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Showing 1 to 4 of 4 for “"trans influence"”.
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Experimental and Theoretical Studies of Inorganic Reactions: Part 1 - Studies of the Ligand Exchange Reactions of Cobalt(ii) Complexes by Nuclear Magnetic Resonance Techniques. Part 2 - Molecular Orbital Studies of the Trans Influence Phenomenon and the Kinetic Trans Effect Inplatinum(ii) Complexes
Made available in DSpace on 2014-12-09T17:36:19Z (GMT). No. of bitstreams: 1 6910890.pdf: 6019024 bytes, checksum: 4dd9d9bb4a5b8d88ba54af43c348df89 (MD5) Previous issue date: 1968
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N-Heterocyclic Carbenes of the Late Transition Metals: A Computational and Structural Database Study
… database study of the bonding in late transition metal N-heterocyclic carbene (NHC) complexes is reported. The results illustrate a metal-carbon bond for these complexes, approximately 4% shorter than that of a M-C single bond found in metal alkyl complexes. As a consequence of this …
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Ein- und mehrkernige Rhodium- und Iridiumkomplexe mit konjugierten organischen Ketten als Brückenliganden
… Hydroxokomplexen der allgemeinen Zusammensetzung trans-[MX(L)(PiPr3)2] (M = Rh, Ir; X = OH, F; L = C=CHR’, CO, CNC6H3-2,6-Me2), trans-[{MX(PiPr3)2}n{µ-C6H(6-n) (CH=C=)n}] (n = 2, 3) und zweitens ihre Reaktivität gegenüber stannylierten 1-Alkinen und Dialkinen. Die Bedeutung der Hydroxo- und …
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Modeling Dark- and Light-Induced Crystal Structures and Single-Crystal Optical Absorption Spectra of Ruthenium-Based Complexes that Undergo SO2-Linkage Photoisomerization
… more complexes, including both photoswitches and transducers. Periodic models are shown to appreciate the competing chemical and crystallographic forces present in these complexes, namely the possible effects of the trans-influence and intermolecular interactions on the simulated optical …