{"id":{"repo_id":"creighton","oai_identifier":"oai:cdr.creighton.edu:10504/109028"},"canonical_url":"https://search.dev.ndltd.org/etd/creighton/oai:cdr.creighton.edu:10504/109028","repository":{"repo_id":"creighton","name":"Creighton University","base_url":"https://cdr.creighton.edu/server/oai/request"},"display":{"title":"Addition Reactions or Diethyl 2,4-dicyanoglutaconate","abstract":"For many years, acrylonitrile has afforded the organic chemist a convenient method of introducing a three-carbon residue onto a variety of organic compounds by the so-called cyano-ethylation reaction. This reaction is generally brought about by a base-catalyzed, nucleophilic addition. The purpose of this work is to investigate and to evaluate the applicability of the readily-available diethyl 2,4-dicyanoglutaconate in a similar type of reaction. Such a reaction, if feasible, would permit the introduction of a seven-carbon residue which possesses reactive terminal functional groups. This would be of great value in synthetic organic chemistry.","abstract_html":"For many years, acrylonitrile has afforded the organic chemist a convenient method of introducing a three-carbon residue onto a variety of organic compounds by the so-called cyano-ethylation reaction. This reaction is generally brought about by a base-catalyzed, nucleophilic addition. The purpose of this work is to investigate and to evaluate the applicability of the readily-available diethyl 2,4-dicyanoglutaconate in a similar type of reaction. Such a reaction, if feasible, would permit the introduction of a seven-carbon residue which possesses reactive terminal functional groups. This would be of great value in synthetic organic chemistry.","abstract_has_math":false,"creators":["Di Mari, Samuel J."],"institution":"Creighton University","degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":[],"advisors":["Takemura, Kaz H."],"committee_chairs":[],"committee_members":[],"year":1962,"date_issued":"1962","date_published":"1962","updated_at":"2026-07-24T01:52:24Z","subjects":[],"languages":["en_US"],"rights":["A non-exclusive distribution right is granted to Creighton University and to ProQuest following the publishing model selected above."],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"http://hdl.handle.net/10504/109028","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.advisor","label":"Advisor","values":["Takemura, Kaz H."]},{"key":"dc:creator","label":"Author","values":["Di Mari, Samuel J."]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.accessioned","label":"Dc Date Accessioned","values":["2017-01-20T22:02:00Z"]},{"key":"dc:date.available","label":"Dc Date Available","values":["2017-01-20T22:02:00Z"]},{"key":"dc:date.issued","label":"Date","values":["1962"]},{"key":"dc:publisher","label":"Institution","values":["Creighton University"]},{"key":"dc:type","label":"Dc Type","values":["Thesis"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language.iso","label":"Language (ISO)","values":["en_US"]},{"key":"dc:rights","label":"Dc Rights","values":["A non-exclusive distribution right is granted to Creighton University and to ProQuest following the publishing model selected above."]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier.uri","label":"Identifier URI","values":["http://hdl.handle.net/10504/109028"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["For many years, acrylonitrile has afforded the organic chemist a convenient method of introducing a three-carbon residue onto a variety of organic compounds by the so-called cyano-ethylation reaction. This reaction is generally brought about by a base-catalyzed, nucleophilic addition. The purpose of this work is to investigate and to evaluate the applicability of the readily-available diethyl 2,4-dicyanoglutaconate in a similar type of reaction. Such a reaction, if feasible, would permit the introduction of a seven-carbon residue which possesses reactive terminal functional groups. This would be of great value in synthetic organic chemistry."]},{"key":"dc:title","label":"Title","values":["Addition Reactions or Diethyl 2,4-dicyanoglutaconate"]}]}],"canonical_facts":{"dc:contributor.advisor":["Takemura, Kaz H."],"dc:creator":["Di Mari, Samuel J."],"dc:date.accessioned":["2017-01-20T22:02:00Z"],"dc:date.available":["2017-01-20T22:02:00Z"],"dc:date.issued":["1962"],"dc:description.abstract":["For many years, acrylonitrile has afforded the organic chemist a convenient method of introducing a three-carbon residue onto a variety of organic compounds by the so-called cyano-ethylation reaction. This reaction is generally brought about by a base-catalyzed, nucleophilic addition. The purpose of this work is to investigate and to evaluate the applicability of the readily-available diethyl 2,4-dicyanoglutaconate in a similar type of reaction. Such a reaction, if feasible, would permit the introduction of a seven-carbon residue which possesses reactive terminal functional groups. This would be of great value in synthetic organic chemistry."],"dc:identifier.uri":["http://hdl.handle.net/10504/109028"],"dc:language.iso":["en_US"],"dc:publisher":["Creighton University"],"dc:rights":["A non-exclusive distribution right is granted to Creighton University and to ProQuest following the publishing model selected above."],"dc:title":["Addition Reactions or Diethyl 2,4-dicyanoglutaconate"],"dc:type":["Thesis"]},"updated_at":"2026-07-24T01:52:24Z"}