Ionic liquids have been used in free radical polymerizations to make polymerized ionic liquid (PIL) materials of various types. PIL gels based on imidazolium cations have been found to exhibit an anion-exchange induced stimuli responsiveness. This thesis explores incorporation of ionic liquids in polyurethane (PU) polymers to make PIL PU gels and dispersions through condensation polymerization. PIL gels are synthesized through a single-pot approach that show stimuli response to solvents. This approach allows one to make these gels rapidly and cheaply on-site. These gels can reversibly porate in different solvents and are found to be porous when analyzed by scanning electron microscope (SEM). PIL based resins are also made in two steps, that show self-dispersion properties in water forming thermodynamically stable nano-scale particles. These materials can be transported as 100% solid resins, where they can be transformed into polyurethane dispersions (PUDs) onsite. These particles also show stimuli responsiveness to different anions and solvents.
","abstract_html":"<p>Ionic liquids have been used in free radical polymerizations to make polymerized ionic liquid (PIL) materials of various types. PIL gels based on imidazolium cations have been found to exhibit an anion-exchange induced stimuli responsiveness. This thesis explores incorporation of ionic liquids in polyurethane (PU) polymers to make PIL PU gels and dispersions through condensation polymerization. PIL gels are synthesized through a single-pot approach that show stimuli response to solvents. This approach allows one to make these gels rapidly and cheaply on-site. These gels can reversibly porate in different solvents and are found to be porous when analyzed by scanning electron microscope (SEM). PIL based resins are also made in two steps, that show self-dispersion properties in water forming thermodynamically stable nano-scale particles. These materials can be transported as 100% solid resins, where they can be transformed into polyurethane dispersions (PUDs) onsite. These particles also show stimuli responsiveness to different anions and solvents.</p>","abstract_has_math":false,"creators":["Gupta, Harshit"],"institution":null,"degree_name":"Master of Science (MS)","degree_level":"Open Access Thesis","degree_discipline":"Engineering Technology","degree_department":null,"school":null,"contributors":["John Texter, PhD","Vijay Kumar Mannari, PhD","Mohamed El-Sayed, PhD"],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2019,"date_issued":"2019-01-01T08:00:00Z","date_published":"2019-01-01T08:00:00Z","updated_at":"2026-07-24T02:17:33Z","subjects":["Contact angle","Ionic Liquid","Poly ionic liquid gel","PUDs","Self Dispersion","Stimuli responsive","Polymer Chemistry"],"languages":[],"rights":[],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"https://commons.emich.edu/theses/964","outbound_label":"Repository record","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["John Texter, PhD","Vijay Kumar Mannari, PhD","Mohamed El-Sayed, PhD"]},{"key":"dc:creator","label":"Author","values":["Gupta, Harshit"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.available","label":"Dc Date Available","values":["2019-05-14T07:00:00Z"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Engineering Technology"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Open Access Thesis"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Master of Science (MS)"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Contact angle","Ionic Liquid","Poly ionic liquid gel","PUDs","Self Dispersion","Stimuli responsive","Polymer Chemistry"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["https://commons.emich.edu/theses/964"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["Ionic liquids have been used in free radical polymerizations to make polymerized ionic liquid (PIL) materials of various types. PIL gels based on imidazolium cations have been found to exhibit an anion-exchange induced stimuli responsiveness. This thesis explores incorporation of ionic liquids in polyurethane (PU) polymers to make PIL PU gels and dispersions through condensation polymerization. PIL gels are synthesized through a single-pot approach that show stimuli response to solvents. This approach allows one to make these gels rapidly and cheaply on-site. These gels can reversibly porate in different solvents and are found to be porous when analyzed by scanning electron microscope (SEM). PIL based resins are also made in two steps, that show self-dispersion properties in water forming thermodynamically stable nano-scale particles. These materials can be transported as 100% solid resins, where they can be transformed into polyurethane dispersions (PUDs) onsite. These particles also show stimuli responsiveness to different anions and solvents.
"]},{"key":"dc:title","label":"Title","values":["Polymerized ionic liquids by condensation polymerization: Stimuli responsive polyurethane gels and dispersions"]}]}],"canonical_facts":{"dc:contributor":["John Texter, PhD","Vijay Kumar Mannari, PhD","Mohamed El-Sayed, PhD"],"dc:creator":["Gupta, Harshit"],"dc:date.available":["2019-05-14T07:00:00Z"],"dc:description.abstract":["Ionic liquids have been used in free radical polymerizations to make polymerized ionic liquid (PIL) materials of various types. PIL gels based on imidazolium cations have been found to exhibit an anion-exchange induced stimuli responsiveness. This thesis explores incorporation of ionic liquids in polyurethane (PU) polymers to make PIL PU gels and dispersions through condensation polymerization. PIL gels are synthesized through a single-pot approach that show stimuli response to solvents. This approach allows one to make these gels rapidly and cheaply on-site. These gels can reversibly porate in different solvents and are found to be porous when analyzed by scanning electron microscope (SEM). PIL based resins are also made in two steps, that show self-dispersion properties in water forming thermodynamically stable nano-scale particles. These materials can be transported as 100% solid resins, where they can be transformed into polyurethane dispersions (PUDs) onsite. These particles also show stimuli responsiveness to different anions and solvents.
"],"dc:identifier":["https://commons.emich.edu/theses/964"],"dc:subject":["Contact angle","Ionic Liquid","Poly ionic liquid gel","PUDs","Self Dispersion","Stimuli responsive","Polymer Chemistry"],"dc:title":["Polymerized ionic liquids by condensation polymerization: Stimuli responsive polyurethane gels and dispersions"],"thesis:degree_discipline":["Engineering Technology"],"thesis:degree_level":["Open Access Thesis"],"thesis:degree_name":["Master of Science (MS)"]},"updated_at":"2026-07-24T02:17:33Z"}