Global ETD Search
Search theses and dissertations gathered from participating repositories worldwide. Every result links back to the library that holds it. No account is needed.
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Showing 1 to 8 of 8 for “"terminal ligand"”.
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Modification of Excited State Behavior with Ligand Substitution in Ru(II),Rh(III) Bimetallic Supramolecular Complexes
The terminal ligand in [(Ph₂phen)₂Ru(dpp)RhCl₂(TL)](PF₆)₃ (Ph2phen = 4,7-diphenyl1,10-phenanthroline; dpp = 2,3-bis(2-pyridyl)pyrazine; TL = terminal ligand – a 4,4′-disubstituted-2,2′-bipyridine where the substituent was carbomethoxy (dcmbpy), hydrogen (bpy) or methyl (Me₂bpy)). The …
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New Polyazine-Bridged Ru(II),Rh(III) and Ru(II),Rh(I) Supramolecular Photocatalysts for Water Reduction to Hydrogen Applicable for Solar Energy Conversion and Mechanistic Investigation of the Photocatalytic Cycle
… analysis of complexes prepared using deuterated ligands was used to characterize these three RuII,RhIII supramolecular complexes. Electrochemical studies suggested that replacing bpy with a tridentate ligand on RhIII shifts the RhIII/II and RhII/I reduction couples positively, which can modulate …
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PNA-Ligand Bioconjugates as Potential Building Blocks for Sequence-Specific, Metal-Mediated DNA-/RNA-Cleavage
… complex. Complexes of several chelating nitrogen ligands are proved to catalyze the phosphodiester cleavage of oligonucleotides. In the course of this Thesis, functionalized nitrogen ligands (terpyridine, bis-picolylamine and phenanthroline) were synthesized, and their metal binding behaviour in …
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Improving Photocatalytic Hydrogen Production of Ru,Rh,Ru Supramolecular Complexes in Aerobic Aqueous Solutions
… architecture [{(TL)2Ru(BL)}2RhX2]5+ (BL=bridging ligand, TL=terminal ligand, X=halide) are among the highest reported in deoxygenated organic solvents, but do not function in air-saturated aqueous solution due to quenching of the metal-to-ligand charge transfer (MLCT) excited-state under these …
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The synthesis and characterization of a new kind of tagged Ru-Pt bimetallic DNA binding agent
… as TAG-LA-BL-BAS (TAG = NMR active phosphine ligand, LA = light absorber, BL = bridging ligand and BAS = bioactive site). The TAG provides a NMR probe for the characterization of supramolecular complexes as well as for the future investigation of the metal complex−DNA interaction process. In …
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Polyazine-Bridged Ru(II),Pt(II) Trimetallic and Tetrametallic Supramolecular Complexes Exhibiting Unusual Excited State Dynamics Important in Catalysis and PDT Drug Development
… excited state dynamics of multi-metallic, multi-ligand complexes. Electrochemical analysis of the [{(TL)2Ru(dpp)}2Ru(BL")PtCl2]6+ complexes suggests a HOMO localized on the terminal Ru centers (E1/2 (RuII/III) = 1.56-1.63 V vs. Ag/AgCl) and a LUMO localized on the remote BL" coordinated to the …
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COMPOSTI AD AZIONE ANTI-AGGREGANTE ESERCITANO UN EFFETTO BENEFICO SU MODELLI CELLULARI DI ATROFIA MUSCOLARE SPINALE BULBARE
… for the poly-glutamine tract (polyGln), in the N-terminal region of the Androgen Receptor (AR) gene. This mutation leads the protein to form intranuclear aggregates in the spinal cord and brainstem and cause the death of those specific cell populations. AR belongs to the nuclear hormone receptors …
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Tuning the Photophysical and Biological Properties of a Series of Ruthenium-Based Chromophores and Chromophore Coupled Cisplatin Analogs with Substituted Terpyridine Ligands
… [(TL)RuCl(BL)PtCl₂](PF₆) with the BL (bridging ligand) = 2,3-bis(2-pyridyl)pyrazine (dpp) and varying TL (terminal ligand) (tpy = 2,2'':6'',2''-terpyridine, MePhtpy = 4''-(4-methylphenyl)- 2,2'':6'',2''- terpyridine, or tBu3tpy = 4,4'',4''-tri-tert-butyl-2,2'':6'',2''-terpyridine) have been …