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Cornell University

Coarse grained molecular dynamic of block copolymer directed self assembly on topographic substrate

Abstract

dc:description.abstract

Directed self-assembly (DSA) of block copolymer (BCP) is a promising and economic method of manufacturing periodic lamellar patterns on wafer that is widely used in semi-conductor and electronic fields. In BCP DSA lithography, same as issues in achieving defective free patterns and smooth edges, an evenly distributed width line space pattern is also critical but in lack of research. Comparing with experiment, simulation has many advantages on cost, accuracy and repeatability. Simulation has been very successful in predicting physical behaviors of systems and guiding the experiments. In this research, a coarse grained molecular dynamic (CGMD) simulation on polystyrene-b-poly (methyl methacrylate) (PS-b-PMMA) block copolymer DSA process using chemoepitaxial method was carried out. By changing BCP composition, substrate properties including topography and interaction strength, their effects on produced lamellae critical dimension (CD) variation, line space variation, roughness and tapering effect were investigated. It gives the direction of optimizing the substrate structure.

Degree

thesis:*
Name thesis:degree_name
M.S., Chemical Engineering
Level thesis:degree_level
Master of Science
Discipline thesis:degree_discipline
Chemical Engineering
Grantor
Cornell University
Year dc:date.issued
2020

Author and committee

dc:creator, dc:contributor.*
Author dc:creator
  • QIU, YUFENG
Committee members dc:contributor.committeemember
  • Ober, Christopher Kemper
  • Wiesner, Uli B.

Subjects

dc:subject × 4

Rights

Language dc:language.iso
en

Identifiers

dc:identifier.*
Dc Identifier Other
ProQuest Submission ID: 10997
ProQuest Publication ID: 28030645
OAI identifier oai:identifier
oai:ecommons.cornell.edu:1813/102999

Chain of custody

source
Harvested from
Cornell University
Base URL
ecommons.cornell.edu/server/oai/request
Last updated
2026-07-24
Source record
OAI-PMH GetRecord
citation

QIU, YUFENG. Coarse grained molecular dynamic of block copolymer directed self assembly on topographic substrate. Master of Science thesis, Cornell University, 2020. https://hdl.handle.net/1813/102999