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Showing 1 to 3 of 3 for “"zincation"”.
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Zincative Functionalization of C–H Bonds Using Lithium Amide Zincate Bases
… rare transition metal catalysts. Deprotonative zincation has been demonstrated as a useful method to achieve C–H functionalization. </p><p>The direct C–H amination of a wide scope of arenes and heteroarenes has been achieved by copper-catalyzed electrophilic amination with O-benzoyl …
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Advances in synthetic, structural and reaction chemistry of zinc and zincate complexes containing alkyl and/or amido ligands
… temperature protocols, ambient temperature zincation of N-Boc pyrrolidine was achieved via sodium zincate [(TMEDA)Na(μ-TMP)(μ-tBu)Zn(tBu)]. Metallated intermediate [(TMEDA)Na(TMP)(α-NC4H7NBoc)Zn(tBu)] 13 was crystallographically characterised. Exploring the basicity of 13, in situ …