{"id":{"repo_id":"gmu","oai_identifier":"oai:MARS:1920/5613"},"canonical_url":"https://search.dev.ndltd.org/etd/gmu/oai:MARS:1920/5613","repository":{"repo_id":"gmu","name":"George Mason University","base_url":"https://mars.gmu.edu/server/oai/request"},"display":{"title":"Fuctionalized Alkyl Quinolines: Synthesis and Characterization","abstract":"Novel syntheses using 4-methoxy-2-methylquinoline were attempted by using a strong base to remove the most acidic proton, one of the protons of the methyl in the 2-position, to generate a carbanion. Upon the introduction of a halide with an electrophile, the electrophile will attack the carbanion where the proton was removed in an SN2 reaction to make a new compound. The methods for how this type of reaction was tried were attempted temperatures and bases are described. The DEPT-90 and 135 of 4-methoxy-2-methylquinoline were run, analyzed and the spectra are given. The DEPT spectra for this compound constitute a new contribution to the reference information for 4-methoxy-2-methylquinoline.","abstract_html":"Novel syntheses using 4-methoxy-2-methylquinoline were attempted by using a strong base to remove the most acidic proton, one of the protons of the methyl in the 2-position, to generate a carbanion. Upon the introduction of a halide with an electrophile, the electrophile will attack the carbanion where the proton was removed in an SN2 reaction to make a new compound. The methods for how this type of reaction was tried were attempted temperatures and bases are described. The DEPT-90 and 135 of 4-methoxy-2-methylquinoline were run, analyzed and the spectra are given. The DEPT spectra for this compound constitute a new contribution to the reference information for 4-methoxy-2-methylquinoline.","abstract_has_math":false,"creators":["Dripps, Rachel B."],"institution":null,"degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":[],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2009,"date_issued":"2009-09-22T20:29:19Z","date_published":"2009-09-22T20:29:19Z","updated_at":"2026-07-27T19:51:58Z","subjects":["Quinolines","Alkyl quinolines","4-methoxy-2-methylquinoline","2-[4-(1,3)-dioxolan-2-yl)butyl]-4-methoxyquinoline"],"languages":[],"rights":[],"rights_urls":[],"identifier_entries":[{"key":"dc:identifier","label":"Identifier","values":["hdl:1920/5613"],"render_values":[{"text":"hdl:1920/5613","href":null,"code":true}]}]},"links":{"outbound_url":null,"outbound_label":null,"outbound_source":null},"metadata_groups":[{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.issued","label":"Date","values":["2009-09-22T20:29:19Z"]},{"key":"dc:type","label":"Dc Type","values":["Thesis"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Quinolines","Alkyl quinolines","4-methoxy-2-methylquinoline","2-[4-(1,3)-dioxolan-2-yl)butyl]-4-methoxyquinoline"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["hdl:1920/5613"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.other","label":"Dc Description Other","values":["Novel syntheses using 4-methoxy-2-methylquinoline were attempted by using a strong base to remove the most acidic proton, one of the protons of the methyl in the 2-position, to generate a carbanion. Upon the introduction of a halide with an electrophile, the electrophile will attack the carbanion where the proton was removed in an SN2 reaction to make a new compound. The methods for how this type of reaction was tried were attempted temperatures and bases are described. The DEPT-90 and 135 of 4-methoxy-2-methylquinoline were run, analyzed and the spectra are given. The DEPT spectra for this compound constitute a new contribution to the reference information for 4-methoxy-2-methylquinoline."]},{"key":"dc:title","label":"Title","values":["Fuctionalized Alkyl Quinolines: Synthesis and Characterization"]}]}],"canonical_facts":{"dc:date.issued":["2009-09-22T20:29:19Z"],"dc:description.other":["Novel syntheses using 4-methoxy-2-methylquinoline were attempted by using a strong base to remove the most acidic proton, one of the protons of the methyl in the 2-position, to generate a carbanion. Upon the introduction of a halide with an electrophile, the electrophile will attack the carbanion where the proton was removed in an SN2 reaction to make a new compound. The methods for how this type of reaction was tried were attempted temperatures and bases are described. The DEPT-90 and 135 of 4-methoxy-2-methylquinoline were run, analyzed and the spectra are given. The DEPT spectra for this compound constitute a new contribution to the reference information for 4-methoxy-2-methylquinoline."],"dc:identifier":["hdl:1920/5613"],"dc:subject":["Quinolines","Alkyl quinolines","4-methoxy-2-methylquinoline","2-[4-(1,3)-dioxolan-2-yl)butyl]-4-methoxyquinoline"],"dc:title":["Fuctionalized Alkyl Quinolines: Synthesis and Characterization"],"dc:type":["Thesis"]},"updated_at":"2026-07-27T19:51:58Z"}