{"id":{"repo_id":"duke","oai_identifier":"oai:dukespace.lib.duke.edu:10161/11331"},"canonical_url":"https://search.dev.ndltd.org/etd/duke/oai:dukespace.lib.duke.edu:10161/11331","repository":{"repo_id":"duke","name":"Duke University","base_url":"https://dukespace.lib.duke.edu/server/oai/request"},"display":{"title":"Modeling Temperature Dependence in Marangoni-driven Thin Films","abstract":"<p>Thin liquid films are often studied by reducing the Navier-Stokes equations</p><p>using Reynolds lubrication theory, which leverages a small aspect ratio</p><p>to yield simplified governing equations. In this dissertation a plate</p><p>coating application, in which polydimethylsiloxane coats a silicon substrate,</p><p>is studied using this approach. Thermal Marangoni stress</p><p>drives fluid motion against the resistance of gravity, with the parameter</p><p>regime being chosen such that these stresses lead to a stable advancing front.</p><p>Additional localized thermal Marangoni stress is used to control the thin film;</p><p>in particular, coating thickness is modulated through the intensity of such</p><p>localized forcing. As thermal effects are central to film dynamics, the dissertation</p><p>focuses specifically on the effect that incorporating temperature dependence</p><p>into viscosity, surface tension, and density has on film dynamics and control.</p><p>Incorporating temperature dependence into viscosity, in particular,</p><p>leads to qualitative changes in film dynamics.</p><p>A mathematical model is developed in which the temperature dependence</p><p>of viscosity and surface tension is carefully taken into account.</p><p>This model is then</p><p>studied through numerical computation of solutions, qualitative analysis,</p><p>and asymptotic analysis. A thorough comparison is made between the</p><p>behavior of solutions to the temperature-independent and</p><p>temperature-dependent models. It is shown that using</p><p>localized thermal Marangoni stress as a control mechanism is feasible</p><p>in both models. Among constant steady-state solutions</p><p>there is a unique such solution in the temperature-dependent model,</p><p>but not in the temperature-independent model, a feature that</p><p>better reflects the known dynamics of the physical system.</p><p>The interaction of boundary conditions with finite domain size is shown</p><p>to generate both periodic and finite-time blow-up solutions, with</p><p>qualitative differences in solution behavior between models.</p><p>This interaction also accounts for the fact that locally perturbed solutions,</p><p>which arise when localized thermal Marangoni forcing is too weak</p><p>to effectively control thin film thickness, exist only for a discrete</p><p>set of boundary heights.</p><p>Modulating the intensity of localized thermal Marangoni forcing is</p><p>an effective means of modulating the thickness of a thin film</p><p>for a plate coating application; however, such control must be initiated before</p><p>the film reaches the full thickness it would reach in the absence of</p><p>such localized forcing. This conclusion holds for both the temperature-independent</p><p>and temperature-dependent mathematical models; furthermore, incorporating</p><p>temperature dependence into viscosity causes qualitative changes in solution</p><p>behavior that better align with known features of the underlying physical system.</p>","abstract_html":"&lt;p&gt;Thin liquid films are often studied by reducing the Navier-Stokes equations&lt;/p&gt;&lt;p&gt;using Reynolds lubrication theory, which leverages a small aspect ratio&lt;/p&gt;&lt;p&gt;to yield simplified governing equations. In this dissertation a plate&lt;/p&gt;&lt;p&gt;coating application, in which polydimethylsiloxane coats a silicon substrate,&lt;/p&gt;&lt;p&gt;is studied using this approach. Thermal Marangoni stress&lt;/p&gt;&lt;p&gt;drives fluid motion against the resistance of gravity, with the parameter&lt;/p&gt;&lt;p&gt;regime being chosen such that these stresses lead to a stable advancing front.&lt;/p&gt;&lt;p&gt;Additional localized thermal Marangoni stress is used to control the thin film;&lt;/p&gt;&lt;p&gt;in particular, coating thickness is modulated through the intensity of such&lt;/p&gt;&lt;p&gt;localized forcing. As thermal effects are central to film dynamics, the dissertation&lt;/p&gt;&lt;p&gt;focuses specifically on the effect that incorporating temperature dependence&lt;/p&gt;&lt;p&gt;into viscosity, surface tension, and density has on film dynamics and control.&lt;/p&gt;&lt;p&gt;Incorporating temperature dependence into viscosity, in particular,&lt;/p&gt;&lt;p&gt;leads to qualitative changes in film dynamics.&lt;/p&gt;&lt;p&gt;A mathematical model is developed in which the temperature dependence&lt;/p&gt;&lt;p&gt;of viscosity and surface tension is carefully taken into account.&lt;/p&gt;&lt;p&gt;This model is then&lt;/p&gt;&lt;p&gt;studied through numerical computation of solutions, qualitative analysis,&lt;/p&gt;&lt;p&gt;and asymptotic analysis. A thorough comparison is made between the&lt;/p&gt;&lt;p&gt;behavior of solutions to the temperature-independent and&lt;/p&gt;&lt;p&gt;temperature-dependent models. It is shown that using&lt;/p&gt;&lt;p&gt;localized thermal Marangoni stress as a control mechanism is feasible&lt;/p&gt;&lt;p&gt;in both models. Among constant steady-state solutions&lt;/p&gt;&lt;p&gt;there is a unique such solution in the temperature-dependent model,&lt;/p&gt;&lt;p&gt;but not in the temperature-independent model, a feature that&lt;/p&gt;&lt;p&gt;better reflects the known dynamics of the physical system.&lt;/p&gt;&lt;p&gt;The interaction of boundary conditions with finite domain size is shown&lt;/p&gt;&lt;p&gt;to generate both periodic and finite-time blow-up solutions, with&lt;/p&gt;&lt;p&gt;qualitative differences in solution behavior between models.&lt;/p&gt;&lt;p&gt;This interaction also accounts for the fact that locally perturbed solutions,&lt;/p&gt;&lt;p&gt;which arise when localized thermal Marangoni forcing is too weak&lt;/p&gt;&lt;p&gt;to effectively control thin film thickness, exist only for a discrete&lt;/p&gt;&lt;p&gt;set of boundary heights.&lt;/p&gt;&lt;p&gt;Modulating the intensity of localized thermal Marangoni forcing is&lt;/p&gt;&lt;p&gt;an effective means of modulating the thickness of a thin film&lt;/p&gt;&lt;p&gt;for a plate coating application; however, such control must be initiated before&lt;/p&gt;&lt;p&gt;the film reaches the full thickness it would reach in the absence of&lt;/p&gt;&lt;p&gt;such localized forcing. This conclusion holds for both the temperature-independent&lt;/p&gt;&lt;p&gt;and temperature-dependent mathematical models; furthermore, incorporating&lt;/p&gt;&lt;p&gt;temperature dependence into viscosity causes qualitative changes in solution&lt;/p&gt;&lt;p&gt;behavior that better align with known features of the underlying physical system.&lt;/p&gt;","abstract_has_math":false,"creators":["Potter, Harrison David"],"institution":null,"degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":[],"advisors":["Witelski, Thomas P"],"committee_chairs":[],"committee_members":[],"year":2015,"date_issued":"2015","date_published":"2015","updated_at":"2026-07-24T02:07:15Z","subjects":["Mathematics","Physics","Fluid Dynamics","Marangoni","Modeling","Nonlinear PDE","Temperature Dependence","Thin Films"],"languages":[],"rights":[],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"https://hdl.handle.net/10161/11331","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.advisor","label":"Advisor","values":["Witelski, Thomas P"]},{"key":"dc:creator","label":"Author","values":["Potter, Harrison David"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.accessioned","label":"Dc Date Accessioned","values":["2016-01-04T19:25:58Z"]},{"key":"dc:date.available","label":"Dc Date Available","values":["2016-01-04T19:25:58Z"]},{"key":"dc:date.issued","label":"Date","values":["2015"]},{"key":"dc:type","label":"Dc Type","values":["Dissertation"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Mathematics","Physics","Fluid Dynamics","Marangoni","Modeling","Nonlinear PDE","Temperature Dependence","Thin Films"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier.uri","label":"Identifier URI","values":["https://hdl.handle.net/10161/11331"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["<p>Thin liquid films are often studied by reducing the Navier-Stokes equations</p><p>using Reynolds lubrication theory, which leverages a small aspect ratio</p><p>to yield simplified governing equations. In this dissertation a plate</p><p>coating application, in which polydimethylsiloxane coats a silicon substrate,</p><p>is studied using this approach. Thermal Marangoni stress</p><p>drives fluid motion against the resistance of gravity, with the parameter</p><p>regime being chosen such that these stresses lead to a stable advancing front.</p><p>Additional localized thermal Marangoni stress is used to control the thin film;</p><p>in particular, coating thickness is modulated through the intensity of such</p><p>localized forcing. As thermal effects are central to film dynamics, the dissertation</p><p>focuses specifically on the effect that incorporating temperature dependence</p><p>into viscosity, surface tension, and density has on film dynamics and control.</p><p>Incorporating temperature dependence into viscosity, in particular,</p><p>leads to qualitative changes in film dynamics.</p><p>A mathematical model is developed in which the temperature dependence</p><p>of viscosity and surface tension is carefully taken into account.</p><p>This model is then</p><p>studied through numerical computation of solutions, qualitative analysis,</p><p>and asymptotic analysis. A thorough comparison is made between the</p><p>behavior of solutions to the temperature-independent and</p><p>temperature-dependent models. It is shown that using</p><p>localized thermal Marangoni stress as a control mechanism is feasible</p><p>in both models. Among constant steady-state solutions</p><p>there is a unique such solution in the temperature-dependent model,</p><p>but not in the temperature-independent model, a feature that</p><p>better reflects the known dynamics of the physical system.</p><p>The interaction of boundary conditions with finite domain size is shown</p><p>to generate both periodic and finite-time blow-up solutions, with</p><p>qualitative differences in solution behavior between models.</p><p>This interaction also accounts for the fact that locally perturbed solutions,</p><p>which arise when localized thermal Marangoni forcing is too weak</p><p>to effectively control thin film thickness, exist only for a discrete</p><p>set of boundary heights.</p><p>Modulating the intensity of localized thermal Marangoni forcing is</p><p>an effective means of modulating the thickness of a thin film</p><p>for a plate coating application; however, such control must be initiated before</p><p>the film reaches the full thickness it would reach in the absence of</p><p>such localized forcing. This conclusion holds for both the temperature-independent</p><p>and temperature-dependent mathematical models; furthermore, incorporating</p><p>temperature dependence into viscosity causes qualitative changes in solution</p><p>behavior that better align with known features of the underlying physical system.</p>"]},{"key":"dc:title","label":"Title","values":["Modeling Temperature Dependence in Marangoni-driven Thin Films"]}]}],"canonical_facts":{"dc:contributor.advisor":["Witelski, Thomas P"],"dc:creator":["Potter, Harrison David"],"dc:date.accessioned":["2016-01-04T19:25:58Z"],"dc:date.available":["2016-01-04T19:25:58Z"],"dc:date.issued":["2015"],"dc:description.abstract":["<p>Thin liquid films are often studied by reducing the Navier-Stokes equations</p><p>using Reynolds lubrication theory, which leverages a small aspect ratio</p><p>to yield simplified governing equations. In this dissertation a plate</p><p>coating application, in which polydimethylsiloxane coats a silicon substrate,</p><p>is studied using this approach. Thermal Marangoni stress</p><p>drives fluid motion against the resistance of gravity, with the parameter</p><p>regime being chosen such that these stresses lead to a stable advancing front.</p><p>Additional localized thermal Marangoni stress is used to control the thin film;</p><p>in particular, coating thickness is modulated through the intensity of such</p><p>localized forcing. As thermal effects are central to film dynamics, the dissertation</p><p>focuses specifically on the effect that incorporating temperature dependence</p><p>into viscosity, surface tension, and density has on film dynamics and control.</p><p>Incorporating temperature dependence into viscosity, in particular,</p><p>leads to qualitative changes in film dynamics.</p><p>A mathematical model is developed in which the temperature dependence</p><p>of viscosity and surface tension is carefully taken into account.</p><p>This model is then</p><p>studied through numerical computation of solutions, qualitative analysis,</p><p>and asymptotic analysis. A thorough comparison is made between the</p><p>behavior of solutions to the temperature-independent and</p><p>temperature-dependent models. It is shown that using</p><p>localized thermal Marangoni stress as a control mechanism is feasible</p><p>in both models. Among constant steady-state solutions</p><p>there is a unique such solution in the temperature-dependent model,</p><p>but not in the temperature-independent model, a feature that</p><p>better reflects the known dynamics of the physical system.</p><p>The interaction of boundary conditions with finite domain size is shown</p><p>to generate both periodic and finite-time blow-up solutions, with</p><p>qualitative differences in solution behavior between models.</p><p>This interaction also accounts for the fact that locally perturbed solutions,</p><p>which arise when localized thermal Marangoni forcing is too weak</p><p>to effectively control thin film thickness, exist only for a discrete</p><p>set of boundary heights.</p><p>Modulating the intensity of localized thermal Marangoni forcing is</p><p>an effective means of modulating the thickness of a thin film</p><p>for a plate coating application; however, such control must be initiated before</p><p>the film reaches the full thickness it would reach in the absence of</p><p>such localized forcing. This conclusion holds for both the temperature-independent</p><p>and temperature-dependent mathematical models; furthermore, incorporating</p><p>temperature dependence into viscosity causes qualitative changes in solution</p><p>behavior that better align with known features of the underlying physical system.</p>"],"dc:identifier.uri":["https://hdl.handle.net/10161/11331"],"dc:subject":["Mathematics","Physics","Fluid Dynamics","Marangoni","Modeling","Nonlinear PDE","Temperature Dependence","Thin Films"],"dc:title":["Modeling Temperature Dependence in Marangoni-driven Thin Films"],"dc:type":["Dissertation"]},"updated_at":"2026-07-24T02:07:15Z"}