{"id":{"repo_id":"cape-town","oai_identifier":"oai:open.uct.ac.za:11427/6341"},"canonical_url":"https://search.dev.ndltd.org/etd/cape-town/oai:open.uct.ac.za:11427/6341","repository":{"repo_id":"cape-town","name":"University of Cape Town","base_url":"https://open.uct.ac.za/oai/request"},"display":{"title":"Crystal engineering of novel organic-inorganic compounds of N- and O-donor dipyridyl ligands","abstract":"Crystal engineering based upon organic-inorganic compounds has made rapid progress in recent years. These compounds are known to combine the inherent advantages of both organic and inorganic substances. In this thesis, a range of metal compounds were investigated. These include compounds of actinides, lanthanides, transition and main group metals using dipyridyl ligands (4,4'-bipyridine-N,N'-dioxide (bpdo), 1,2-bis(4-pyridyl)ethane (BPE) and 1,2-di(4-pyridyl)ethylene (OPE) Compounds prepared were characterised by x-ray diffractometry. Thermal analysis (thermogravimetry (TG), differential scanning calorimetry (DSC) and hot stage microscopy (HSM)) was used to determine the thermal behaviour of these compounds. Microanalysis was used to confirm elemental composition.","abstract_html":"Crystal engineering based upon organic-inorganic compounds has made rapid progress in recent years. These compounds are known to combine the inherent advantages of both organic and inorganic substances. In this thesis, a range of metal compounds were investigated. These include compounds of actinides, lanthanides, transition and main group metals using dipyridyl ligands (4,4'-bipyridine-N,N'-dioxide (bpdo), 1,2-bis(4-pyridyl)ethane (BPE) and 1,2-di(4-pyridyl)ethylene (OPE) Compounds prepared were characterised by x-ray diffractometry. Thermal analysis (thermogravimetry (TG), differential scanning calorimetry (DSC) and hot stage microscopy (HSM)) was used to determine the thermal behaviour of these compounds. Microanalysis was used to confirm elemental composition.","abstract_has_math":false,"creators":["Moitsheki, Lesego J"],"institution":"Department of Chemistry","degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":[],"advisors":["Bourne, Susan A","Nassimbeni, Luigi R"],"committee_chairs":[],"committee_members":[],"year":2006,"date_issued":"2006","date_published":"2006","updated_at":"2026-07-22T22:23:30Z","subjects":[],"languages":["eng"],"rights":[],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"http://hdl.handle.net/11427/6341","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.advisor","label":"Advisor","values":["Bourne, Susan A","Nassimbeni, Luigi R"]},{"key":"dc:creator","label":"Author","values":["Moitsheki, Lesego J"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.accessioned","label":"Dc Date Accessioned","values":["2014-08-13T14:27:25Z"]},{"key":"dc:date.available","label":"Dc Date Available","values":["2014-08-13T14:27:25Z"]},{"key":"dc:date.issued","label":"Date","values":["2006"]},{"key":"dc:publisher.department","label":"Dc Publisher Department","values":["Department of Chemistry"]},{"key":"dc:publisher.institution","label":"Dc Publisher Institution","values":["University of Cape Town"]},{"key":"dc:type","label":"Dc Type","values":["Doctoral Thesis"]},{"key":"dc:type.qualificationlevel","label":"Dc Type Qualificationlevel","values":["Doctoral"]},{"key":"dc:type.qualificationname","label":"Dc Type Qualificationname","values":["PhD"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language.iso","label":"Language (ISO)","values":["eng"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier.uri","label":"Identifier URI","values":["http://hdl.handle.net/11427/6341"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["Includes bibliographical references."]},{"key":"dc:description.abstract","label":"Abstract","values":["Crystal engineering based upon organic-inorganic compounds has made rapid progress in recent years. These compounds are known to combine the inherent advantages of both organic and inorganic substances. In this thesis, a range of metal compounds were investigated. These include compounds of actinides, lanthanides, transition and main group metals using dipyridyl ligands (4,4'-bipyridine-N,N'-dioxide (bpdo), 1,2-bis(4-pyridyl)ethane (BPE) and 1,2-di(4-pyridyl)ethylene (OPE) Compounds prepared were characterised by x-ray diffractometry. Thermal analysis (thermogravimetry (TG), differential scanning calorimetry (DSC) and hot stage microscopy (HSM)) was used to determine the thermal behaviour of these compounds. Microanalysis was used to confirm elemental composition."]},{"key":"dc:title","label":"Title","values":["Crystal engineering of novel organic-inorganic compounds of N- and O-donor dipyridyl ligands"]}]}],"canonical_facts":{"dc:contributor.advisor":["Bourne, Susan A","Nassimbeni, Luigi R"],"dc:creator":["Moitsheki, Lesego J"],"dc:date.accessioned":["2014-08-13T14:27:25Z"],"dc:date.available":["2014-08-13T14:27:25Z"],"dc:date.issued":["2006"],"dc:description":["Includes bibliographical references."],"dc:description.abstract":["Crystal engineering based upon organic-inorganic compounds has made rapid progress in recent years. These compounds are known to combine the inherent advantages of both organic and inorganic substances. In this thesis, a range of metal compounds were investigated. These include compounds of actinides, lanthanides, transition and main group metals using dipyridyl ligands (4,4'-bipyridine-N,N'-dioxide (bpdo), 1,2-bis(4-pyridyl)ethane (BPE) and 1,2-di(4-pyridyl)ethylene (OPE) Compounds prepared were characterised by x-ray diffractometry. Thermal analysis (thermogravimetry (TG), differential scanning calorimetry (DSC) and hot stage microscopy (HSM)) was used to determine the thermal behaviour of these compounds. Microanalysis was used to confirm elemental composition."],"dc:identifier.uri":["http://hdl.handle.net/11427/6341"],"dc:language.iso":["eng"],"dc:publisher.department":["Department of Chemistry"],"dc:publisher.institution":["University of Cape Town"],"dc:title":["Crystal engineering of novel organic-inorganic compounds of N- and O-donor dipyridyl ligands"],"dc:type":["Doctoral Thesis"],"dc:type.qualificationlevel":["Doctoral"],"dc:type.qualificationname":["PhD"]},"updated_at":"2026-07-22T22:23:30Z"}