The synthesis, characterization and reactivity of metallacycloalkanes and their precursors
type: CreativeWork
description: A series of bis(alkenyl)platinum(II) complexes of the type [PtL2{(CH2)nCH=CH2h](L2 = 1 ,3-bis( diphenylphosphino )propane and n = 3-6) have been successfully synthesized and characterized by IH, I3C and 31p NMR spectroscopy, elemental analysis and mass spectrometry. I3C NMR data for these complexes is herein presented for the first time. A new route for the synthesis of dicarbonyldibromide rhenium complexCp*Re(CO)2Br2 affording the product in very high yields is also herein reported.
abstract: A series of bis(alkenyl)platinum(II) complexes of the type [PtL2{(CH2)nCH=CH2h](L2 = 1 ,3-bis( diphenylphosphino )propane and n = 3-6) have been successfully synthesized and characterized by IH, I3C and 31p NMR spectroscopy, elemental analysis and mass spectrometry. I3C NMR data for these complexes is herein presented for the first time. A new route for the synthesis of dicarbonyldibromide rhenium complexCp*Re(CO)2Br2 affording the product in very high yields is also herein reported.
author: Madzivire, Cecilia Rutendo
language: eng
date published: 2010
date modified: 2026-07-22T22:22:50Z
provider: University of Cape Town
publisher: Networked Digital Library of Theses and Dissertations
type: WebPage
source organization: Department of Chemistry

PropertyValue
property ID: Handle
value: http://hdl.handle.net/11427/11047