{"id":{"repo_id":"cuny-grad","oai_identifier":"oai:academicworks.cuny.edu:gc_etds-3425"},"canonical_url":"https://search.dev.ndltd.org/etd/cuny-grad/oai:academicworks.cuny.edu:gc_etds-3425","repository":{"repo_id":"cuny-grad","name":"City University of New York - Graduate Center","base_url":"https://academicworks.cuny.edu/do/oai/"},"display":{"title":"Nuclear Magnetic Resonance Studies of Electrode and Electrolyte Materials for Li-Ion Batteries","abstract":"<p>In this thesis, Nuclear Magnetic Resonance (NMR) spectroscopic techniques are used to study lithium electrode and electrolyte materials for advanced rechargeable lithium ion batteries. Three projects are described in this thesis. The first involves <sup>23</sup>Na and <sup>37</sup>Al static and magic angle spinning NMR studies of NaAlH<sub>4</sub>/C anode materials for advanced rechargeable batteries. The second project is a study of paramagnetic lithium transition-metal phosphate cathode materials for Li-ion batteries, where<sup> 7</sup>Li, and <sup>31</sup>P single crystal NMR was used in order to obtain detailed information on the local electronic and magnetic environments. The third project investigates the dynamics and motional properties of PS-PEO (16-16)/LiTFSI, a solid electrolyte material, through pulse field gradient NMR.</p>","abstract_html":"&lt;p&gt;In this thesis, Nuclear Magnetic Resonance (NMR) spectroscopic techniques are used to study lithium electrode and electrolyte materials for advanced rechargeable lithium ion batteries. Three projects are described in this thesis. The first involves &lt;sup&gt;23&lt;/sup&gt;Na and &lt;sup&gt;37&lt;/sup&gt;Al static and magic angle spinning NMR studies of NaAlH&lt;sub&gt;4&lt;/sub&gt;/C anode materials for advanced rechargeable batteries. The second project is a study of paramagnetic lithium transition-metal phosphate cathode materials for Li-ion batteries, where&lt;sup&gt; 7&lt;/sup&gt;Li, and &lt;sup&gt;31&lt;/sup&gt;P single crystal NMR was used in order to obtain detailed information on the local electronic and magnetic environments. The third project investigates the dynamics and motional properties of PS-PEO (16-16)/LiTFSI, a solid electrolyte material, through pulse field gradient NMR.&lt;/p&gt;","abstract_has_math":false,"creators":["Cirrincione, Lisa"],"institution":"The Graduate School and University Center of The City University of New York","degree_name":"Doctor of Philosophy","degree_level":"Doctoral","degree_discipline":"Physics","degree_department":null,"school":null,"contributors":[],"advisors":["Steve G. Greenbaum"],"committee_chairs":[],"committee_members":["Sophia N. Suarez","Neepa T. Maitra","Yuhang Ren","J.R.P. Jayakody"],"year":2017,"date_issued":"2017-09-01T07:00:00Z","date_published":"2017-09-01T07:00:00Z","updated_at":"2026-07-24T01:58:22Z","subjects":["Other Physics","Physics","NMR","Batteries","Li-ion Batteries","Diffusion NMR","Anode","Cathode","Electrolyte","Spectroscopy"],"languages":[],"rights":[],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"https://academicworks.cuny.edu/gc_etds/2408","outbound_label":"Repository record","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.advisor","label":"Advisor","values":["Steve G. Greenbaum"]},{"key":"dc:contributor.committeemember","label":"Committee Member","values":["Sophia N. Suarez","Neepa T. Maitra","Yuhang Ren","J.R.P. 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Three projects are described in this thesis. The first involves <sup>23</sup>Na and <sup>37</sup>Al static and magic angle spinning NMR studies of NaAlH<sub>4</sub>/C anode materials for advanced rechargeable batteries. The second project is a study of paramagnetic lithium transition-metal phosphate cathode materials for Li-ion batteries, where<sup> 7</sup>Li, and <sup>31</sup>P single crystal NMR was used in order to obtain detailed information on the local electronic and magnetic environments. The third project investigates the dynamics and motional properties of PS-PEO (16-16)/LiTFSI, a solid electrolyte material, through pulse field gradient NMR.</p>"]},{"key":"dc:title","label":"Title","values":["Nuclear Magnetic Resonance Studies of Electrode and Electrolyte Materials for Li-Ion Batteries"]}]}],"canonical_facts":{"dc:contributor.advisor":["Steve G. Greenbaum"],"dc:contributor.committeemember":["Sophia N. Suarez","Neepa T. Maitra","Yuhang Ren","J.R.P. Jayakody"],"dc:creator":["Cirrincione, Lisa"],"dc:date.available":["2017-09-12T07:00:00Z"],"dc:description.abstract":["<p>In this thesis, Nuclear Magnetic Resonance (NMR) spectroscopic techniques are used to study lithium electrode and electrolyte materials for advanced rechargeable lithium ion batteries. Three projects are described in this thesis. The first involves <sup>23</sup>Na and <sup>37</sup>Al static and magic angle spinning NMR studies of NaAlH<sub>4</sub>/C anode materials for advanced rechargeable batteries. The second project is a study of paramagnetic lithium transition-metal phosphate cathode materials for Li-ion batteries, where<sup> 7</sup>Li, and <sup>31</sup>P single crystal NMR was used in order to obtain detailed information on the local electronic and magnetic environments. The third project investigates the dynamics and motional properties of PS-PEO (16-16)/LiTFSI, a solid electrolyte material, through pulse field gradient NMR.</p>"],"dc:identifier":["https://academicworks.cuny.edu/gc_etds/2408"],"dc:subject":["Other Physics","Physics","NMR","Batteries","Li-ion Batteries","Diffusion NMR","Anode","Cathode","Electrolyte","Spectroscopy"],"dc:title":["Nuclear Magnetic Resonance Studies of Electrode and Electrolyte Materials for Li-Ion Batteries"],"thesis:degree_discipline":["Physics"],"thesis:degree_level":["Doctoral"],"thesis:degree_name":["Doctor of Philosophy"],"thesis:institution_name":["The Graduate School and University Center of The City University of New York"]},"updated_at":"2026-07-24T01:58:22Z"}