{"id":{"repo_id":"brock","oai_identifier":"oai:brocku.scholaris.ca:10464/10426"},"canonical_url":"https://search.dev.ndltd.org/etd/brock/oai:brocku.scholaris.ca:10464/10426","repository":{"repo_id":"brock","name":"Brock University","base_url":"https://brocku.scholaris.ca/server/oai/request"},"display":{"title":"Bis(dialkylamino)cyclopropeneimine Substituted Proton Sponge Derivatives: Synthesis, Theory, and Application","abstract":"The work presented herein describes the synthesis, as well as the experimental and theoretical investigation of hitherto unknown cyclopropenimine containing compounds, mostly within the proton sponge backbone. The properties of these molecules are discussed in the context of other proton sponge derivatives reported in the literature. The superbasicity, catalytic activity, and fluorescent nature of these cyclopropenimine derivatives are also investigated and discussed.","abstract_html":"The work presented herein describes the synthesis, as well as the experimental and theoretical investigation of hitherto unknown cyclopropenimine containing compounds, mostly within the proton sponge backbone. The properties of these molecules are discussed in the context of other proton sponge derivatives reported in the literature. The superbasicity, catalytic activity, and fluorescent nature of these cyclopropenimine derivatives are also investigated and discussed.","abstract_has_math":false,"creators":["Belding, Lee"],"institution":"Brock University","degree_name":"Ph.D. Chemistry","degree_level":"Doctoral","degree_discipline":"Faculty of Mathematics and Science","degree_department":"Department of Chemistry","school":null,"contributors":[],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2016,"date_issued":"2016-09-21T19:59:10Z","date_published":"2016-09-21T19:59:10Z","updated_at":"2026-07-24T01:23:04Z","subjects":["Cyclopropenimine, Proton Sponge, Superbase, Organic Chemistry"],"languages":["eng"],"rights":[],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"http://hdl.handle.net/10464/10426","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.department","label":"Department","values":["Department of Chemistry"]},{"key":"dc:creator","label":"Author","values":["Belding, Lee"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.accessioned","label":"Dc Date Accessioned","values":["2016-09-21T19:59:10Z"]},{"key":"dc:date.available","label":"Dc Date Available","values":["2016-09-21T19:59:10Z"]},{"key":"dc:date.issued","label":"Date","values":["2016-09-21T19:59:10Z"]},{"key":"dc:type","label":"Dc Type","values":["Electronic Thesis or Dissertation"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Faculty of Mathematics and Science"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Doctoral"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Ph.D. Chemistry"]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["Brock University"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Cyclopropenimine, Proton Sponge, Superbase, Organic Chemistry"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language.iso","label":"Language (ISO)","values":["eng"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier.uri","label":"Identifier URI","values":["http://hdl.handle.net/10464/10426"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["The work presented herein describes the synthesis, as well as the experimental and theoretical investigation of hitherto unknown cyclopropenimine containing compounds, mostly within the proton sponge backbone. The properties of these molecules are discussed in the context of other proton sponge derivatives reported in the literature. The superbasicity, catalytic activity, and fluorescent nature of these cyclopropenimine derivatives are also investigated and discussed."]},{"key":"dc:title","label":"Title","values":["Bis(dialkylamino)cyclopropeneimine Substituted Proton Sponge Derivatives: Synthesis, Theory, and Application"]}]}],"canonical_facts":{"dc:contributor.department":["Department of Chemistry"],"dc:creator":["Belding, Lee"],"dc:date.accessioned":["2016-09-21T19:59:10Z"],"dc:date.available":["2016-09-21T19:59:10Z"],"dc:date.issued":["2016-09-21T19:59:10Z"],"dc:description.abstract":["The work presented herein describes the synthesis, as well as the experimental and theoretical investigation of hitherto unknown cyclopropenimine containing compounds, mostly within the proton sponge backbone. The properties of these molecules are discussed in the context of other proton sponge derivatives reported in the literature. The superbasicity, catalytic activity, and fluorescent nature of these cyclopropenimine derivatives are also investigated and discussed."],"dc:identifier.uri":["http://hdl.handle.net/10464/10426"],"dc:language.iso":["eng"],"dc:subject":["Cyclopropenimine, Proton Sponge, Superbase, Organic Chemistry"],"dc:title":["Bis(dialkylamino)cyclopropeneimine Substituted Proton Sponge Derivatives: Synthesis, Theory, and Application"],"dc:type":["Electronic Thesis or Dissertation"],"thesis:degree_discipline":["Faculty of Mathematics and Science"],"thesis:degree_level":["Doctoral"],"thesis:degree_name":["Ph.D. Chemistry"],"thesis:institution_name":["Brock University"]},"updated_at":"2026-07-24T01:23:04Z"}