{"id":{"repo_id":"cape-town","oai_identifier":"oai:open.uct.ac.za:11427/10260"},"canonical_url":"https://search.dev.ndltd.org/etd/cape-town/oai:open.uct.ac.za:11427/10260","repository":{"repo_id":"cape-town","name":"University of Cape Town","base_url":"https://open.uct.ac.za/oai/request"},"display":{"title":"Synthesis and characterisation of palladium, platinum and gold complexes and their biological activity against oesophageal cancer cell lines","abstract":"New iminophosphine ligands were synthesised in good yields from the condensation of N-(2-(diphenylphosphino)benzaldehyde with the appropriate amine. A series of new metal complexes (Pd, Pt and Au) were obtained by coordination of the iminophosphine ligands in good yields. The complexes were characterised using the spectroscopic and analytical techniques mentioned above, with the exception of the palladium dichloride complexes that are highly insoluble in organic solvents.","abstract_html":"New iminophosphine ligands were synthesised in good yields from the condensation of N-(2-(diphenylphosphino)benzaldehyde with the appropriate amine. A series of new metal complexes (Pd, Pt and Au) were obtained by coordination of the iminophosphine ligands in good yields. The complexes were characterised using the spectroscopic and analytical techniques mentioned above, with the exception of the palladium dichloride complexes that are highly insoluble in organic solvents.","abstract_has_math":false,"creators":["Chiririwa, Haleden"],"institution":"Department of Chemistry","degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":[],"advisors":["Moss, John R"],"committee_chairs":[],"committee_members":[],"year":2010,"date_issued":"2010","date_published":"2010","updated_at":"2026-07-22T22:23:17Z","subjects":[],"languages":["eng"],"rights":[],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"http://hdl.handle.net/11427/10260","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.advisor","label":"Advisor","values":["Moss, John R"]},{"key":"dc:creator","label":"Author","values":["Chiririwa, Haleden"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.accessioned","label":"Dc Date Accessioned","values":["2014-12-27T14:16:42Z"]},{"key":"dc:date.available","label":"Dc Date Available","values":["2014-12-27T14:16:42Z"]},{"key":"dc:date.issued","label":"Date","values":["2010"]},{"key":"dc:publisher.department","label":"Dc Publisher Department","values":["Department of Chemistry"]},{"key":"dc:publisher.institution","label":"Dc Publisher Institution","values":["University of Cape Town"]},{"key":"dc:type","label":"Dc Type","values":["Doctoral Thesis"]},{"key":"dc:type.qualificationlevel","label":"Dc Type Qualificationlevel","values":["Doctoral"]},{"key":"dc:type.qualificationname","label":"Dc Type Qualificationname","values":["PhD"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language.iso","label":"Language (ISO)","values":["eng"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier.uri","label":"Identifier URI","values":["http://hdl.handle.net/11427/10260"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["Includes bibliographical references."]},{"key":"dc:description.abstract","label":"Abstract","values":["New iminophosphine ligands were synthesised in good yields from the condensation of N-(2-(diphenylphosphino)benzaldehyde with the appropriate amine. A series of new metal complexes (Pd, Pt and Au) were obtained by coordination of the iminophosphine ligands in good yields. The complexes were characterised using the spectroscopic and analytical techniques mentioned above, with the exception of the palladium dichloride complexes that are highly insoluble in organic solvents."]},{"key":"dc:title","label":"Title","values":["Synthesis and characterisation of palladium, platinum and gold complexes and their biological activity against oesophageal cancer cell lines"]}]}],"canonical_facts":{"dc:contributor.advisor":["Moss, John R"],"dc:creator":["Chiririwa, Haleden"],"dc:date.accessioned":["2014-12-27T14:16:42Z"],"dc:date.available":["2014-12-27T14:16:42Z"],"dc:date.issued":["2010"],"dc:description":["Includes bibliographical references."],"dc:description.abstract":["New iminophosphine ligands were synthesised in good yields from the condensation of N-(2-(diphenylphosphino)benzaldehyde with the appropriate amine. 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