Non-equilibrium phase separation in active matter
type: CreativeWork
description: Active matter, characterised by the ability to inject energy into the environment locally, forms an important class of non-equilibrium systems. Recently there has been a surge of interest in active systems with chemical reactions, fuelled in particular by studies in biomolecular condensates, or ‘membraneless organelles’, within cells. In contrast to their passive counterparts, such systems have conserved and non-conserved dynamics that do not, in general, derive from a shared free energy. This mismatch breaks time- reversal symmetry (TRS) and leads to new types of dynamical competition that are absent in or near equilibrium. We construct a canonical scalar field theory to describe such systems, with conserved and non-conserved dynamics obeying Model B and Model A respectively (in the Hohenberg-Halperin classification), chosen such that the two free energies involved are incompatible. The resulting minimal model is shown to capture the various phenomenologies reported previously for more complicated models within this class, including microphase separation, limit cycles and droplet splitting. To expand upon the systematic study of non-equilibrium reaction-diffusion systems, we also consider that the diffusive dynamics can break time reversal symmetry in its own right. This happens only at higher order in the gradient expansion, but is the leading behaviour without reactions present. We incorporate the higher gradient terms into Model AB and show that for slow reaction rates the system can undergo a new type of hierarchical microphase separation, which we call ‘bubbly microphase separation’. In this state, small droplets of one fluid are continuously created and absorbed into large droplets, whose length-scales are controlled by the competing reactive and diffusive dynamics. Motivated by the distinct non-equilibrium nature of active systems, we introduce the entropy production rate (EPR) as a quantitative measure of time reversal symmetry breaking. It can be defined e…
abstract: Active matter, characterised by the ability to inject energy into the environment locally, forms an important class of non-equilibrium systems. Recently there has been a surge of interest in active systems with chemical reactions, fuelled in particular by studies in biomolecular condensates, or ‘membraneless organelles’, within cells. In contrast to their passive counterparts, such systems have conserved and non-conserved dynamics that do not, in general, derive from a shared free energy. This mismatch breaks time- reversal symmetry (TRS) and leads to new types of dynamical competition that are absent in or near equilibrium. We construct a canonical scalar field theory to describe such systems, with conserved and non-conserved dynamics obeying Model B and Model A respectively (in the Hohenberg-Halperin classification), chosen such that the two free energies involved are incompatible. The resulting minimal model is shown to capture the various phenomenologies reported previously for more complicated models within this class, including microphase separation, limit cycles and droplet splitting. To expand upon the systematic study of non-equilibrium reaction-diffusion systems, we also consider that the diffusive dynamics can break time reversal symmetry in its own right. This happens only at higher order in the gradient expansion, but is the leading behaviour without reactions present. We incorporate the higher gradient terms into Model AB and show that for slow reaction rates the system can undergo a new type of hierarchical microphase separation, which we call ‘bubbly microphase separation’. In this state, small droplets of one fluid are continuously created and absorbed into large droplets, whose length-scales are controlled by the competing reactive and diffusive dynamics. Motivated by the distinct non-equilibrium nature of active systems, we introduce the entropy production rate (EPR) as a quantitative measure of time reversal symmetry breaking. It can be defined e…
author: Li, Yuting
language: eng
keywords: Soft Matter, Active Matter, Entropy
license: https://www.rioxx.net/licenses/all-rights-reserved/
date published: 2021-10-21
date modified: 2026-07-22T22:24:06Z
provider: Cambridge University
publisher: Networked Digital Library of Theses and Dissertations
type: WebPage
source organization: University of Cambridge

PropertyValue
property ID: DOI
value: 10.17863/CAM.80384