{"id":{"repo_id":"brock","oai_identifier":"oai:brocku.scholaris.ca:10464/2038"},"canonical_url":"https://search.dev.ndltd.org/etd/brock/oai:brocku.scholaris.ca:10464/2038","repository":{"repo_id":"brock","name":"Brock University","base_url":"https://brocku.scholaris.ca/server/oai/request"},"display":{"title":"Rotation-electronic interaction in the 3p-complex Rydberg state of water","abstract":"An energy theory is formulated for the rotational energy levels in a p-complex Rydberg state of an asymmetric top molecule of symmetry C2v. The effective Hamiltonian used consists of the usual rigid rotor Hamiltonian augmented with terms representing electronic spin and orbital angular momentum effects. Criteria for assigning symmetry species to the rotational energy levels, following Houganfs scheme that uses the full molecular group,are established and given in the form of a table. This is particularly suitable when eigenvectors are calculated on a digital computer. Also, an intensity theory for transitions to the Rydberg p-complex singlet states is presented and selection rules in terms of symmetry species of energy states are established. Finally, applications to HpO and DpO are given.","abstract_html":"An energy theory is formulated for the rotational energy levels in a p-complex Rydberg state of an asymmetric top molecule of symmetry C2v. The effective Hamiltonian used consists of the usual rigid rotor Hamiltonian augmented with terms representing electronic spin and orbital angular momentum effects. Criteria for assigning symmetry species to the rotational energy levels, following Houganfs scheme that uses the full molecular group,are established and given in the form of a table. This is particularly suitable when eigenvectors are calculated on a digital computer. Also, an intensity theory for transitions to the Rydberg p-complex singlet states is presented and selection rules in terms of symmetry species of energy states are established. Finally, applications to HpO and DpO are given.","abstract_has_math":false,"creators":["Hussain, Syed Mohammad Javed."],"institution":"Brock University","degree_name":"M.Sc. Physics","degree_level":"Masters","degree_discipline":"Faculty of Mathematics and Science","degree_department":"Department of Physics","school":null,"contributors":[],"advisors":[],"committee_chairs":[],"committee_members":[],"year":1979,"date_issued":"1979-07-09T18:42:42Z","date_published":"1979-07-09T18:42:42Z","updated_at":"2026-07-24T01:23:07Z","subjects":["Rotors.","Rotational motion.","Molecular rotation.","Water--Analysis."],"languages":["eng"],"rights":[],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"http://hdl.handle.net/10464/2038","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.department","label":"Department","values":["Department of Physics"]},{"key":"dc:creator","label":"Author","values":["Hussain, Syed Mohammad Javed."]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.accessioned","label":"Dc Date Accessioned","values":["2009-07-09T18:42:42Z"]},{"key":"dc:date.available","label":"Dc Date Available","values":["2009-07-09T18:42:42Z"]},{"key":"dc:date.issued","label":"Date","values":["1979-07-09T18:42:42Z"]},{"key":"dc:type","label":"Dc Type","values":["Electronic Thesis or Dissertation"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Faculty of Mathematics and Science"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Masters"]},{"key":"thesis:degree_name","label":"Degree Name","values":["M.Sc. 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The effective Hamiltonian used consists of the usual rigid rotor Hamiltonian augmented with terms representing electronic spin and orbital angular momentum effects. Criteria for assigning symmetry species to the rotational energy levels, following Houganfs scheme that uses the full molecular group,are established and given in the form of a table. This is particularly suitable when eigenvectors are calculated on a digital computer. Also, an intensity theory for transitions to the Rydberg p-complex singlet states is presented and selection rules in terms of symmetry species of energy states are established. Finally, applications to HpO and DpO are given."]},{"key":"dc:title","label":"Title","values":["Rotation-electronic interaction in the 3p-complex Rydberg state of water"]}]}],"canonical_facts":{"dc:contributor.department":["Department of Physics"],"dc:creator":["Hussain, Syed Mohammad Javed."],"dc:date.accessioned":["2009-07-09T18:42:42Z"],"dc:date.available":["2009-07-09T18:42:42Z"],"dc:date.issued":["1979-07-09T18:42:42Z"],"dc:description.abstract":["An energy theory is formulated for the rotational energy levels in a p-complex Rydberg state of an asymmetric top molecule of symmetry C2v. The effective Hamiltonian used consists of the usual rigid rotor Hamiltonian augmented with terms representing electronic spin and orbital angular momentum effects. Criteria for assigning symmetry species to the rotational energy levels, following Houganfs scheme that uses the full molecular group,are established and given in the form of a table. This is particularly suitable when eigenvectors are calculated on a digital computer. Also, an intensity theory for transitions to the Rydberg p-complex singlet states is presented and selection rules in terms of symmetry species of energy states are established. Finally, applications to HpO and DpO are given."],"dc:identifier.uri":["http://hdl.handle.net/10464/2038"],"dc:language.iso":["eng"],"dc:subject":["Rotors.","Rotational motion.","Molecular rotation.","Water--Analysis."],"dc:title":["Rotation-electronic interaction in the 3p-complex Rydberg state of water"],"dc:type":["Electronic Thesis or Dissertation"],"thesis:degree_discipline":["Faculty of Mathematics and Science"],"thesis:degree_level":["Masters"],"thesis:degree_name":["M.Sc. Physics"],"thesis:institution_name":["Brock University"]},"updated_at":"2026-07-24T01:23:07Z"}