{"id":{"repo_id":"catania","oai_identifier":"oai:www.iris.unict.it:20.500.11769/586195"},"canonical_url":"https://search.dev.ndltd.org/etd/catania/oai:www.iris.unict.it:20.500.11769/586195","repository":{"repo_id":"catania","name":"Università degli Studi di Catania","base_url":"https://www.iris.unict.it/oai/request"},"display":{"title":"SYNTHESIS AND CHARACTERIATION OF WATER SOLUBLE C2 AND C3 SYMMETRIC MULTI-CALIX[4]ARENE DENDRIMERS AND PILLARARENES A NOVEL CLASS OF MACROCYCLE IN SUPRAMOLECULAR CHEMISTRY","abstract":"In this PhD work it was carried non-covalent synthesis of supramolecular modular systems homo-and hetero-component, through the use of pillararenes and calixarenes coupled to porphyrins; in particular it was designed to the preparation of discrete assembled at the nanoscopic level, by means of hierarchical 'self-assembly' of organized systems governed by electrostatic interactions and host-guest inclusion in aqueous phase and in organic solvents. Moreover was conducted the study of 'intelligent' chiral aggregates, obtained by inclusion of chiral centers in various structures.","abstract_html":"In this PhD work it was carried non-covalent synthesis of supramolecular modular systems homo-and hetero-component, through the use of pillararenes and calixarenes coupled to porphyrins; in particular it was designed to the preparation of discrete assembled at the nanoscopic level, by means of hierarchical 'self-assembly' of organized systems governed by electrostatic interactions and host-guest inclusion in aqueous phase and in organic solvents. Moreover was conducted the study of 'intelligent' chiral aggregates, obtained by inclusion of chiral centers in various structures.","abstract_has_math":false,"creators":["MARINO, NINO"],"institution":"Università degli studi di Catania","degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":["PURRELLO, Roberto"],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2013,"date_issued":"2013-12-10","date_published":"2013-12-10","updated_at":"2026-07-24T01:35:15Z","subjects":["supramolecular chemistry, calixarenes, dendrimers, pillararenes"],"languages":["eng"],"rights":["info:eu-repo/semantics/openAccess","license:PUBBLICO - Pubblico con Copyright","license uri:iris.PUB02"],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"https://hdl.handle.net/20.500.11769/586195","outbound_label":"Handle","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["Marino, Nino","PURRELLO, Roberto"]},{"key":"dc:creator","label":"Author","values":["MARINO, NINO"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["2013-12-10"]},{"key":"dc:publisher","label":"Institution","values":["Università degli studi di Catania","place:Catania"]},{"key":"dc:type","label":"Dc Type","values":["info:eu-repo/semantics/doctoralThesis"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["supramolecular chemistry, calixarenes, dendrimers, pillararenes"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["eng"]},{"key":"dc:rights","label":"Dc Rights","values":["info:eu-repo/semantics/openAccess","license:PUBBLICO - Pubblico con Copyright","license uri:iris.PUB02"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["https://hdl.handle.net/20.500.11769/586195"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["In this PhD work it was carried non-covalent synthesis of supramolecular modular systems homo-and hetero-component, through the use of pillararenes and calixarenes coupled to porphyrins; in particular it was designed to the preparation of discrete assembled at the nanoscopic level, by means of hierarchical 'self-assembly' of organized systems governed by electrostatic interactions and host-guest inclusion in aqueous phase and in organic solvents. Moreover was conducted the study of 'intelligent' chiral aggregates, obtained by inclusion of chiral centers in various structures.","In questo lavoro di dottorato è stata condotta la sintesi non-covalente di sistemi modulari supramolecolari omo ed etero-componente, attraverso l'uso di pillararenes, e calixareni accoppiati alle porfirine, in particolare in questo lavoro è stata progettata la preparazione di discreti assemblati a livello nanoscopica, tramite 'self-assembly' gerarchico di sistemi organizzati e governati da interazioni elettrostatiche e l'inclusione host-guest in fase acquosa e in solventi organici. Inoltre è stato condotto lo studio degli aggregati chirali 'intelligenti', ottenuti mediante l'inserimento di centri chirali nelle varie strutture."]},{"key":"dc:title","label":"Title","values":["SYNTHESIS AND CHARACTERIATION OF WATER SOLUBLE C2 AND C3 SYMMETRIC MULTI-CALIX[4]ARENE DENDRIMERS AND PILLARARENES A NOVEL CLASS OF MACROCYCLE IN SUPRAMOLECULAR CHEMISTRY"]}]}],"canonical_facts":{"dc:contributor":["Marino, Nino","PURRELLO, Roberto"],"dc:creator":["MARINO, NINO"],"dc:date":["2013-12-10"],"dc:description":["In this PhD work it was carried non-covalent synthesis of supramolecular modular systems homo-and hetero-component, through the use of pillararenes and calixarenes coupled to porphyrins; in particular it was designed to the preparation of discrete assembled at the nanoscopic level, by means of hierarchical 'self-assembly' of organized systems governed by electrostatic interactions and host-guest inclusion in aqueous phase and in organic solvents. Moreover was conducted the study of 'intelligent' chiral aggregates, obtained by inclusion of chiral centers in various structures.","In questo lavoro di dottorato è stata condotta la sintesi non-covalente di sistemi modulari supramolecolari omo ed etero-componente, attraverso l'uso di pillararenes, e calixareni accoppiati alle porfirine, in particolare in questo lavoro è stata progettata la preparazione di discreti assemblati a livello nanoscopica, tramite 'self-assembly' gerarchico di sistemi organizzati e governati da interazioni elettrostatiche e l'inclusione host-guest in fase acquosa e in solventi organici. Inoltre è stato condotto lo studio degli aggregati chirali 'intelligenti', ottenuti mediante l'inserimento di centri chirali nelle varie strutture."],"dc:identifier":["https://hdl.handle.net/20.500.11769/586195"],"dc:language":["eng"],"dc:publisher":["Università degli studi di Catania","place:Catania"],"dc:rights":["info:eu-repo/semantics/openAccess","license:PUBBLICO - Pubblico con Copyright","license uri:iris.PUB02"],"dc:subject":["supramolecular chemistry, calixarenes, dendrimers, pillararenes"],"dc:title":["SYNTHESIS AND CHARACTERIATION OF WATER SOLUBLE C2 AND C3 SYMMETRIC MULTI-CALIX[4]ARENE DENDRIMERS AND PILLARARENES A NOVEL CLASS OF MACROCYCLE IN SUPRAMOLECULAR CHEMISTRY"],"dc:type":["info:eu-repo/semantics/doctoralThesis"]},"updated_at":"2026-07-24T01:35:15Z"}