{"id":{"repo_id":"cape-town","oai_identifier":"oai:open.uct.ac.za:11427/13870"},"canonical_url":"https://search.dev.ndltd.org/etd/cape-town/oai:open.uct.ac.za:11427/13870","repository":{"repo_id":"cape-town","name":"University of Cape Town","base_url":"https://open.uct.ac.za/oai/request"},"display":{"title":"Rhizophoraceae alkaloids : preliminary studies in the synthesis of Gerrardine","abstract":"The synthesis envisaged the building of the dithiolane ring on to homoproline, the synthesis of which was effected from tetrahydrofurfuryl alcohol and from proline itself. The reactions involved in these syntheses are discussed with particular reference to the protection of the secondary nitrogen, the difficulties encountered in the application of the Arndt-Eistert reaction, and the possible application of the Prins reaction.","abstract_html":"The synthesis envisaged the building of the dithiolane ring on to homoproline, the synthesis of which was effected from tetrahydrofurfuryl alcohol and from proline itself. The reactions involved in these syntheses are discussed with particular reference to the protection of the secondary nitrogen, the difficulties encountered in the application of the Arndt-Eistert reaction, and the possible application of the Prins reaction.","abstract_has_math":false,"creators":["Kleynhans, C R"],"institution":"Department of Chemistry","degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":[],"advisors":["Warren, F L"],"committee_chairs":[],"committee_members":[],"year":1968,"date_issued":"1968","date_published":"1968","updated_at":"2026-07-22T22:23:44Z","subjects":[],"languages":["eng"],"rights":[],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"http://hdl.handle.net/11427/13870","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.advisor","label":"Advisor","values":["Warren, F L"]},{"key":"dc:creator","label":"Author","values":["Kleynhans, C R"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.accessioned","label":"Dc Date Accessioned","values":["2015-09-14T08:35:26Z"]},{"key":"dc:date.available","label":"Dc Date Available","values":["2015-09-14T08:35:26Z"]},{"key":"dc:date.issued","label":"Date","values":["1968"]},{"key":"dc:publisher.department","label":"Dc Publisher Department","values":["Department of Chemistry"]},{"key":"dc:publisher.institution","label":"Dc Publisher Institution","values":["University of Cape Town"]},{"key":"dc:type","label":"Dc Type","values":["Master Thesis"]},{"key":"dc:type.qualificationlevel","label":"Dc Type Qualificationlevel","values":["Masters"]},{"key":"dc:type.qualificationname","label":"Dc Type Qualificationname","values":["MSc"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language.iso","label":"Language (ISO)","values":["eng"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier.uri","label":"Identifier URI","values":["http://hdl.handle.net/11427/13870"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["Includes bibliography."]},{"key":"dc:description.abstract","label":"Abstract","values":["The synthesis envisaged the building of the dithiolane ring on to homoproline, the synthesis of which was effected from tetrahydrofurfuryl alcohol and from proline itself. The reactions involved in these syntheses are discussed with particular reference to the protection of the secondary nitrogen, the difficulties encountered in the application of the Arndt-Eistert reaction, and the possible application of the Prins reaction."]},{"key":"dc:title","label":"Title","values":["Rhizophoraceae alkaloids : preliminary studies in the synthesis of Gerrardine"]}]}],"canonical_facts":{"dc:contributor.advisor":["Warren, F L"],"dc:creator":["Kleynhans, C R"],"dc:date.accessioned":["2015-09-14T08:35:26Z"],"dc:date.available":["2015-09-14T08:35:26Z"],"dc:date.issued":["1968"],"dc:description":["Includes bibliography."],"dc:description.abstract":["The synthesis envisaged the building of the dithiolane ring on to homoproline, the synthesis of which was effected from tetrahydrofurfuryl alcohol and from proline itself. 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