{"id":{"repo_id":"anu","oai_identifier":"oai:openresearch-repository.anu.edu.au:1885/155166"},"canonical_url":"https://search.dev.ndltd.org/etd/anu/oai:openresearch-repository.anu.edu.au:1885/155166","repository":{"repo_id":"anu","name":"Australian National University","base_url":"https://openresearch-repository.anu.edu.au/server/oai/request"},"display":{"title":"Cross-Coupling Chemistry as a Tool for the Synthesis of Diverse Heterocyclic Systems and Natural Products","abstract":"My thesis consists of six publications. The first publication is a review article with the title 'The Palladium-catalysed Ullmann Cross-coupling Reaction: A Modern Variant on a Time-honored Process'. The second publication has the title 'Palladium-Catalyzed Ullmann Cross-Coupling of beta-Iodoenones and beta-Iodoacrylates with o-Halonitroarenes or o-Iodobenzonitriles and Reductive Cyclization of the Resulting Products To Give Diverse Heterocyclic Systems'. The third publication has the title 'Reductive Cyclization of o-Nitroarylated-alpha,beta-Unsaturated Aldehydes and Ketones with TiCl3/HCl or Fe/HCl Leading to 1,2,3,9-Tetrahydro-4H-carbazol-4-ones and Related Heterocycles'. The fourth publication has the title 'Synthesis of a Highly Functionalised and Homochiral 2-Iodocyclohexenone Related to the C-Ring of the Polycyclic, Indole Alkaloids Aspidophytine and Haplophytine'. The fifth publication has the title 'Syntheses of Structurally and Stereochemically Varied Forms of C7N Aminocyclitol Derivatives from Enzymatically-derived and Homochiral cis-1,2-Dihydrocatechols' and the last publication is a review article with the title 'Chemical Syntheses of the Cochliomycins and Certain Related Resorcylic Acid Lactones'.","abstract_html":"My thesis consists of six publications. The first publication is a review article with the title 'The Palladium-catalysed Ullmann Cross-coupling Reaction: A Modern Variant on a Time-honored Process'. The second publication has the title 'Palladium-Catalyzed Ullmann Cross-Coupling of beta-Iodoenones and beta-Iodoacrylates with o-Halonitroarenes or o-Iodobenzonitriles and Reductive Cyclization of the Resulting Products To Give Diverse Heterocyclic Systems'. The third publication has the title 'Reductive Cyclization of o-Nitroarylated-alpha,beta-Unsaturated Aldehydes and Ketones with TiCl3/HCl or Fe/HCl Leading to 1,2,3,9-Tetrahydro-4H-carbazol-4-ones and Related Heterocycles'. The fourth publication has the title 'Synthesis of a Highly Functionalised and Homochiral 2-Iodocyclohexenone Related to the C-Ring of the Polycyclic, Indole Alkaloids Aspidophytine and Haplophytine'. The fifth publication has the title 'Syntheses of Structurally and Stereochemically Varied Forms of C7N Aminocyclitol Derivatives from Enzymatically-derived and Homochiral cis-1,2-Dihydrocatechols' and the last publication is a review article with the title 'Chemical Syntheses of the Cochliomycins and Certain Related Resorcylic Acid Lactones'.","abstract_has_math":false,"creators":["Dlugosch, Michael"],"institution":null,"degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":[],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2019,"date_issued":"2019","date_published":"2019","updated_at":"2026-07-24T00:54:38Z","subjects":[],"languages":["en_AU"],"rights":[],"rights_urls":[],"identifier_entries":[{"key":"dc:identifier.other","label":"Dc Identifier Other","values":["b59285357"],"render_values":[{"text":"b59285357","href":null,"code":true}]}]},"links":{"outbound_url":"http://hdl.handle.net/1885/155166","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:creator","label":"Author","values":["Dlugosch, Michael"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.accessioned","label":"Dc Date Accessioned","values":["2019-01-14T21:47:35Z"]},{"key":"dc:date.available","label":"Dc Date Available","values":["2019-01-14T21:47:35Z"]},{"key":"dc:date.issued","label":"Date","values":["2019"]},{"key":"dc:type","label":"Dc Type","values":["Thesis (PhD)"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language.iso","label":"Language (ISO)","values":["en_AU"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier.other","label":"Dc Identifier Other","values":["b59285357"]},{"key":"dc:identifier.uri","label":"Identifier URI","values":["http://hdl.handle.net/1885/155166"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["My thesis consists of six publications. The first publication is a review article with the title 'The Palladium-catalysed Ullmann Cross-coupling Reaction: A Modern Variant on a Time-honored Process'. The second publication has the title 'Palladium-Catalyzed Ullmann Cross-Coupling of beta-Iodoenones and beta-Iodoacrylates with o-Halonitroarenes or o-Iodobenzonitriles and Reductive Cyclization of the Resulting Products To Give Diverse Heterocyclic Systems'. The third publication has the title 'Reductive Cyclization of o-Nitroarylated-alpha,beta-Unsaturated Aldehydes and Ketones with TiCl3/HCl or Fe/HCl Leading to 1,2,3,9-Tetrahydro-4H-carbazol-4-ones and Related Heterocycles'. The fourth publication has the title 'Synthesis of a Highly Functionalised and Homochiral 2-Iodocyclohexenone Related to the C-Ring of the Polycyclic, Indole Alkaloids Aspidophytine and Haplophytine'. The fifth publication has the title 'Syntheses of Structurally and Stereochemically Varied Forms of C7N Aminocyclitol Derivatives from Enzymatically-derived and Homochiral cis-1,2-Dihydrocatechols' and the last publication is a review article with the title 'Chemical Syntheses of the Cochliomycins and Certain Related Resorcylic Acid Lactones'."]},{"key":"dc:title","label":"Title","values":["Cross-Coupling Chemistry as a Tool for the Synthesis of Diverse Heterocyclic Systems and Natural Products"]}]}],"canonical_facts":{"dc:creator":["Dlugosch, Michael"],"dc:date.accessioned":["2019-01-14T21:47:35Z"],"dc:date.available":["2019-01-14T21:47:35Z"],"dc:date.issued":["2019"],"dc:description.abstract":["My thesis consists of six publications. The first publication is a review article with the title 'The Palladium-catalysed Ullmann Cross-coupling Reaction: A Modern Variant on a Time-honored Process'. The second publication has the title 'Palladium-Catalyzed Ullmann Cross-Coupling of beta-Iodoenones and beta-Iodoacrylates with o-Halonitroarenes or o-Iodobenzonitriles and Reductive Cyclization of the Resulting Products To Give Diverse Heterocyclic Systems'. The third publication has the title 'Reductive Cyclization of o-Nitroarylated-alpha,beta-Unsaturated Aldehydes and Ketones with TiCl3/HCl or Fe/HCl Leading to 1,2,3,9-Tetrahydro-4H-carbazol-4-ones and Related Heterocycles'. The fourth publication has the title 'Synthesis of a Highly Functionalised and Homochiral 2-Iodocyclohexenone Related to the C-Ring of the Polycyclic, Indole Alkaloids Aspidophytine and Haplophytine'. The fifth publication has the title 'Syntheses of Structurally and Stereochemically Varied Forms of C7N Aminocyclitol Derivatives from Enzymatically-derived and Homochiral cis-1,2-Dihydrocatechols' and the last publication is a review article with the title 'Chemical Syntheses of the Cochliomycins and Certain Related Resorcylic Acid Lactones'."],"dc:identifier.other":["b59285357"],"dc:identifier.uri":["http://hdl.handle.net/1885/155166"],"dc:language.iso":["en_AU"],"dc:title":["Cross-Coupling Chemistry as a Tool for the Synthesis of Diverse Heterocyclic Systems and Natural Products"],"dc:type":["Thesis (PhD)"]},"updated_at":"2026-07-24T00:54:38Z"}