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Showing 1 to 4 of 4 for “"thiosulfinates"”.
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UNDERSTANDING SULFUR BASED REDOX BIOLOGY THROUGH ADVANCEMENTS IN CHEMICAL BIOLOGY
… converted to other species including disulfides, thiosulfinates, sulfinic acids, or sulfonic acids, leading to changes in protein function. The resulting structural and functional changes can modulate enzyme activity, activate transcription factors, and lead to signaling cascades. Understanding …
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Developing an optimal method for producing a tearless onion
… thiosulfinate. A consequence of the raised thiosulfinates levels was a marked increase in the downstream production of a non-enzymatically produced zwiebelane isomer that has never previously been identified, and other volatile compounds, di-1-propenyl disulfides and …
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Peri-substituted dithianaphthalenes as sources of reactive intermediates in organic chemistry
… are reactive intermediates in the oxidation of thiosulfinates to thiosulfonates. The oxidation of 1,8-naphthalene disulfides was investigated. Cyclic voltammetry demonstrated that electron-rich 3,8-dimethoxynaphtho[1,8-cd][1,2]dithiole (87) was easier to oxidise than the parent naphthalene …
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Elucidation of the Various Mechanisms of Antioxidant Activity of Organosulfur Compounds
… species. Our group previously shown that thiosulfinates (RS(O)SR), key components of garlic, are potent radical-trapping antioxidants (RTAs) through the intermediacy of sulfenic acids (RSOH). In an effort to shed light on the antioxidant mechanisms of other organosulfur constituents of …