Polymerizable ionic liquid surfactants were synthesized and polymerized, yielding engineered advanced polymers that can be tailored for diverse applications. First, 1-(2-acryloyloxyundecyl)-3-methylimidazolium tetrafluoroborate (IL-BF4) was synthesized and was copolymerized with methyl methacrylate (MMA) via microemulsion polymerization. The resulting polymer gels can be transformed into porous materials by anion exchange, and the porosity of the material can be tuned through the solvent shifting. Second, an ionic liquid composed of a 1-(2-acryloyloxyundecyl)-3- methylimidazolium (IL) cation and 2-acryloamido-2-methyl-propylsulfonate (AMPS) anion was synthesized and polymerized by UV irradiation, and introductory data are illustrated for humidity sensitive preparations suitable for chemFETs, for proton conducting polymer electrolyte membranes (PEM) suitable for fuel cell fabrication, and for lithium ion and silver ion conducting membranes suitable for fast ionic conducting batteries.
","abstract_html":"<p>Polymerizable ionic liquid surfactants were synthesized and polymerized, yielding engineered advanced polymers that can be tailored for diverse applications. First, 1-(2-acryloyloxyundecyl)-3-methylimidazolium tetrafluoroborate (IL-BF<sub>4</sub>) was synthesized and was copolymerized with methyl methacrylate (MMA) via microemulsion polymerization. The resulting polymer gels can be transformed into porous materials by anion exchange, and the porosity of the material can be tuned through the solvent shifting. Second, an ionic liquid composed of a 1-(2-acryloyloxyundecyl)-3- methylimidazolium (IL) cation and 2-acryloamido-2-methyl-propylsulfonate (AMPS) anion was synthesized and polymerized by UV irradiation, and introductory data are illustrated for humidity sensitive preparations suitable for chemFETs, for proton conducting polymer electrolyte membranes (PEM) suitable for fuel cell fabrication, and for lithium ion and silver ion conducting membranes suitable for fast ionic conducting batteries.</p>","abstract_has_math":false,"creators":["Gu, Hong"],"institution":null,"degree_name":"Master of Science (MS)","degree_level":"Open Access Thesis","degree_discipline":"Engineering Technology","degree_department":null,"school":null,"contributors":["John Texter, PhD, Chair","Donald Snyder, PhD","Bob Lahidji, PhD"],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2009,"date_issued":"2009-03-01T08:00:00Z","date_published":"2009-03-01T08:00:00Z","updated_at":"2026-07-24T02:16:36Z","subjects":["Ionic solutions","Polymerization","Surface chemistry","Polymer and Organic Materials"],"languages":[],"rights":[],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"https://commons.emich.edu/theses/239","outbound_label":"Repository record","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["John Texter, PhD, Chair","Donald Snyder, PhD","Bob Lahidji, PhD"]},{"key":"dc:creator","label":"Author","values":["Gu, Hong"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"thesis:degree_discipline","label":"Discipline","values":["Engineering Technology"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Open Access Thesis"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Master of Science (MS)"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Ionic solutions","Polymerization","Surface chemistry","Polymer and Organic Materials"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["https://commons.emich.edu/theses/239"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["Polymerizable ionic liquid surfactants were synthesized and polymerized, yielding engineered advanced polymers that can be tailored for diverse applications. First, 1-(2-acryloyloxyundecyl)-3-methylimidazolium tetrafluoroborate (IL-BF4) was synthesized and was copolymerized with methyl methacrylate (MMA) via microemulsion polymerization. The resulting polymer gels can be transformed into porous materials by anion exchange, and the porosity of the material can be tuned through the solvent shifting. Second, an ionic liquid composed of a 1-(2-acryloyloxyundecyl)-3- methylimidazolium (IL) cation and 2-acryloamido-2-methyl-propylsulfonate (AMPS) anion was synthesized and polymerized by UV irradiation, and introductory data are illustrated for humidity sensitive preparations suitable for chemFETs, for proton conducting polymer electrolyte membranes (PEM) suitable for fuel cell fabrication, and for lithium ion and silver ion conducting membranes suitable for fast ionic conducting batteries.
"]},{"key":"dc:title","label":"Title","values":["Materials and coatings derived from the polymerizable ionic liquid surfactants 1-(2-acryloyloxyundecyl)-3-methylimidazolium tetrafluoroborate and 1-(2-acryloyloxyundecyl)-3-methylimidazolium 2-acrylamido-2-methyl-propylsulfonate"]}]}],"canonical_facts":{"dc:contributor":["John Texter, PhD, Chair","Donald Snyder, PhD","Bob Lahidji, PhD"],"dc:creator":["Gu, Hong"],"dc:description.abstract":["Polymerizable ionic liquid surfactants were synthesized and polymerized, yielding engineered advanced polymers that can be tailored for diverse applications. First, 1-(2-acryloyloxyundecyl)-3-methylimidazolium tetrafluoroborate (IL-BF4) was synthesized and was copolymerized with methyl methacrylate (MMA) via microemulsion polymerization. The resulting polymer gels can be transformed into porous materials by anion exchange, and the porosity of the material can be tuned through the solvent shifting. Second, an ionic liquid composed of a 1-(2-acryloyloxyundecyl)-3- methylimidazolium (IL) cation and 2-acryloamido-2-methyl-propylsulfonate (AMPS) anion was synthesized and polymerized by UV irradiation, and introductory data are illustrated for humidity sensitive preparations suitable for chemFETs, for proton conducting polymer electrolyte membranes (PEM) suitable for fuel cell fabrication, and for lithium ion and silver ion conducting membranes suitable for fast ionic conducting batteries.
"],"dc:identifier":["https://commons.emich.edu/theses/239"],"dc:subject":["Ionic solutions","Polymerization","Surface chemistry","Polymer and Organic Materials"],"dc:title":["Materials and coatings derived from the polymerizable ionic liquid surfactants 1-(2-acryloyloxyundecyl)-3-methylimidazolium tetrafluoroborate and 1-(2-acryloyloxyundecyl)-3-methylimidazolium 2-acrylamido-2-methyl-propylsulfonate"],"thesis:degree_discipline":["Engineering Technology"],"thesis:degree_level":["Open Access Thesis"],"thesis:degree_name":["Master of Science (MS)"]},"updated_at":"2026-07-24T02:16:36Z"}