{"id":{"repo_id":"cape-town","oai_identifier":"oai:open.uct.ac.za:11427/22273"},"canonical_url":"https://search.dev.ndltd.org/etd/cape-town/oai:open.uct.ac.za:11427/22273","repository":{"repo_id":"cape-town","name":"University of Cape Town","base_url":"https://open.uct.ac.za/oai/request"},"display":{"title":"A study of the self-diffusion of certain of the lower alkyl halides","abstract":"The self-diffusion coefficients of Mel, and Et-, nPris-,isoPr-, nBu-, isoBu- and secBu-iodides and bromides were determined by application of the capillary tube method and using iodine-131 and bromine-82 for labelling the compounds. Viscosities were measured for those compounds for which the data in the literature were insufficient for calculation of energies of activation. The diffusion coefficients were of the order of 2 x 10⁻⁵ cm².sec⁻ with activation energies of 2 kcal./mole; determined from plots of log D/T versus l/T. The temperatures at which coefficients were measured were 7.35, 19.35 and 30.00° C. The activation energies measured agreed with those for viscous flow as is required by the theories of Frenkel and Eyring.","abstract_html":"The self-diffusion coefficients of Mel, and Et-, nPris-,isoPr-, nBu-, isoBu- and secBu-iodides and bromides were determined by application of the capillary tube method and using iodine-131 and bromine-82 for labelling the compounds. Viscosities were measured for those compounds for which the data in the literature were insufficient for calculation of energies of activation. The diffusion coefficients were of the order of 2 x 10⁻⁵ cm².sec⁻ with activation energies of 2 kcal./mole; determined from plots of log D/T versus l/T. The temperatures at which coefficients were measured were 7.35, 19.35 and 30.00° C. The activation energies measured agreed with those for viscous flow as is required by the theories of Frenkel and Eyring.","abstract_has_math":false,"creators":["Stein, Louis Henry"],"institution":"Department of Chemistry","degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":[],"advisors":["Carman, P C","Spong, A H"],"committee_chairs":[],"committee_members":[],"year":1955,"date_issued":"1955","date_published":"1955","updated_at":"2026-07-22T22:23:30Z","subjects":[],"languages":["eng"],"rights":[],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"http://hdl.handle.net/11427/22273","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.advisor","label":"Advisor","values":["Carman, P C","Spong, A H"]},{"key":"dc:creator","label":"Author","values":["Stein, Louis Henry"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.accessioned","label":"Dc Date Accessioned","values":["2016-10-24T03:50:28Z"]},{"key":"dc:date.available","label":"Dc Date Available","values":["2016-10-24T03:50:28Z"]},{"key":"dc:date.issued","label":"Date","values":["1955"]},{"key":"dc:publisher.department","label":"Dc Publisher Department","values":["Department of Chemistry"]},{"key":"dc:publisher.institution","label":"Dc Publisher Institution","values":["University of Cape Town"]},{"key":"dc:type","label":"Dc Type","values":["Doctoral Thesis"]},{"key":"dc:type.qualificationlevel","label":"Dc Type Qualificationlevel","values":["Doctoral"]},{"key":"dc:type.qualificationname","label":"Dc Type Qualificationname","values":["PhD"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language.iso","label":"Language (ISO)","values":["eng"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier.uri","label":"Identifier URI","values":["http://hdl.handle.net/11427/22273"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["The self-diffusion coefficients of Mel, and Et-, nPris-,isoPr-, nBu-, isoBu- and secBu-iodides and bromides were determined by application of the capillary tube method and using iodine-131 and bromine-82 for labelling the compounds. Viscosities were measured for those compounds for which the data in the literature were insufficient for calculation of energies of activation. The diffusion coefficients were of the order of 2 x 10⁻⁵ cm².sec⁻ with activation energies of 2 kcal./mole; determined from plots of log D/T versus l/T. The temperatures at which coefficients were measured were 7.35, 19.35 and 30.00° C. The activation energies measured agreed with those for viscous flow as is required by the theories of Frenkel and Eyring."]},{"key":"dc:title","label":"Title","values":["A study of the self-diffusion of certain of the lower alkyl halides"]}]}],"canonical_facts":{"dc:contributor.advisor":["Carman, P C","Spong, A H"],"dc:creator":["Stein, Louis Henry"],"dc:date.accessioned":["2016-10-24T03:50:28Z"],"dc:date.available":["2016-10-24T03:50:28Z"],"dc:date.issued":["1955"],"dc:description.abstract":["The self-diffusion coefficients of Mel, and Et-, nPris-,isoPr-, nBu-, isoBu- and secBu-iodides and bromides were determined by application of the capillary tube method and using iodine-131 and bromine-82 for labelling the compounds. Viscosities were measured for those compounds for which the data in the literature were insufficient for calculation of energies of activation. The diffusion coefficients were of the order of 2 x 10⁻⁵ cm².sec⁻ with activation energies of 2 kcal./mole; determined from plots of log D/T versus l/T. The temperatures at which coefficients were measured were 7.35, 19.35 and 30.00° C. The activation energies measured agreed with those for viscous flow as is required by the theories of Frenkel and Eyring."],"dc:identifier.uri":["http://hdl.handle.net/11427/22273"],"dc:language.iso":["eng"],"dc:publisher.department":["Department of Chemistry"],"dc:publisher.institution":["University of Cape Town"],"dc:title":["A study of the self-diffusion of certain of the lower alkyl halides"],"dc:type":["Doctoral Thesis"],"dc:type.qualificationlevel":["Doctoral"],"dc:type.qualificationname":["PhD"]},"updated_at":"2026-07-22T22:23:30Z"}