{"id":{"repo_id":"greece","oai_identifier":"oai:10442/0560"},"canonical_url":"https://search.dev.ndltd.org/etd/greece/oai:10442/0560","repository":{"repo_id":"greece","name":"Greek National Archive of PhD Theses","base_url":"https://phdtheses.ekt.gr/eadd_oai/request"},"display":{"title":"ΕΝΔΟΜΟΡΙΑΚΗ ΦΩΤΟΚΥΚΛΟΠΟΙΗΣΗ ΤΗΣ ΚΑΡΒΟΝΗΣ ΠΡΟΣ ΚΑΡΒΟΝΟΚΑΜΦΟΡΑ","abstract":"THE QUANTUM YIELDS OF THE PHOTOCYCLOADDITION OF CARVONE (I) TO CARVONECAMPHOR (2) (TYPE) HAVE BEEN DETERMINED IN NON POLAR AND POLAR SOLVENTS, UNDER NITROGEN AND IN AIR-EQUILIBRATED SOLUTIONS. QUENCHING BY OXYGEN HAS BEEN OBSERVED ONLY IN NON POLAR SOLVENTS, BENZENE 01 --> 2=0.0025 UNDER NITROGEN AND 0.0012 IN AIR-EQUILIBRATED SOLUTIONS. SENSITIZATION EXPERIMENTS WITH BENZOPHENONE HAVE SHOWNALSO THAT THE REACTION IN BENZENE MUST PROCEED BY TRIPLET SENSITIZATION. A MARKED ENHANCEMENT OF THE QUANTUM YIELD HAS BEEN OBSERVED IN ETOH-H2O MIXTURES COMPARED TO THAT IN BENZENE AND IN ETOH, 01 --> 2=0.085 IN ETOH-H2O(2:8) & 0. 0088IN ETOH. INVOLVEMENT OF DIFFERENT EXCITED STATES IS SUGGESTED FOR THE PHOTOCYCLIZATION OF CARVONE IN NON POLAR (A TRIPLET STATE) AND IN HYDROXYLIC SOLVENTS (N,N* SINGLET STATE) ON THE BASIS OF THE RESULTS AND THE EFFECT OF WATER ON THE ABSORPTION SPECTRUM OF CARVONE. THE INTRAMOLECULAR PHOTOCYCLOADDITION OF CARVONE TO CARVONECAMPHOR HAS BEEN PROPOSED AMONG OTHER REACTIONS AS A POSSIBLE SYSTEM FOR SOLAR ENERGY STORAGE. TO THIS DIRECTION, THE REVERSE REACTION IN THE DARKWAS ACHIEVED FOR THE FIRST TIME BY USING RH2(CO)4CL2 AS A CATALYST.","abstract_html":"THE QUANTUM YIELDS OF THE PHOTOCYCLOADDITION OF CARVONE (I) TO CARVONECAMPHOR (2) (TYPE) HAVE BEEN DETERMINED IN NON POLAR AND POLAR SOLVENTS, UNDER NITROGEN AND IN AIR-EQUILIBRATED SOLUTIONS. QUENCHING BY OXYGEN HAS BEEN OBSERVED ONLY IN NON POLAR SOLVENTS, BENZENE 01 --> 2=0.0025 UNDER NITROGEN AND 0.0012 IN AIR-EQUILIBRATED SOLUTIONS. SENSITIZATION EXPERIMENTS WITH BENZOPHENONE HAVE SHOWNALSO THAT THE REACTION IN BENZENE MUST PROCEED BY TRIPLET SENSITIZATION. A MARKED ENHANCEMENT OF THE QUANTUM YIELD HAS BEEN OBSERVED IN ETOH-H2O MIXTURES COMPARED TO THAT IN BENZENE AND IN ETOH, 01 --> 2=0.085 IN ETOH-H2O(2:8) & 0. 0088IN ETOH. INVOLVEMENT OF DIFFERENT EXCITED STATES IS SUGGESTED FOR THE PHOTOCYCLIZATION OF CARVONE IN NON POLAR (A TRIPLET STATE) AND IN HYDROXYLIC SOLVENTS (N,N* SINGLET STATE) ON THE BASIS OF THE RESULTS AND THE EFFECT OF WATER ON THE ABSORPTION SPECTRUM OF CARVONE. THE INTRAMOLECULAR PHOTOCYCLOADDITION OF CARVONE TO CARVONECAMPHOR HAS BEEN PROPOSED AMONG OTHER REACTIONS AS A POSSIBLE SYSTEM FOR SOLAR ENERGY STORAGE. TO THIS DIRECTION, THE REVERSE REACTION IN THE DARKWAS ACHIEVED FOR THE FIRST TIME BY USING RH2(CO)4CL2 AS A CATALYST.","abstract_has_math":false,"creators":["Τσίπη, Δέσποινα"],"institution":"Εθνικό και Καποδιστριακό Πανεπιστήμιο Αθηνών (ΕΚΠΑ)","degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":[],"advisors":[],"committee_chairs":[],"committee_members":[],"year":1987,"date_issued":"1987","date_published":"1987","updated_at":"2026-07-24T02:25:21Z","subjects":["ABSORPTION SPECTRA, EMISSION","FLASH PHOTOLYSIS","PHOTOCHEMICAL PRODUCTS","QUANTUM YIELD MEASUREMENTS","SENSITIZATION, BENROPHENONE","SOLAR EMERGY STORAGE","THE REVERSE REACTION","ΑΠΟΘΗΚΕΥΣΗ ΗΛΙΑΚΗΣ ΕΝΕΡΓΕΙΑΣ","ΜΕΤΡΗΣΕΙΣ ΚΒΑΝΤΙΚΗΣ ΑΠΟΔΟΣΗΣ","ΠΑΛΜΙΚΗ ΦΩΤΟΛΥΣΗ","ΦΑΣΜΑΤΑ ΑΠΟΡΡΟΦΗΣΗΣ, ΕΚΠΟΜΠΗΣ","Φυσικές Επιστήμες","Natural Sciences","Χημεία","Chemical Sciences"],"languages":["gre"],"rights":[],"rights_urls":[],"identifier_entries":[{"key":"dc:identifier","label":"Identifier","values":["10.12681/eadd/0560"],"render_values":[{"text":"10.12681/eadd/0560","href":"https://doi.org/10.12681/eadd/0560","code":true}]}]},"links":{"outbound_url":"http://hdl.handle.net/10442/hedi/0560","outbound_label":"Handle","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:creator","label":"Author","values":["Τσίπη, Δέσποινα"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["1987"]},{"key":"dc:publisher","label":"Institution","values":["Εθνικό και Καποδιστριακό Πανεπιστήμιο Αθηνών (ΕΚΠΑ)","National and Kapodistrian University of Athens"]},{"key":"dc:type","label":"Dc Type","values":["PhD Thesis"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["ABSORPTION SPECTRA, EMISSION","FLASH PHOTOLYSIS","PHOTOCHEMICAL PRODUCTS","QUANTUM YIELD MEASUREMENTS","SENSITIZATION, BENROPHENONE","SOLAR EMERGY STORAGE","THE REVERSE REACTION","ΑΠΟΘΗΚΕΥΣΗ ΗΛΙΑΚΗΣ ΕΝΕΡΓΕΙΑΣ","ΜΕΤΡΗΣΕΙΣ ΚΒΑΝΤΙΚΗΣ ΑΠΟΔΟΣΗΣ","ΠΑΛΜΙΚΗ ΦΩΤΟΛΥΣΗ","ΦΑΣΜΑΤΑ ΑΠΟΡΡΟΦΗΣΗΣ, ΕΚΠΟΜΠΗΣ","Φυσικές Επιστήμες","Natural Sciences","Χημεία","Chemical Sciences"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["gre"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["10.12681/eadd/0560","http://hdl.handle.net/10442/hedi/0560"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["THE QUANTUM YIELDS OF THE PHOTOCYCLOADDITION OF CARVONE (I) TO CARVONECAMPHOR (2) (TYPE) HAVE BEEN DETERMINED IN NON POLAR AND POLAR SOLVENTS, UNDER NITROGEN AND IN AIR-EQUILIBRATED SOLUTIONS. QUENCHING BY OXYGEN HAS BEEN OBSERVED ONLY IN NON POLAR SOLVENTS, BENZENE 01 --> 2=0.0025 UNDER NITROGEN AND 0.0012 IN AIR-EQUILIBRATED SOLUTIONS. SENSITIZATION EXPERIMENTS WITH BENZOPHENONE HAVE SHOWNALSO THAT THE REACTION IN BENZENE MUST PROCEED BY TRIPLET SENSITIZATION. A MARKED ENHANCEMENT OF THE QUANTUM YIELD HAS BEEN OBSERVED IN ETOH-H2O MIXTURES COMPARED TO THAT IN BENZENE AND IN ETOH, 01 --> 2=0.085 IN ETOH-H2O(2:8) & 0. 0088IN ETOH. INVOLVEMENT OF DIFFERENT EXCITED STATES IS SUGGESTED FOR THE PHOTOCYCLIZATION OF CARVONE IN NON POLAR (A TRIPLET STATE) AND IN HYDROXYLIC SOLVENTS (N,N* SINGLET STATE) ON THE BASIS OF THE RESULTS AND THE EFFECT OF WATER ON THE ABSORPTION SPECTRUM OF CARVONE. THE INTRAMOLECULAR PHOTOCYCLOADDITION OF CARVONE TO CARVONECAMPHOR HAS BEEN PROPOSED AMONG OTHER REACTIONS AS A POSSIBLE SYSTEM FOR SOLAR ENERGY STORAGE. TO THIS DIRECTION, THE REVERSE REACTION IN THE DARKWAS ACHIEVED FOR THE FIRST TIME BY USING RH2(CO)4CL2 AS A CATALYST.","ΣΤΗΝ ΕΡΓΑΣΙΑ ΑΤΥΗ ΜΕΛΕΤΗΘΗΚΕ Η ΑΝΤΙΔΡΑΣΗ ΦΩΤΟΚΥΚΛΟΠΟΙΗΣΗΣ ΤΗΣ ΚΑΡΒΟΝΗΣ (1) ΠΡΟΣΚΑΡΒΟΝΟΚΑΜΦΟΡΑ (2) (ΤΥΠΟΣ). Η ΜΕΛΕΤΗ ΤΗΣ (1) -- > (2) ΕΧΕΙ ΠΡΑΚΤΙΚΕΣ ΠΡΟΕΚΤΑΣΕΙΣ ΣΤΟ ΠΕΔΙΟ \"ΜΕΤΑΤΡΟΠΗΣ ΚΑΙ ΑΠΟΘΗΚΕΥΣΕΩΣ ΤΗΣ ΗΛΙΑΚΗΣ ΕΝΕΡΓΕΙΑΣ\". ΜΕΛΕΤΗΘΗΚΑΝ ΤΑ ΕΞΗΣ Α) ΟΙ ΚΒΑΝΤΙΚΕΣ ΑΠΟΔΟΣΕΙΣ ΤΗΣ ΑΝΤΙΔΡΑΣΗΣ (1) --> (2) ΣΕ ΔΙΑΦΟΡΟΥΣ ΔΙΑΛΥΤΕΣ. ΣΤΟΥΣ ΠΟΛΙΚΟΥΣ ΔΙΑΛΥΤΕΣ ΒΡΕΘΗΚΕ ΝΑ ΕΠΙΔΡΑ ΤΟ Η2Ο ΣΤΗΝ ΑΠΟΔΟΣΗ, Η ΚΒΑΝΤΙΚΗ ΑΠΟΔΟΣΗ ΑΥΞΗΘΗΚΕ ΑΠΟ 0.0088 ΣΕ ΔΙΑΛ. ΕΤΟΗ ΣΕ 0.0 ΣΕ ΜΙΓΜΑ (ΤΥΠΟΣ). ΣΤΟΥΣ ΜΗ ΠΟΛΙΚΟΥΣ ΔΙΑΛΥΤΕΣ ΑΥΞΗΘΗΚΕ Η ΚΒΑΝΤΙΚΗ ΑΠΟΔΟΣΗ ΜΕ ΤΗΝ ΧΡΗΣΙΜΟΠΟΙΗΣΗ ΩΣ \"ΦΩΤΟΕΥΑΙΣΘΗΤΟΠΟΙΗΤΗ\" ΤΗΝ ΒΕΝΖΟΦΑΙΝΟΝΗ (ΕΤ=68.5 KCALMOL-1) [ΑΠΟ 0.0025 ΣΕ 0.012]. Β) ΤΑ ΠΑΡΑΠΡΟΙΟΝΤΑ ΤΗΣ ΑΝΤΙΔΡΑΣΗΣ (1) --> (2) ΚΑΙ ΕΠΙΤΕΥΧΘΗΚΕ Ο ΠΕΡΙΟΡΙΣΜΟΣ ΤΟΥΣ. Γ) ΠΡΟΤΑΘΗΚΕ ΜΗΧΑΝΙΣΜΟΣ ΓΙΑ ΤΗΝ ΑΝΤΙΔΡΑΣΗ. ΤΑ ΠΕΙΡΑΜΑΤΙΚΑ ΑΠΟΤΕΛΕΣΜΑΤΑ ΟΔΗΓΟΥΝ ΣΤΟ ΣΥΜΠΕΡΑΣΜΑ ΟΤΙ Η ΚΑΡΒΟΝΟΚΑΜΦΟΡΑ ΣΕ ΜΗ ΠΟΛΙΚΟΥΣ ΔΙΑΛΥΤΕΣ ΣΧΗΜΑΤΙΖΕΤΑΙ ΜΟΝΟ ΜΕΣΩ ΕΝΔΙΑΜΕΣΟΥ ΤΡΙΠΛΗΣ ΚΑΤΑΣΤΑΣΗΣ (ΤΙ)3Π-Π*. ΣΤΗΝ ΠΕΡΙΠΤΩΣΗ ΠΟΛΙΚΩΝ ΥΔΡΟΞΥ-ΔΙΑΛΥΤΩΝ ΠΕΡΙΛΑΜΒΝΟΝΤΑΙ ΚΑΙ ΙΟΝΤΙΚΑ ΕΝΔΙΑΜΕΣΑ. Δ) ΓΙΑ ΠΡΩΤΗ ΦΟΡΑ ΕΓΙΝΑΝ ΠΡΟΣΠΑΘΕΙΕΣ ΑΝΤΙΣΤΡΟΦΗΣ ΤΗΣ ΑΝΤΙΔΡΑΣΕΩΣ (1) --> (2). ΧΡΗΣΙΜΟΠΟΙΗΘΗΚΑΝ ΩΣ ΚΑΤΑΛΥΤΕΣ ΤΟΥ ΡΟΔΙΟΥ. ΕΥΡΕΘΗ ΟΤΙ ΤΟ ΣΥΜΠΛΟΚΟ RH2(CD)4CL2 ΚΑΤΑΛΥΕΙ ΤΗΝ ΑΝΤΙΔΡΑΣΗ (2) --> (1) ΔΗΛΑΔΗ ΚΑΡΒΟΝΟΚΑΜΦΟΡΑΣ ΠΡΟΣ ΚΑΡΒΟΝΗ ΣΕ ΠΟΣΟΣΤΟ 38% ΣΤΟΥΣ 140 C."]},{"key":"dc:title","label":"Title","values":["ΕΝΔΟΜΟΡΙΑΚΗ ΦΩΤΟΚΥΚΛΟΠΟΙΗΣΗ ΤΗΣ ΚΑΡΒΟΝΗΣ ΠΡΟΣ ΚΑΡΒΟΝΟΚΑΜΦΟΡΑ","THE INTRAMOLECULAR PHOTOCYCLOADDITION OF CARVONE TO CARVONECAMPHOR"]}]}],"canonical_facts":{"dc:creator":["Τσίπη, Δέσποινα"],"dc:date":["1987"],"dc:description":["THE QUANTUM YIELDS OF THE PHOTOCYCLOADDITION OF CARVONE (I) TO CARVONECAMPHOR (2) (TYPE) HAVE BEEN DETERMINED IN NON POLAR AND POLAR SOLVENTS, UNDER NITROGEN AND IN AIR-EQUILIBRATED SOLUTIONS. QUENCHING BY OXYGEN HAS BEEN OBSERVED ONLY IN NON POLAR SOLVENTS, BENZENE 01 --> 2=0.0025 UNDER NITROGEN AND 0.0012 IN AIR-EQUILIBRATED SOLUTIONS. SENSITIZATION EXPERIMENTS WITH BENZOPHENONE HAVE SHOWNALSO THAT THE REACTION IN BENZENE MUST PROCEED BY TRIPLET SENSITIZATION. A MARKED ENHANCEMENT OF THE QUANTUM YIELD HAS BEEN OBSERVED IN ETOH-H2O MIXTURES COMPARED TO THAT IN BENZENE AND IN ETOH, 01 --> 2=0.085 IN ETOH-H2O(2:8) & 0. 0088IN ETOH. INVOLVEMENT OF DIFFERENT EXCITED STATES IS SUGGESTED FOR THE PHOTOCYCLIZATION OF CARVONE IN NON POLAR (A TRIPLET STATE) AND IN HYDROXYLIC SOLVENTS (N,N* SINGLET STATE) ON THE BASIS OF THE RESULTS AND THE EFFECT OF WATER ON THE ABSORPTION SPECTRUM OF CARVONE. THE INTRAMOLECULAR PHOTOCYCLOADDITION OF CARVONE TO CARVONECAMPHOR HAS BEEN PROPOSED AMONG OTHER REACTIONS AS A POSSIBLE SYSTEM FOR SOLAR ENERGY STORAGE. TO THIS DIRECTION, THE REVERSE REACTION IN THE DARKWAS ACHIEVED FOR THE FIRST TIME BY USING RH2(CO)4CL2 AS A CATALYST.","ΣΤΗΝ ΕΡΓΑΣΙΑ ΑΤΥΗ ΜΕΛΕΤΗΘΗΚΕ Η ΑΝΤΙΔΡΑΣΗ ΦΩΤΟΚΥΚΛΟΠΟΙΗΣΗΣ ΤΗΣ ΚΑΡΒΟΝΗΣ (1) ΠΡΟΣΚΑΡΒΟΝΟΚΑΜΦΟΡΑ (2) (ΤΥΠΟΣ). Η ΜΕΛΕΤΗ ΤΗΣ (1) -- > (2) ΕΧΕΙ ΠΡΑΚΤΙΚΕΣ ΠΡΟΕΚΤΑΣΕΙΣ ΣΤΟ ΠΕΔΙΟ \"ΜΕΤΑΤΡΟΠΗΣ ΚΑΙ ΑΠΟΘΗΚΕΥΣΕΩΣ ΤΗΣ ΗΛΙΑΚΗΣ ΕΝΕΡΓΕΙΑΣ\". ΜΕΛΕΤΗΘΗΚΑΝ ΤΑ ΕΞΗΣ Α) ΟΙ ΚΒΑΝΤΙΚΕΣ ΑΠΟΔΟΣΕΙΣ ΤΗΣ ΑΝΤΙΔΡΑΣΗΣ (1) --> (2) ΣΕ ΔΙΑΦΟΡΟΥΣ ΔΙΑΛΥΤΕΣ. ΣΤΟΥΣ ΠΟΛΙΚΟΥΣ ΔΙΑΛΥΤΕΣ ΒΡΕΘΗΚΕ ΝΑ ΕΠΙΔΡΑ ΤΟ Η2Ο ΣΤΗΝ ΑΠΟΔΟΣΗ, Η ΚΒΑΝΤΙΚΗ ΑΠΟΔΟΣΗ ΑΥΞΗΘΗΚΕ ΑΠΟ 0.0088 ΣΕ ΔΙΑΛ. ΕΤΟΗ ΣΕ 0.0 ΣΕ ΜΙΓΜΑ (ΤΥΠΟΣ). ΣΤΟΥΣ ΜΗ ΠΟΛΙΚΟΥΣ ΔΙΑΛΥΤΕΣ ΑΥΞΗΘΗΚΕ Η ΚΒΑΝΤΙΚΗ ΑΠΟΔΟΣΗ ΜΕ ΤΗΝ ΧΡΗΣΙΜΟΠΟΙΗΣΗ ΩΣ \"ΦΩΤΟΕΥΑΙΣΘΗΤΟΠΟΙΗΤΗ\" ΤΗΝ ΒΕΝΖΟΦΑΙΝΟΝΗ (ΕΤ=68.5 KCALMOL-1) [ΑΠΟ 0.0025 ΣΕ 0.012]. Β) ΤΑ ΠΑΡΑΠΡΟΙΟΝΤΑ ΤΗΣ ΑΝΤΙΔΡΑΣΗΣ (1) --> (2) ΚΑΙ ΕΠΙΤΕΥΧΘΗΚΕ Ο ΠΕΡΙΟΡΙΣΜΟΣ ΤΟΥΣ. Γ) ΠΡΟΤΑΘΗΚΕ ΜΗΧΑΝΙΣΜΟΣ ΓΙΑ ΤΗΝ ΑΝΤΙΔΡΑΣΗ. ΤΑ ΠΕΙΡΑΜΑΤΙΚΑ ΑΠΟΤΕΛΕΣΜΑΤΑ ΟΔΗΓΟΥΝ ΣΤΟ ΣΥΜΠΕΡΑΣΜΑ ΟΤΙ Η ΚΑΡΒΟΝΟΚΑΜΦΟΡΑ ΣΕ ΜΗ ΠΟΛΙΚΟΥΣ ΔΙΑΛΥΤΕΣ ΣΧΗΜΑΤΙΖΕΤΑΙ ΜΟΝΟ ΜΕΣΩ ΕΝΔΙΑΜΕΣΟΥ ΤΡΙΠΛΗΣ ΚΑΤΑΣΤΑΣΗΣ (ΤΙ)3Π-Π*. ΣΤΗΝ ΠΕΡΙΠΤΩΣΗ ΠΟΛΙΚΩΝ ΥΔΡΟΞΥ-ΔΙΑΛΥΤΩΝ ΠΕΡΙΛΑΜΒΝΟΝΤΑΙ ΚΑΙ ΙΟΝΤΙΚΑ ΕΝΔΙΑΜΕΣΑ. Δ) ΓΙΑ ΠΡΩΤΗ ΦΟΡΑ ΕΓΙΝΑΝ ΠΡΟΣΠΑΘΕΙΕΣ ΑΝΤΙΣΤΡΟΦΗΣ ΤΗΣ ΑΝΤΙΔΡΑΣΕΩΣ (1) --> (2). ΧΡΗΣΙΜΟΠΟΙΗΘΗΚΑΝ ΩΣ ΚΑΤΑΛΥΤΕΣ ΤΟΥ ΡΟΔΙΟΥ. ΕΥΡΕΘΗ ΟΤΙ ΤΟ ΣΥΜΠΛΟΚΟ RH2(CD)4CL2 ΚΑΤΑΛΥΕΙ ΤΗΝ ΑΝΤΙΔΡΑΣΗ (2) --> (1) ΔΗΛΑΔΗ ΚΑΡΒΟΝΟΚΑΜΦΟΡΑΣ ΠΡΟΣ ΚΑΡΒΟΝΗ ΣΕ ΠΟΣΟΣΤΟ 38% ΣΤΟΥΣ 140 C."],"dc:identifier":["10.12681/eadd/0560","http://hdl.handle.net/10442/hedi/0560"],"dc:language":["gre"],"dc:publisher":["Εθνικό και Καποδιστριακό Πανεπιστήμιο Αθηνών (ΕΚΠΑ)","National and Kapodistrian University of Athens"],"dc:subject":["ABSORPTION SPECTRA, EMISSION","FLASH PHOTOLYSIS","PHOTOCHEMICAL PRODUCTS","QUANTUM YIELD MEASUREMENTS","SENSITIZATION, BENROPHENONE","SOLAR EMERGY STORAGE","THE REVERSE REACTION","ΑΠΟΘΗΚΕΥΣΗ ΗΛΙΑΚΗΣ ΕΝΕΡΓΕΙΑΣ","ΜΕΤΡΗΣΕΙΣ ΚΒΑΝΤΙΚΗΣ ΑΠΟΔΟΣΗΣ","ΠΑΛΜΙΚΗ ΦΩΤΟΛΥΣΗ","ΦΑΣΜΑΤΑ ΑΠΟΡΡΟΦΗΣΗΣ, ΕΚΠΟΜΠΗΣ","Φυσικές Επιστήμες","Natural Sciences","Χημεία","Chemical Sciences"],"dc:title":["ΕΝΔΟΜΟΡΙΑΚΗ ΦΩΤΟΚΥΚΛΟΠΟΙΗΣΗ ΤΗΣ ΚΑΡΒΟΝΗΣ ΠΡΟΣ ΚΑΡΒΟΝΟΚΑΜΦΟΡΑ","THE INTRAMOLECULAR PHOTOCYCLOADDITION OF CARVONE TO CARVONECAMPHOR"],"dc:type":["PhD Thesis"]},"updated_at":"2026-07-24T02:25:21Z"}