{"id":{"repo_id":"etsu","oai_identifier":"oai:dc.etsu.edu:etd-3080"},"canonical_url":"https://search.dev.ndltd.org/etd/etsu/oai:dc.etsu.edu:etd-3080","repository":{"repo_id":"etsu","name":"East Tennessee State University","base_url":"https://dc.etsu.edu/do/oai/"},"display":{"title":"Cyanoscorpionates and Transition Metal Complexes.","abstract":"<p>The new dihydrobis(4-cyano-3-tert-butylpyrazolylborate) ligand has been synthesized. Isolated crystals of the thallium complex were collected and structurally characterized by X-ray diffraction. Transition metal complexes of the ligand are currently under investigation.</p>","abstract_html":"&lt;p&gt;The new dihydrobis(4-cyano-3-tert-butylpyrazolylborate) ligand has been synthesized. Isolated crystals of the thallium complex were collected and structurally characterized by X-ray diffraction. Transition metal complexes of the ligand are currently under investigation.&lt;/p&gt;","abstract_has_math":false,"creators":["Johnson, Donald Martin"],"institution":null,"degree_name":"MS (Master of Science)","degree_level":"Thesis - unrestricted","degree_discipline":"Chemistry","degree_department":null,"school":null,"contributors":[],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2010,"date_issued":"2010-08-13T07:00:00Z","date_published":"2010-08-13T07:00:00Z","updated_at":"2026-07-24T02:20:55Z","subjects":["Transition Metal Complex","Ligands","Magnetic Polymers","Material Science","Polypyrazolylborate","Conductive Polymer","Pyrazole","Cyanoscorpionate","Chemistry","Inorganic Chemistry","Physical Sciences and Mathematics"],"languages":[],"rights":["Copyright by the authors."],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"https://dc.etsu.edu/etd/1725","outbound_label":"Repository record","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:creator","label":"Author","values":["Johnson, Donald Martin"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.issued","label":"Date","values":["2010-08-13T07:00:00Z"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Chemistry"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Thesis - unrestricted"]},{"key":"thesis:degree_name","label":"Degree Name","values":["MS (Master of Science)"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Transition Metal Complex","Ligands","Magnetic Polymers","Material Science","Polypyrazolylborate","Conductive Polymer","Pyrazole","Cyanoscorpionate","Chemistry","Inorganic Chemistry","Physical Sciences and Mathematics"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:rights","label":"Dc Rights","values":["Copyright by the authors."]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["https://dc.etsu.edu/context/etd/article/3080/viewcontent/JohnsonD081010f.pdf","https://dc.etsu.edu/etd/1725"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["<p>The new dihydrobis(4-cyano-3-tert-butylpyrazolylborate) ligand has been synthesized. Isolated crystals of the thallium complex were collected and structurally characterized by X-ray diffraction. Transition metal complexes of the ligand are currently under investigation.</p>"]},{"key":"dc:title","label":"Title","values":["Cyanoscorpionates and Transition Metal Complexes."]}]}],"canonical_facts":{"dc:creator":["Johnson, Donald Martin"],"dc:date.issued":["2010-08-13T07:00:00Z"],"dc:description.abstract":["<p>The new dihydrobis(4-cyano-3-tert-butylpyrazolylborate) ligand has been synthesized. Isolated crystals of the thallium complex were collected and structurally characterized by X-ray diffraction. Transition metal complexes of the ligand are currently under investigation.</p>"],"dc:identifier":["https://dc.etsu.edu/context/etd/article/3080/viewcontent/JohnsonD081010f.pdf","https://dc.etsu.edu/etd/1725"],"dc:rights":["Copyright by the authors."],"dc:subject":["Transition Metal Complex","Ligands","Magnetic Polymers","Material Science","Polypyrazolylborate","Conductive Polymer","Pyrazole","Cyanoscorpionate","Chemistry","Inorganic Chemistry","Physical Sciences and Mathematics"],"dc:title":["Cyanoscorpionates and Transition Metal Complexes."],"thesis:degree_discipline":["Chemistry"],"thesis:degree_level":["Thesis - unrestricted"],"thesis:degree_name":["MS (Master of Science)"]},"updated_at":"2026-07-24T02:20:55Z"}