{"id":{"repo_id":"cape-town","oai_identifier":"oai:open.uct.ac.za:11427/40435"},"canonical_url":"https://search.dev.ndltd.org/etd/cape-town/oai:open.uct.ac.za:11427/40435","repository":{"repo_id":"cape-town","name":"University of Cape Town","base_url":"https://open.uct.ac.za/oai/request"},"display":{"title":"Application of crystal field theory to the infrared spectra of transition metal complexes","abstract":"[pages missing] problem in the IR spectra of 8-quinolinol chelqtes of di~ and trivalent metals of the first transition series. The metal-sensitivity of bands in the IR spectra of structura~ly differing substituted 8-quinolinol Qhelates ~eceives an interpretation in terms of crystal field theory. The effect of halogen and methyl substituents in the I~ spectra of the Cu(II) chelates is consistent with the band assignments based on crystal field effects P.nd is relat;.ep to both the resonance and inductive capacities of th~ substituents. A total of 232 compounds have been synthesized and are discussed.","abstract_html":"[pages missing] problem in the IR spectra of 8-quinolinol chelqtes of di~ and trivalent metals of the first transition series. The metal-sensitivity of bands in the IR spectra of structura~ly differing substituted 8-quinolinol Qhelates ~eceives an interpretation in terms of crystal field theory. The effect of halogen and methyl substituents in the I~ spectra of the Cu(II) chelates is consistent with the band assignments based on crystal field effects P.nd is relat;.ep to both the resonance and inductive capacities of th~ substituents. A total of 232 compounds have been synthesized and are discussed.","abstract_has_math":false,"creators":["Shephard, Gordon Seymour"],"institution":"Department of Chemistry","degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":[],"advisors":["Thornton, David A"],"committee_chairs":[],"committee_members":[],"year":1973,"date_issued":"1973","date_published":"1973","updated_at":"2026-07-22T22:23:35Z","subjects":["Chemistry"],"languages":[],"rights":[],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"http://hdl.handle.net/11427/40435","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.advisor","label":"Advisor","values":["Thornton, David A"]},{"key":"dc:creator","label":"Author","values":["Shephard, Gordon Seymour"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.accessioned","label":"Dc Date Accessioned","values":["2024-07-23T12:46:36Z"]},{"key":"dc:date.available","label":"Dc Date Available","values":["2024-07-23T12:46:36Z"]},{"key":"dc:date.issued","label":"Date","values":["1973"]},{"key":"dc:publisher.department","label":"Dc Publisher Department","values":["Department of Chemistry"]},{"key":"dc:type","label":"Dc Type","values":["Thesis / Dissertation"]},{"key":"dc:type.qualificationlevel","label":"Dc Type Qualificationlevel","values":["Doctoral","PhD"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Chemistry"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier.uri","label":"Identifier URI","values":["http://hdl.handle.net/11427/40435"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["[pages missing] problem in the IR spectra of 8-quinolinol chelqtes of di~ and trivalent metals of the first transition series. The metal-sensitivity of bands in the IR spectra of structura~ly differing substituted 8-quinolinol Qhelates ~eceives an interpretation in terms of crystal field theory. The effect of halogen and methyl substituents in the I~ spectra of the Cu(II) chelates is consistent with the band assignments based on crystal field effects P.nd is relat;.ep to both the resonance and inductive capacities of th~ substituents. A total of 232 compounds have been synthesized and are discussed."]},{"key":"dc:title","label":"Title","values":["Application of crystal field theory to the infrared spectra of transition metal complexes"]}]}],"canonical_facts":{"dc:contributor.advisor":["Thornton, David A"],"dc:creator":["Shephard, Gordon Seymour"],"dc:date.accessioned":["2024-07-23T12:46:36Z"],"dc:date.available":["2024-07-23T12:46:36Z"],"dc:date.issued":["1973"],"dc:description.abstract":["[pages missing] problem in the IR spectra of 8-quinolinol chelqtes of di~ and trivalent metals of the first transition series. The metal-sensitivity of bands in the IR spectra of structura~ly differing substituted 8-quinolinol Qhelates ~eceives an interpretation in terms of crystal field theory. The effect of halogen and methyl substituents in the I~ spectra of the Cu(II) chelates is consistent with the band assignments based on crystal field effects P.nd is relat;.ep to both the resonance and inductive capacities of th~ substituents. A total of 232 compounds have been synthesized and are discussed."],"dc:identifier.uri":["http://hdl.handle.net/11427/40435"],"dc:publisher.department":["Department of Chemistry"],"dc:subject":["Chemistry"],"dc:title":["Application of crystal field theory to the infrared spectra of transition metal complexes"],"dc:type":["Thesis / Dissertation"],"dc:type.qualificationlevel":["Doctoral","PhD"]},"updated_at":"2026-07-22T22:23:35Z"}