Nanomaterials-based inks for flexible electronics, energy and photocatalytic applications

Due to the combination of their electronic, optical and mechanical properties, graphene and other layered materials (GRMs) have great potential for applications such as flexible optoelectronics and energy storage. Given that GRMs can be dispersed in solvents, solution processing is a particularly interesting approach that allows large volume production with tailored properties according to the targeted applications. \par In this dissertation I investigate liquid phase exfoliation and formulation of GRMs-based inks for flexible (opto) electronics, energy and photocatalysis. First I develop a protocol for the characterization of graphene inks, based on the statistical analysis of their Raman spectra. Such a tool is essential because of the scattering of characteristics in liquid-phase exfoliated material. I then report two novel processing techniques. The first consists on the exfoliation of graphene in organic solvents by the means of α-functionalized alkanes as stabilising agents, which allows yield by weight (Y_W) of $\sim 100\%$. The second is based on exfoliation of graphite by microfluidization, where the material is stabilised in aqueous solution, with concentrations up to 100g/L. Such inks are successfully deposited by blade coating, leading to films of conductivity $\sim$ 2$\cdot$10⁴ S/m at 25μm. I then investigate the use of graphene inks in optoelectronics and energy applications: First, I investigate inkjet printed graphene as hole injection layer (HTL). The cells with graphene HTL show high long-term stability, retaining 85$\%$ of the initial fill factor after 900 hrs in damp heat conditions. I then demonstrate flexible displays with graphene-SWNTs as pixel electrode. A 4x4 inch² demonstrator is realised integrating the ink into 12,700 pixels. I investigate graphene/MoO₃ electrode for supercapacitors with a specific capacitance of 342 F/cm³. The electrode shows high cyclic stability, preserving $\sim$96$\%$ of the initial capacitance after 10,000 cycles. I finally report the production of TiO₂/exfoliated graphite as efficient photocatalytic composite able to degrade $\sim$100$\%$ more model pollutant with respect to TiO₂.

Name dc:type.qualificationname

Doctor of Philosophy (PhD)

Level dc:type.qualificationlevel

Doctoral

Grantor dc:publisher.institution

University of Cambridge

Year dc:date.issued

2018

Author dc:creator

• TOMARCHIO, FLAVIA

Advisor dc:contributor.advisor

• FERRARI, ANDREA CARLO

• graphene
• layered materials
• energy
• display
• photocatalysis

Licence

• https://apollo8-f-pro.lib.cam.ac.uk/bitstreams/7c6e8979-517e-4753-95f1-3b4e06dd9630/download
• https://www.rioxx.net/licenses/all-rights-reserved/

Language dc:language

en

DOI dc:identifier.doi

https://doi.org/10.17863/CAM.23160

OAI identifier oai:identifier

oai:www.repository.cam.ac.uk:1810/275888