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Showing 1 to 1 of 1 for “"titanium amide"”.
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Regioselective, Nucleophilic Activation of C-F Bonds in o-Fluoroanilines
Reactions of fluorinated anilines with stoichiometric Ti(NMe2)4 in mesitylene (typically for 23 h at 120 °C) afforded moderate to high yields of the corresponding N,N-dimethyl-o-phenylenediamine derivatives resulting from defluoroamination of a fluorine atom ortho to the NH2 of the starting …