HCL IS 49,3 KJ MOLE-1. THE RATE IS STRONGLY AFFECTED BY AXIAL COORDINATION AT LOWER (< 6M HCL) ACID CONCENTRATIONS THE REACTION IS COMPLICATED BY HYDROLYSIS. (SHORTENED)","ΕΓΙΝΑΝ ΚΙΝΗΤΙΚΕΣ ΜΕΤΡΗΣΕΙΣ ΚΑΙ ΜΕΛΕΤΗ ΤΟΥ ΜΗΧΑΝΙΣΜΟΥ ΤΗΣ ΑΝΤΙΔΡΑΣΗΣ ΟΞΕΙΔΩΤΙΚΗΣΠΡΟΣΘΗΚΗΣ ΠΡΩΤΟΝΙΟΥ ΣΤΟΝ ΤΕΤΡΑΠΛΟ ΔΕΣΜΟ ΤΟΥ ΑΝΙΟΝΤΟΣ MO2CL8 4- ΠΡΟΣ MO2CL8H3-.ΟΙ ΚΙΝΗΤΙΚΕΣ ΜΕΤΡΗΣΕΙΣ ΣΕ 6-ΙΟΜ HCL ΔΕΙΧΝΟΥΝ ΑΝΤΙΔΡΑΣΗ ΠΡΩΤΗΣ ΤΑΞΕΩΣ ΩΣ ΠΡΟΣ ΤΗ ΣΥΓΚΕΝΤΡΩΣΗ ΤΟΥ ΟΞΕΟΣ ΚΑΙ ΕΠΙΣΗΣ ΠΡΩΤΗΣ ΤΑΞΕΩΣ ΩΣ ΠΡΟΣ ΤΟ ΑΝΤΙΔΡΟΝ MO24+. Η ΕΝΕΡΓΕΙΑ ΕΝΕΡΓΟΠΟΙΗΣΗΣ ΣΕ 6Μ HCL ΕΙΝΑΙ 49,3 KJ MOLE-1. Η ΤΑΧΥΤΗΤΑ ΕΞΑΡΤΑΤΑΙ ΑΠΟ ΤΟΥΣ ΑΞΟΝΙΚΟΥΣ ΥΠΟΚΑΤΑΣΤΑΤΕΣ ΣΕ ΜΙΚΡΟΤΕΡΕΣ ΣΥΓΚΕΝΤΡΩΣΕΙΣ ΟΞΕΟΣ (6M HCL) Η ΑΝΤΙΔΡΑΣΗ ΕΙΝΑΙ ΠΕΡΙΠΛΟΚΗ ΛΟΓΩ ΥΔΡΟΛΥΣΕΩΣ. (ΠΕΡΙΚΟΠΗ)"],"dc:identifier":["10.12681/eadd/0581","http://hdl.handle.net/10442/hedi/0581"],"dc:language":["gre"],"dc:publisher":["National and Kapodistrian University of Athens","Εθνικό και Καποδιστριακό Πανεπιστήμιο Αθηνών (ΕΚΠΑ)"],"dc:subject":["ΑΝΑΓΩΓΙΚΕΣ ΑΝΤΙΔΡΑΣΕΙΣ CR","Οξειδωτική προσθήκη","ΠΟΛΛΑΠΛΟΙ ΔΕΣΜΟΙ ΜΟΛΥΒΔΑΙΝΙΟΥ-ΜΟΛΥΒΔΑΙΝΙΟΥ","MOLYBDENUM-MOLYBDENUM MULTIPLE BONDS","OXIDATION ADDITION","REDUCTION REACTIONS CR","Φυσικές Επιστήμες","Χημεία","Natural Sciences","Chemical Sciences"],"dc:title":["ΑΝΤΙΔΡΑΣΕΙΣ ΕΝΩΣΕΩΝ ΜΕ ΠΟΛΛΑΠΛΟΥΣ ΔΕΣΜΟΥΣ ΜΟΛΥΒΔΑΙΝΙΟΥ-ΜΟΛΥΒΔΑΙΝΙΟΥ","REACTIONS OF COMPOUNDS WITH MOLYBDENUM-MOLYBDENUM MULTIPLE BONDS"],"dc:type":["PhD Thesis"]},"updated_at":"2026-07-24T02:25:21Z"}