{"id":{"repo_id":"creighton","oai_identifier":"oai:cdr.creighton.edu:10504/114413"},"canonical_url":"https://search.dev.ndltd.org/etd/creighton/oai:cdr.creighton.edu:10504/114413","repository":{"repo_id":"creighton","name":"Creighton University","base_url":"https://cdr.creighton.edu/server/oai/request"},"display":{"title":"A Study of the Structure Of 1,1,2,2-Tetracyanocyclopropane-Methanol Adduct","abstract":"In 1975 Danishefsky proposed that for homoconjugate addition to occur between a nucleophile and a cyclopropane, it was necessary for the cyclopropane to contain two activating groups, such as -COCR or -CN. The initial intent of this research was to investigate the possibility of similar reactions with 1,1,2,2- tetracyanocyclopropanes. However, in the preparation of the cyanocyclopropanes, an unexpected product was obtained. The research was then redirected to investigate the nature of this product.","abstract_html":"In 1975 Danishefsky proposed that for homoconjugate addition to occur between a nucleophile and a cyclopropane, it was necessary for the cyclopropane to contain two activating groups, such as -COCR or -CN. The initial intent of this research was to investigate the possibility of similar reactions with 1,1,2,2- tetracyanocyclopropanes. However, in the preparation of the cyanocyclopropanes, an unexpected product was obtained. The research was then redirected to investigate the nature of this product.","abstract_has_math":false,"creators":["Cook, Janine Denis"],"institution":"Creighton University","degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":[],"advisors":["Takemura, Kaz H."],"committee_chairs":[],"committee_members":[],"year":1977,"date_issued":"1977","date_published":"1977","updated_at":"2026-07-24T01:52:03Z","subjects":[],"languages":["en_US"],"rights":["A non-exclusive distribution right is granted to Creighton University and to ProQuest following the publishing model selected above."],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"http://hdl.handle.net/10504/114413","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.advisor","label":"Advisor","values":["Takemura, Kaz H."]},{"key":"dc:creator","label":"Author","values":["Cook, Janine Denis"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.accessioned","label":"Dc Date Accessioned","values":["2017-10-04T20:50:25Z"]},{"key":"dc:date.available","label":"Dc Date Available","values":["2017-10-04T20:50:25Z"]},{"key":"dc:date.issued","label":"Date","values":["1977"]},{"key":"dc:publisher","label":"Institution","values":["Creighton University"]},{"key":"dc:type","label":"Dc Type","values":["Thesis"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language.iso","label":"Language (ISO)","values":["en_US"]},{"key":"dc:rights","label":"Dc Rights","values":["A non-exclusive distribution right is granted to Creighton University and to ProQuest following the publishing model selected above."]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier.uri","label":"Identifier URI","values":["http://hdl.handle.net/10504/114413"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["In 1975 Danishefsky proposed that for homoconjugate addition to occur between a nucleophile and a cyclopropane, it was necessary for the cyclopropane to contain two activating groups, such as -COCR or -CN. The initial intent of this research was to investigate the possibility of similar reactions with 1,1,2,2- tetracyanocyclopropanes. However, in the preparation of the cyanocyclopropanes, an unexpected product was obtained. The research was then redirected to investigate the nature of this product."]},{"key":"dc:title","label":"Title","values":["A Study of the Structure Of 1,1,2,2-Tetracyanocyclopropane-Methanol Adduct"]}]}],"canonical_facts":{"dc:contributor.advisor":["Takemura, Kaz H."],"dc:creator":["Cook, Janine Denis"],"dc:date.accessioned":["2017-10-04T20:50:25Z"],"dc:date.available":["2017-10-04T20:50:25Z"],"dc:date.issued":["1977"],"dc:description.abstract":["In 1975 Danishefsky proposed that for homoconjugate addition to occur between a nucleophile and a cyclopropane, it was necessary for the cyclopropane to contain two activating groups, such as -COCR or -CN. The initial intent of this research was to investigate the possibility of similar reactions with 1,1,2,2- tetracyanocyclopropanes. However, in the preparation of the cyanocyclopropanes, an unexpected product was obtained. The research was then redirected to investigate the nature of this product."],"dc:identifier.uri":["http://hdl.handle.net/10504/114413"],"dc:language.iso":["en_US"],"dc:publisher":["Creighton University"],"dc:rights":["A non-exclusive distribution right is granted to Creighton University and to ProQuest following the publishing model selected above."],"dc:title":["A Study of the Structure Of 1,1,2,2-Tetracyanocyclopropane-Methanol Adduct"],"dc:type":["Thesis"]},"updated_at":"2026-07-24T01:52:03Z"}