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Department of Chemistry

The molecular geometry of d⁸ five-coordination : an analysis of static deformations

Abstract

dc:description.abstract

The geometries of the ML₅ fragments in 196 five-coordinate metal complexes (M = Ni(II), Pd(II), Pt(II), Rh(I), Ir(I); L = coordinated ligand atom) have been studied using multi-variate statistical techniques. For each molecular fragment the geometry has been precisely described by two sets of twelve non-redundant symmetry coordinates.

Degree

thesis:*
Grantor dc:publisher.institution
Department of Chemistry
Year dc:date.issued
1988

Author and committee

dc:creator, dc:contributor.*
Author dc:creator
  • Auf der Heyde, Thomas Paul Edwin
Advisor dc:contributor.advisor
  • Nassimbeni, Luigi R

Rights

Language dc:language.iso
eng

Identifiers

dc:identifier.*
Handle dc:identifier.uri
http://hdl.handle.net/11427/17046
OAI identifier oai:identifier
oai:open.uct.ac.za:11427/17046

Chain of custody

source
Harvested from
University of Cape Town
Base URL
open.uct.ac.za/oai/request
Last updated
2026-07-22
Source record
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citation

Auf der Heyde, Thomas Paul Edwin. The molecular geometry of d⁸ five-coordination : an analysis of static deformations. Department of Chemistry, 1988. http://hdl.handle.net/11427/17046