{"id":{"repo_id":"cape-town","oai_identifier":"oai:open.uct.ac.za:11427/6328"},"canonical_url":"https://search.dev.ndltd.org/etd/cape-town/oai:open.uct.ac.za:11427/6328","repository":{"repo_id":"cape-town","name":"University of Cape Town","base_url":"https://open.uct.ac.za/oai/request"},"display":{"title":"The synthesis, characterization and decomposition studies of novel palladacycloalkanes and their precursors","abstract":"The synthesis and characterization of palladacycloheptane and palladacyclononane complexes based on 1,5-cyclooctadiene (COD), 2,2'bipyridine (bipy), triphenylphosphine (PPh3), and 1,2-bis(diphenylphosphino)ethane (dppe), and their precursors were successfully carried out. The complexes were characterized by 1H, 13C and 31p NMR spectroscopy, mass spectrometry as well as elemental analysis. The palladacycloalkanes were prepared from the bis(alkenyl) complexes of the type cis-[Pd{(CH2)nCH=CH2hL21 (n = 2, 3; L = PPh3; L2 = COD, bipy, dppe) by ring closing metathesis (RCM) reactions followed by hydrogenation.","abstract_html":"The synthesis and characterization of palladacycloheptane and palladacyclononane complexes based on 1,5-cyclooctadiene (COD), 2,2'bipyridine (bipy), triphenylphosphine (PPh3), and 1,2-bis(diphenylphosphino)ethane (dppe), and their precursors were successfully carried out. The complexes were characterized by 1H, 13C and 31p NMR spectroscopy, mass spectrometry as well as elemental analysis. The palladacycloalkanes were prepared from the bis(alkenyl) complexes of the type cis-[Pd{(CH2)nCH=CH2hL21 (n = 2, 3; L = PPh3; L2 = COD, bipy, dppe) by ring closing metathesis (RCM) reactions followed by hydrogenation.","abstract_has_math":false,"creators":["Mahamo, Tebello"],"institution":"Department of Chemistry","degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":[],"advisors":["Moss, John R","Smith, Gregory"],"committee_chairs":[],"committee_members":[],"year":2007,"date_issued":"2007","date_published":"2007","updated_at":"2026-07-22T22:22:46Z","subjects":[],"languages":["eng"],"rights":[],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"http://hdl.handle.net/11427/6328","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.advisor","label":"Advisor","values":["Moss, John R","Smith, Gregory"]},{"key":"dc:creator","label":"Author","values":["Mahamo, Tebello"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.accessioned","label":"Dc Date Accessioned","values":["2014-08-13T14:26:57Z"]},{"key":"dc:date.available","label":"Dc Date Available","values":["2014-08-13T14:26:57Z"]},{"key":"dc:date.issued","label":"Date","values":["2007"]},{"key":"dc:publisher.department","label":"Dc Publisher Department","values":["Department of Chemistry"]},{"key":"dc:publisher.institution","label":"Dc Publisher Institution","values":["University of Cape Town"]},{"key":"dc:type","label":"Dc Type","values":["Master Thesis"]},{"key":"dc:type.qualificationlevel","label":"Dc Type Qualificationlevel","values":["Masters"]},{"key":"dc:type.qualificationname","label":"Dc Type Qualificationname","values":["MSc"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language.iso","label":"Language (ISO)","values":["eng"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier.uri","label":"Identifier URI","values":["http://hdl.handle.net/11427/6328"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["Includes bibliographical references (leaf 100)."]},{"key":"dc:description.abstract","label":"Abstract","values":["The synthesis and characterization of palladacycloheptane and palladacyclononane complexes based on 1,5-cyclooctadiene (COD), 2,2'bipyridine (bipy), triphenylphosphine (PPh3), and 1,2-bis(diphenylphosphino)ethane (dppe), and their precursors were successfully carried out. The complexes were characterized by 1H, 13C and 31p NMR spectroscopy, mass spectrometry as well as elemental analysis. The palladacycloalkanes were prepared from the bis(alkenyl) complexes of the type cis-[Pd{(CH2)nCH=CH2hL21 (n = 2, 3; L = PPh3; L2 = COD, bipy, dppe) by ring closing metathesis (RCM) reactions followed by hydrogenation."]},{"key":"dc:title","label":"Title","values":["The synthesis, characterization and decomposition studies of novel palladacycloalkanes and their precursors"]}]}],"canonical_facts":{"dc:contributor.advisor":["Moss, John R","Smith, Gregory"],"dc:creator":["Mahamo, Tebello"],"dc:date.accessioned":["2014-08-13T14:26:57Z"],"dc:date.available":["2014-08-13T14:26:57Z"],"dc:date.issued":["2007"],"dc:description":["Includes bibliographical references (leaf 100)."],"dc:description.abstract":["The synthesis and characterization of palladacycloheptane and palladacyclononane complexes based on 1,5-cyclooctadiene (COD), 2,2'bipyridine (bipy), triphenylphosphine (PPh3), and 1,2-bis(diphenylphosphino)ethane (dppe), and their precursors were successfully carried out. The complexes were characterized by 1H, 13C and 31p NMR spectroscopy, mass spectrometry as well as elemental analysis. The palladacycloalkanes were prepared from the bis(alkenyl) complexes of the type cis-[Pd{(CH2)nCH=CH2hL21 (n = 2, 3; L = PPh3; L2 = COD, bipy, dppe) by ring closing metathesis (RCM) reactions followed by hydrogenation."],"dc:identifier.uri":["http://hdl.handle.net/11427/6328"],"dc:language.iso":["eng"],"dc:publisher.department":["Department of Chemistry"],"dc:publisher.institution":["University of Cape Town"],"dc:title":["The synthesis, characterization and decomposition studies of novel palladacycloalkanes and their precursors"],"dc:type":["Master Thesis"],"dc:type.qualificationlevel":["Masters"],"dc:type.qualificationname":["MSc"]},"updated_at":"2026-07-22T22:22:46Z"}