{"id":{"repo_id":"cape-town","oai_identifier":"oai:open.uct.ac.za:11427/9772"},"canonical_url":"https://search.dev.ndltd.org/etd/cape-town/oai:open.uct.ac.za:11427/9772","repository":{"repo_id":"cape-town","name":"University of Cape Town","base_url":"https://open.uct.ac.za/oai/request"},"display":{"title":"Synthetic, structural and molecular modelling studies of organoiron complexes of catalytic importance","abstract":"The synthesis and characterization of a series of new alkyl dicarbonyl pentaznethylcyclopentadienyl iron compounds, [(η⁵-C₅(CH₃)₅)Fe(CO)₂R], is the starting point for an investigation of these compounds and their relevance as models for catalytic reactions. The compounds have been synthesized by the reaction of Na[(η⁵-C₅(CH₃)₅)Fe(CO)₂] with the appropriate n-alkyl chloride or bromide (R=n-C₃H₇ to n-C₁₂H₂₅). The majority of the compounds are new and have been fully characterized by microanalysis, IR, ¹H, and ¹³C NMR and mass spectrometry. The data are discussed and some properties and reactions of the compounds are described.","abstract_html":"The synthesis and characterization of a series of new alkyl dicarbonyl pentaznethylcyclopentadienyl iron compounds, [(η⁵-C₅(CH₃)₅)Fe(CO)₂R], is the starting point for an investigation of these compounds and their relevance as models for catalytic reactions. The compounds have been synthesized by the reaction of Na[(η⁵-C₅(CH₃)₅)Fe(CO)₂] with the appropriate n-alkyl chloride or bromide (R=n-C₃H₇ to n-C₁₂H₂₅). The majority of the compounds are new and have been fully characterized by microanalysis, IR, ¹H, and ¹³C NMR and mass spectrometry. The data are discussed and some properties and reactions of the compounds are described.","abstract_has_math":false,"creators":["Hill, Robert Oliver"],"institution":"Department of Chemistry","degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":[],"advisors":["Moss, John R","Marias, Charles","Naidoo, Kevin J"],"committee_chairs":[],"committee_members":[],"year":1999,"date_issued":"1999","date_published":"1999","updated_at":"2026-07-22T22:22:52Z","subjects":[],"languages":["eng"],"rights":[],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"http://hdl.handle.net/11427/9772","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.advisor","label":"Advisor","values":["Moss, John R","Marias, Charles","Naidoo, Kevin J"]},{"key":"dc:creator","label":"Author","values":["Hill, Robert Oliver"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.accessioned","label":"Dc Date Accessioned","values":["2014-11-21T16:15:23Z"]},{"key":"dc:date.available","label":"Dc Date Available","values":["2014-11-21T16:15:23Z"]},{"key":"dc:date.issued","label":"Date","values":["1999"]},{"key":"dc:publisher.department","label":"Dc Publisher Department","values":["Department of Chemistry"]},{"key":"dc:publisher.institution","label":"Dc Publisher Institution","values":["University of Cape Town"]},{"key":"dc:type","label":"Dc Type","values":["Doctoral Thesis"]},{"key":"dc:type.qualificationlevel","label":"Dc Type Qualificationlevel","values":["Doctoral"]},{"key":"dc:type.qualificationname","label":"Dc Type Qualificationname","values":["PhD"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language.iso","label":"Language (ISO)","values":["eng"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier.uri","label":"Identifier URI","values":["http://hdl.handle.net/11427/9772"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["Includes bibliography."]},{"key":"dc:description.abstract","label":"Abstract","values":["The synthesis and characterization of a series of new alkyl dicarbonyl pentaznethylcyclopentadienyl iron compounds, [(η⁵-C₅(CH₃)₅)Fe(CO)₂R], is the starting point for an investigation of these compounds and their relevance as models for catalytic reactions. The compounds have been synthesized by the reaction of Na[(η⁵-C₅(CH₃)₅)Fe(CO)₂] with the appropriate n-alkyl chloride or bromide (R=n-C₃H₇ to n-C₁₂H₂₅). The majority of the compounds are new and have been fully characterized by microanalysis, IR, ¹H, and ¹³C NMR and mass spectrometry. The data are discussed and some properties and reactions of the compounds are described."]},{"key":"dc:title","label":"Title","values":["Synthetic, structural and molecular modelling studies of organoiron complexes of catalytic importance"]}]}],"canonical_facts":{"dc:contributor.advisor":["Moss, John R","Marias, Charles","Naidoo, Kevin J"],"dc:creator":["Hill, Robert Oliver"],"dc:date.accessioned":["2014-11-21T16:15:23Z"],"dc:date.available":["2014-11-21T16:15:23Z"],"dc:date.issued":["1999"],"dc:description":["Includes bibliography."],"dc:description.abstract":["The synthesis and characterization of a series of new alkyl dicarbonyl pentaznethylcyclopentadienyl iron compounds, [(η⁵-C₅(CH₃)₅)Fe(CO)₂R], is the starting point for an investigation of these compounds and their relevance as models for catalytic reactions. The compounds have been synthesized by the reaction of Na[(η⁵-C₅(CH₃)₅)Fe(CO)₂] with the appropriate n-alkyl chloride or bromide (R=n-C₃H₇ to n-C₁₂H₂₅). The majority of the compounds are new and have been fully characterized by microanalysis, IR, ¹H, and ¹³C NMR and mass spectrometry. The data are discussed and some properties and reactions of the compounds are described."],"dc:identifier.uri":["http://hdl.handle.net/11427/9772"],"dc:language.iso":["eng"],"dc:publisher.department":["Department of Chemistry"],"dc:publisher.institution":["University of Cape Town"],"dc:title":["Synthetic, structural and molecular modelling studies of organoiron complexes of catalytic importance"],"dc:type":["Doctoral Thesis"],"dc:type.qualificationlevel":["Doctoral"],"dc:type.qualificationname":["PhD"]},"updated_at":"2026-07-22T22:22:52Z"}