{"id":{"repo_id":"cape-town","oai_identifier":"oai:open.uct.ac.za:11427/8616"},"canonical_url":"https://search.dev.ndltd.org/etd/cape-town/oai:open.uct.ac.za:11427/8616","repository":{"repo_id":"cape-town","name":"University of Cape Town","base_url":"https://open.uct.ac.za/oai/request"},"display":{"title":"Platinum group metal coordination complexes of ferrocenyl N-donor ligands and their potential application in catalysis and medicinal chemistry","abstract":"In this project a series of multinuclear complexes were successfully prepared and characterised using an array of analytical techniques. The use of nitrogen-donor ligands, in particular pyridine and ferrocenyl derivatives thereof was examined. Two main approaches were taken in the preparation of the ferrocenylpyridines: i. The ferrocenylpyridines were systematically studied by varying the position of substituents along the pyridyl ring in the 4-,3-and 2-positions. ii. The effect of placing spacer groups between the ferrocenyl group and the pendant pyridine was examined. iii. The ligands were prepared with a system of conjugated π bonds, allowing for an electronic pathway within the ligand.","abstract_html":"In this project a series of multinuclear complexes were successfully prepared and characterised using an array of analytical techniques. The use of nitrogen-donor ligands, in particular pyridine and ferrocenyl derivatives thereof was examined. Two main approaches were taken in the preparation of the ferrocenylpyridines: i. The ferrocenylpyridines were systematically studied by varying the position of substituents along the pyridyl ring in the 4-,3-and 2-positions. ii. The effect of placing spacer groups between the ferrocenyl group and the pendant pyridine was examined. iii. The ligands were prepared with a system of conjugated π bonds, allowing for an electronic pathway within the ligand.","abstract_has_math":false,"creators":["Rajput, Jaisheila"],"institution":"Department of Chemistry","degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":[],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2003,"date_issued":"2003","date_published":"2003","updated_at":"2026-07-22T22:23:49Z","subjects":[],"languages":["eng"],"rights":[],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"http://hdl.handle.net/11427/8616","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:creator","label":"Author","values":["Rajput, Jaisheila"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.accessioned","label":"Dc Date Accessioned","values":["2014-10-18T06:06:02Z"]},{"key":"dc:date.available","label":"Dc Date Available","values":["2014-10-18T06:06:02Z"]},{"key":"dc:date.issued","label":"Date","values":["2003"]},{"key":"dc:publisher.department","label":"Dc Publisher Department","values":["Department of Chemistry"]},{"key":"dc:publisher.institution","label":"Dc Publisher Institution","values":["University of Cape Town"]},{"key":"dc:type","label":"Dc Type","values":["Doctoral Thesis"]},{"key":"dc:type.qualificationlevel","label":"Dc Type Qualificationlevel","values":["Doctoral"]},{"key":"dc:type.qualificationname","label":"Dc Type Qualificationname","values":["PhD"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language.iso","label":"Language (ISO)","values":["eng"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier.uri","label":"Identifier URI","values":["http://hdl.handle.net/11427/8616"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["Includes bibliographical references."]},{"key":"dc:description.abstract","label":"Abstract","values":["In this project a series of multinuclear complexes were successfully prepared and characterised using an array of analytical techniques. The use of nitrogen-donor ligands, in particular pyridine and ferrocenyl derivatives thereof was examined. Two main approaches were taken in the preparation of the ferrocenylpyridines: i. The ferrocenylpyridines were systematically studied by varying the position of substituents along the pyridyl ring in the 4-,3-and 2-positions. ii. The effect of placing spacer groups between the ferrocenyl group and the pendant pyridine was examined. iii. The ligands were prepared with a system of conjugated π bonds, allowing for an electronic pathway within the ligand."]},{"key":"dc:title","label":"Title","values":["Platinum group metal coordination complexes of ferrocenyl N-donor ligands and their potential application in catalysis and medicinal chemistry"]}]}],"canonical_facts":{"dc:creator":["Rajput, Jaisheila"],"dc:date.accessioned":["2014-10-18T06:06:02Z"],"dc:date.available":["2014-10-18T06:06:02Z"],"dc:date.issued":["2003"],"dc:description":["Includes bibliographical references."],"dc:description.abstract":["In this project a series of multinuclear complexes were successfully prepared and characterised using an array of analytical techniques. The use of nitrogen-donor ligands, in particular pyridine and ferrocenyl derivatives thereof was examined. Two main approaches were taken in the preparation of the ferrocenylpyridines: i. The ferrocenylpyridines were systematically studied by varying the position of substituents along the pyridyl ring in the 4-,3-and 2-positions. ii. The effect of placing spacer groups between the ferrocenyl group and the pendant pyridine was examined. iii. The ligands were prepared with a system of conjugated π bonds, allowing for an electronic pathway within the ligand."],"dc:identifier.uri":["http://hdl.handle.net/11427/8616"],"dc:language.iso":["eng"],"dc:publisher.department":["Department of Chemistry"],"dc:publisher.institution":["University of Cape Town"],"dc:title":["Platinum group metal coordination complexes of ferrocenyl N-donor ligands and their potential application in catalysis and medicinal chemistry"],"dc:type":["Doctoral Thesis"],"dc:type.qualificationlevel":["Doctoral"],"dc:type.qualificationname":["PhD"]},"updated_at":"2026-07-22T22:23:49Z"}