Structures of Werner clathrates

X-ray crystallographic studies have been used to elucidate the structures of two new Werner clathrates. ... The chloroform molecule is disordered, lying on a two-fold axis. Stoicheiometric characterization of the clathrates was determined using various chemical techniques, including mass spectroscopy, proton nuclear magnetic resonance and complex iometric titration. The clathrating phase of the second clathrate was investigated by guest-loss studies on a McBain balance followed by X-ray powder photography. Host-quest non-bonded interactions of both clathrate compounds were studied using atom-pair potentials.

Grantor dc:publisher.institution

Department of Chemistry

Year dc:date.issued

1983

Author dc:creator

• Papanicolaou, Sevasti

Advisor dc:contributor.advisor

• Nassimbeni, Luigi R

Language dc:language.iso

eng

Handle dc:identifier.uri

http://hdl.handle.net/11427/15811

OAI identifier oai:identifier

oai:open.uct.ac.za:11427/15811