Catalytic Oxidation of Methane Over Alumina Supported Palladium Oxides

<p>The objectives of this research include development and characterization of alumina supported palladium oxide catalysts for low temperature catalytic oxidation of methane. The catalysts were prepared by various methods and then characterized and screened to select the best catalyst for further studies. A 5% (wt/wt) Pd/y-AhCb catalyst prepared by an improved vortex-assisted incipient wetness method showed the best activity of 94% (mol/mol) methane conversion at 325 °C. The active surface species was found to be PdO and Pd native oxides (PdNtv) as confirmed by X-ray Photoelectron Spectroscopy and activity studies. The y-AhCb support played an integral role in the formation of Pd native oxides as well as a facilitator in oxygen mobility. INDEX</p>

Name thesis:degree_name

Chemistry

Level thesis:degree_level

Thesis

Discipline thesis:degree_discipline

Chemistry

Year dc:date.available

2018

Author dc:creator

• McGuire, Jacqueline Michelle

Contributors dc:contributor

• Dr. Anil C. Banerjee
• Dr. Zewdu Gebeyehu
• Dr. Daniel Wade Holley

• Supported Palladium Catalysts
• Palladium Oxide
• Palladium Native Oxide
• Aluminum Oxide
• Methane Oxidation
• Methane Combustion
• Chemistry
• Inorganic Chemistry

Language dc:language

English

Repository record dc:identifier

https://csuepress.columbusstate.edu/theses_dissertations/289

OAI identifier oai:identifier

oai:csuepress.columbusstate.edu:theses_dissertations-1294