{"id":{"repo_id":"creighton","oai_identifier":"oai:cdr.creighton.edu:10504/92694"},"canonical_url":"https://search.dev.ndltd.org/etd/creighton/oai:cdr.creighton.edu:10504/92694","repository":{"repo_id":"creighton","name":"Creighton University","base_url":"https://cdr.creighton.edu/server/oai/request"},"display":{"title":"The Oximes of 1-(3-Methoxy-4-Agetoxyphenyl)-2, 6-Dicarbethoxycyclohex-Anedione-3,5 and their Derivatives","abstract":"The oximes represent an important group of compounds in the research field of organic chemistry. They can \"be prepared either by the reaction of the carbonyl group with hydroxylamine or by the reaction of nitrous acid or nitrous acid esters on compounds containing reactive methylene groups. These isonitroso compounds rearrange to oximes. |Oximes are most often used for purposes of preparing 1,2 dike to compounds. Thus the hydrolysis of Nitroso methyl ethyl ketone gives biacetyl, which is important in the preparation of perfumes. Also diisonitro-soacetone is important as the starting material for the production of diamino acetone, which in turn is used for the imidazole synthesis.' A special use of isonitroso ketone consists of their condensation to isatin and isatin derivatives.","abstract_html":"The oximes represent an important group of compounds in the research field of organic chemistry. They can "be prepared either by the reaction of the carbonyl group with hydroxylamine or by the reaction of nitrous acid or nitrous acid esters on compounds containing reactive methylene groups. These isonitroso compounds rearrange to oximes. |Oximes are most often used for purposes of preparing 1,2 dike to compounds. Thus the hydrolysis of Nitroso methyl ethyl ketone gives biacetyl, which is important in the preparation of perfumes. Also diisonitro-soacetone is important as the starting material for the production of diamino acetone, which in turn is used for the imidazole synthesis.' A special use of isonitroso ketone consists of their condensation to isatin and isatin derivatives.","abstract_has_math":false,"creators":["Chin, Carl"],"institution":"Creighton University","degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":[],"advisors":["Papadakis, Phillippos E."],"committee_chairs":[],"committee_members":[],"year":1950,"date_issued":"1950","date_published":"1950","updated_at":"2026-07-24T01:49:51Z","subjects":[],"languages":["en_US"],"rights":["A non-exclusive distribution right is granted to Creighton University and to ProQuest following the publishing model selected above."],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"http://hdl.handle.net/10504/92694","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.advisor","label":"Advisor","values":["Papadakis, Phillippos E."]},{"key":"dc:creator","label":"Author","values":["Chin, Carl"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.accessioned","label":"Dc Date Accessioned","values":["2016-11-14T17:43:02Z"]},{"key":"dc:date.available","label":"Dc Date Available","values":["2016-11-14T17:43:02Z"]},{"key":"dc:date.issued","label":"Date","values":["1950"]},{"key":"dc:publisher","label":"Institution","values":["Creighton University"]},{"key":"dc:type","label":"Dc Type","values":["Thesis"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language.iso","label":"Language (ISO)","values":["en_US"]},{"key":"dc:rights","label":"Dc Rights","values":["A non-exclusive distribution right is granted to Creighton University and to ProQuest following the publishing model selected above."]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier.uri","label":"Identifier URI","values":["http://hdl.handle.net/10504/92694"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["The oximes represent an important group of compounds in the research field of organic chemistry. They can \"be prepared either by the reaction of the carbonyl group with hydroxylamine or by the reaction of nitrous acid or nitrous acid esters on compounds containing reactive methylene groups. These isonitroso compounds rearrange to oximes. |Oximes are most often used for purposes of preparing 1,2 dike to compounds. Thus the hydrolysis of Nitroso methyl ethyl ketone gives biacetyl, which is important in the preparation of perfumes. Also diisonitro-soacetone is important as the starting material for the production of diamino acetone, which in turn is used for the imidazole synthesis.' A special use of isonitroso ketone consists of their condensation to isatin and isatin derivatives."]},{"key":"dc:title","label":"Title","values":["The Oximes of 1-(3-Methoxy-4-Agetoxyphenyl)-2, 6-Dicarbethoxycyclohex-Anedione-3,5 and their Derivatives"]}]}],"canonical_facts":{"dc:contributor.advisor":["Papadakis, Phillippos E."],"dc:creator":["Chin, Carl"],"dc:date.accessioned":["2016-11-14T17:43:02Z"],"dc:date.available":["2016-11-14T17:43:02Z"],"dc:date.issued":["1950"],"dc:description.abstract":["The oximes represent an important group of compounds in the research field of organic chemistry. They can \"be prepared either by the reaction of the carbonyl group with hydroxylamine or by the reaction of nitrous acid or nitrous acid esters on compounds containing reactive methylene groups. These isonitroso compounds rearrange to oximes. |Oximes are most often used for purposes of preparing 1,2 dike to compounds. Thus the hydrolysis of Nitroso methyl ethyl ketone gives biacetyl, which is important in the preparation of perfumes. Also diisonitro-soacetone is important as the starting material for the production of diamino acetone, which in turn is used for the imidazole synthesis.' A special use of isonitroso ketone consists of their condensation to isatin and isatin derivatives."],"dc:identifier.uri":["http://hdl.handle.net/10504/92694"],"dc:language.iso":["en_US"],"dc:publisher":["Creighton University"],"dc:rights":["A non-exclusive distribution right is granted to Creighton University and to ProQuest following the publishing model selected above."],"dc:title":["The Oximes of 1-(3-Methoxy-4-Agetoxyphenyl)-2, 6-Dicarbethoxycyclohex-Anedione-3,5 and their Derivatives"],"dc:type":["Thesis"]},"updated_at":"2026-07-24T01:49:51Z"}