(Trimethylsilyloxy)acrylsäureester in der organischen Synthese

(Trimethylsilyloxy)acrylic esters have been reacted with different electrophiles such as acetals, thioacetals and mixed N,O-acetals to gain access to densly functionalized gamma-substituted alpha-keto esters. Simple metal triflates such as copper(II)triflate was used as catalyst. The thus obtained products could easily be transformed into alpha-oximes, alpha-hydrazones as well as gamma-hydroxy-alpha-keto esters under mild conditions and in high yields.

Grantor dc:publisher

Publikationsserver der RWTH Aachen University

Year dc:date

2011

Author dc:creator

• Krebs, Anke

Contributors dc:contributor

• Bolm, Carsten

• info:eu-repo/classification/ddc/540
• Organische Synthese
• Acrylsäureester
• Chemie
• Kupfertriflat
• organic synthesis
• acrylic ester
• coppertriflate

Statement dc:rights

• info:eu-repo/semantics/openAccess

Language dc:language

ger

Identifier

https://publications.rwth-aachen.de/search?p=id:%22RWTH-CONV-115047%22

OAI record oai:identifier

https://publications.rwth-aachen.de/oai2d?verb=GetRecord&metadataPrefix=oai_dc&identifier=oai%3Apublications.rwth-aachen.de%3A52854