{"id":{"repo_id":"cape-town","oai_identifier":"oai:open.uct.ac.za:11427/11047"},"canonical_url":"https://search.dev.ndltd.org/etd/cape-town/oai:open.uct.ac.za:11427/11047","repository":{"repo_id":"cape-town","name":"University of Cape Town","base_url":"https://open.uct.ac.za/oai/request"},"display":{"title":"The synthesis, characterization and reactivity of metallacycloalkanes and their precursors","abstract":"A series of bis(alkenyl)platinum(II) complexes of the type [PtL2{(CH2)nCH=CH2h](L2 = 1 ,3-bis( diphenylphosphino )propane and n = 3-6) have been successfully synthesized and characterized by IH, I3C and 31p NMR spectroscopy, elemental analysis and mass spectrometry. I3C NMR data for these complexes is herein presented for the first time. A new route for the synthesis of dicarbonyldibromide rhenium complexCp*Re(CO)2Br2 affording the product in very high yields is also herein reported.","abstract_html":"A series of bis(alkenyl)platinum(II) complexes of the type [PtL2{(CH2)nCH=CH2h](L2 = 1 ,3-bis( diphenylphosphino )propane and n = 3-6) have been successfully synthesized and characterized by IH, I3C and 31p NMR spectroscopy, elemental analysis and mass spectrometry. I3C NMR data for these complexes is herein presented for the first time. A new route for the synthesis of dicarbonyldibromide rhenium complexCp*Re(CO)2Br2 affording the product in very high yields is also herein reported.","abstract_has_math":false,"creators":["Madzivire, Cecilia Rutendo"],"institution":"Department of Chemistry","degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":[],"advisors":["Moss, John R","Hutton, Alan T"],"committee_chairs":[],"committee_members":[],"year":2010,"date_issued":"2010","date_published":"2010","updated_at":"2026-07-22T22:22:50Z","subjects":[],"languages":["eng"],"rights":[],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"http://hdl.handle.net/11427/11047","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.advisor","label":"Advisor","values":["Moss, John R","Hutton, Alan T"]},{"key":"dc:creator","label":"Author","values":["Madzivire, Cecilia Rutendo"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.accessioned","label":"Dc Date Accessioned","values":["2015-01-02T09:26:23Z"]},{"key":"dc:date.available","label":"Dc Date Available","values":["2015-01-02T09:26:23Z"]},{"key":"dc:date.issued","label":"Date","values":["2010"]},{"key":"dc:publisher.department","label":"Dc Publisher Department","values":["Department of Chemistry"]},{"key":"dc:publisher.institution","label":"Dc Publisher Institution","values":["University of Cape Town"]},{"key":"dc:type","label":"Dc Type","values":["Master Thesis"]},{"key":"dc:type.qualificationlevel","label":"Dc Type Qualificationlevel","values":["Masters"]},{"key":"dc:type.qualificationname","label":"Dc Type Qualificationname","values":["MSc"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language.iso","label":"Language (ISO)","values":["eng"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier.uri","label":"Identifier URI","values":["http://hdl.handle.net/11427/11047"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["Includes abstract.","Includes bibliographical references."]},{"key":"dc:description.abstract","label":"Abstract","values":["A series of bis(alkenyl)platinum(II) complexes of the type [PtL2{(CH2)nCH=CH2h](L2 = 1 ,3-bis( diphenylphosphino )propane and n = 3-6) have been successfully synthesized and characterized by IH, I3C and 31p NMR spectroscopy, elemental analysis and mass spectrometry. I3C NMR data for these complexes is herein presented for the first time. A new route for the synthesis of dicarbonyldibromide rhenium complexCp*Re(CO)2Br2 affording the product in very high yields is also herein reported."]},{"key":"dc:title","label":"Title","values":["The synthesis, characterization and reactivity of metallacycloalkanes and their precursors"]}]}],"canonical_facts":{"dc:contributor.advisor":["Moss, John R","Hutton, Alan T"],"dc:creator":["Madzivire, Cecilia Rutendo"],"dc:date.accessioned":["2015-01-02T09:26:23Z"],"dc:date.available":["2015-01-02T09:26:23Z"],"dc:date.issued":["2010"],"dc:description":["Includes abstract.","Includes bibliographical references."],"dc:description.abstract":["A series of bis(alkenyl)platinum(II) complexes of the type [PtL2{(CH2)nCH=CH2h](L2 = 1 ,3-bis( diphenylphosphino )propane and n = 3-6) have been successfully synthesized and characterized by IH, I3C and 31p NMR spectroscopy, elemental analysis and mass spectrometry. I3C NMR data for these complexes is herein presented for the first time. A new route for the synthesis of dicarbonyldibromide rhenium complexCp*Re(CO)2Br2 affording the product in very high yields is also herein reported."],"dc:identifier.uri":["http://hdl.handle.net/11427/11047"],"dc:language.iso":["eng"],"dc:publisher.department":["Department of Chemistry"],"dc:publisher.institution":["University of Cape Town"],"dc:title":["The synthesis, characterization and reactivity of metallacycloalkanes and their precursors"],"dc:type":["Master Thesis"],"dc:type.qualificationlevel":["Masters"],"dc:type.qualificationname":["MSc"]},"updated_at":"2026-07-22T22:22:50Z"}