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Different alpha-hydroxy-tetralone, - indanone- and -chromanone-derivatives could be obtained with generation of a quaternary stereogenic center with high enantioselectivities. This alpha-hydroxy-ketones are structural motifs of many bioactive natural products. Thus, synthetic concepts for the synthesis of (S)-eucomol and (S)-lacinilen C methylether have been followed. Furthermore, an efficient proline-catalyzed asymmetric intramolecular 5-enolexo aldol reaction for the cis-selective synthesis of 3-hydroxy-2,3-dihydrobenzofuranes has been developed. After a simple 1,2-addition the corresponding tertiary alcohols can be obtained which are structural motifs in many bioactive natural products such as the coumarins smyrindiol and vaginidiol.","abstract_html":"In nature many metal free catalytic reactions are accomplished in enzymes. The broad facilities of organocatalysis as a selective and environment-friendly synthetic method has only been recognized recently by chemists. This thesis deals with the synthesis of novel chiral polycylic triazolim salts as pre-catalysts for N-heterocyclic carbenes. Their application was shown in the first asymmetric intramolecular aldehyde-ketone benzoin reaction. Different alpha-hydroxy-tetralone, - indanone- and -chromanone-derivatives could be obtained with generation of a quaternary stereogenic center with high enantioselectivities. This alpha-hydroxy-ketones are structural motifs of many bioactive natural products. Thus, synthetic concepts for the synthesis of (S)-eucomol and (S)-lacinilen C methylether have been followed. Furthermore, an efficient proline-catalyzed asymmetric intramolecular 5-enolexo aldol reaction for the cis-selective synthesis of 3-hydroxy-2,3-dihydrobenzofuranes has been developed. 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