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Showing 1 to 1 of 1 for “"vanadate ester"”.

  1. Enzyme-Catalyzed Phosphoryl Transfer Reactions: Energetics of Transition States and Vanadate Analogues in Aqueous Solution

    … such as glycolysis and DNA replication. Vanadate is recognized as an effective structural and electronic analogue of phosphate. Solvation effects are significant contributors to the reaction free energies and activation barriers of organic phosphate hydrolysis reactions. The methanolysis …

    loyola-thes Repository record for Enzyme-Catalyzed Phosphoryl Transfer Reactions: Energetics of Transition States and Vanadate Analogues in Aqueous Solution (opens in a new tab)