{"id":{"repo_id":"columbia-diss","oai_identifier":"oai:academiccommons.columbia.edu:10.7916/D86W9JD8"},"canonical_url":"https://search.dev.ndltd.org/etd/columbia-diss/oai:academiccommons.columbia.edu:10.7916/D86W9JD8","repository":{"repo_id":"columbia-diss","name":"Columbia University","base_url":"https://academiccommons.columbia.edu/oai"},"display":{"title":"Synthetic Studies of the Yunnaneic Acids","abstract":"The total syntheses of yunnaneic acid C, yunnaneic acid D, and rufescenolide are described. The highly substituted bicyclic cores of these molecules were synthesized in a single step via a oxidative dearomatization/Diels-Alder cascade sequence from simple precursors. Dimerization studies towards yunnaneic acid A and yunnaneic acid B are also described, which resulted in the synthesis of several novel, non-natural structures.","abstract_html":"The total syntheses of yunnaneic acid C, yunnaneic acid D, and rufescenolide are described. The highly substituted bicyclic cores of these molecules were synthesized in a single step via a oxidative dearomatization/Diels-Alder cascade sequence from simple precursors. Dimerization studies towards yunnaneic acid A and yunnaneic acid B are also described, which resulted in the synthesis of several novel, non-natural structures.","abstract_has_math":false,"creators":["Griffith, Daniel"],"institution":null,"degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":[],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2013,"date_issued":"2013","date_published":"2013","updated_at":"2026-07-24T01:44:32Z","subjects":["Chemistry","Diels-Alder reaction","Natural products--Synthesis"],"languages":["English"],"rights":[],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"https://doi.org/10.7916/D86W9JD8","outbound_label":"DOI","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:creator","label":"Author","values":["Griffith, Daniel"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["2013"]},{"key":"dc:type","label":"Dc Type","values":["Theses"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Chemistry","Diels-Alder reaction","Natural products--Synthesis"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["English"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["https://doi.org/10.7916/D86W9JD8"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["The total syntheses of yunnaneic acid C, yunnaneic acid D, and rufescenolide are described. The highly substituted bicyclic cores of these molecules were synthesized in a single step via a oxidative dearomatization/Diels-Alder cascade sequence from simple precursors. Dimerization studies towards yunnaneic acid A and yunnaneic acid B are also described, which resulted in the synthesis of several novel, non-natural structures."]},{"key":"dc:title","label":"Title","values":["Synthetic Studies of the Yunnaneic Acids"]}]}],"canonical_facts":{"dc:creator":["Griffith, Daniel"],"dc:date":["2013"],"dc:description":["The total syntheses of yunnaneic acid C, yunnaneic acid D, and rufescenolide are described. The highly substituted bicyclic cores of these molecules were synthesized in a single step via a oxidative dearomatization/Diels-Alder cascade sequence from simple precursors. Dimerization studies towards yunnaneic acid A and yunnaneic acid B are also described, which resulted in the synthesis of several novel, non-natural structures."],"dc:identifier":["https://doi.org/10.7916/D86W9JD8"],"dc:language":["English"],"dc:subject":["Chemistry","Diels-Alder reaction","Natural products--Synthesis"],"dc:title":["Synthetic Studies of the Yunnaneic Acids"],"dc:type":["Theses"]},"updated_at":"2026-07-24T01:44:32Z"}