Global ETD Search
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Showing 1 to 4 of 4 for “"thiolate ligand"”.
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Investigating the Interactions Between the Thiolate Ligand and Mutants of a Conserved Tryptophan in the Proximal Heme Pocket of the Oxygenase Domains of Endothelial and Staphyloccus Aureus Nitric Oxide Synthases
The electronegativity of thiolate ligation in the hemeprotein nitric oxide synthase (NOS) proteins has been identified as an influence on autoinhibition in this enzyme. The mutation of a conserved tryptophan residue, which hydrogen bonds to the coordinating thiolate ligand and therefore influences …
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TOWARD UNDERSTANDING THE FUNDAMENTALS IN THE SYNTHESIS OF METAL NANOCLUSTERS
… of Au NCs is adpated from Brust method, where thiolate ligand is first mixed with Au(III) salt, followed by the addition of NaBH4 reducing agent. Although this method is widely applied in the synthesis of Au NCs, its understanding lacks behind, with most understanding based on the available …
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Cyclometallated platinum and iridium complexes with thiolate ligands, and novel bioimaging agents inspired by dynamic disulfide interchange reactions
… and bidentate cyclometallating aromatic ligands; L = monodentate pyridine ligand; X = heterocyclic N or cyclometallated aryl C; n = 0,1) is described and their reactions with thiolates are explored with the aim of producing new classes of thiol sensors. Thus, novel monometallic complexes …
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Koordinationschemie von zweikernigen Palladium(II)komplexen mit mehrzähnigen Amin-Phosphin-Thiolatliganden
… und die Reaktivität untersucht. Es wurden Koliganden gebunden und eine Reaktion am Zweikernzentrum durchgeführt. Mit den bizyklischen N,S-Liganden L1 und L2 wurden zweikernige Komplexe dargestellt, in denen die Palladiumionen relativ weit voneinander entfernt sind. Die Umsetzung von L2 mit …