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Showing 1 to 2 of 2 for “"synergic base"”.
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Advances in alkali-metal-mediated manganation and comparisons with magnesiation
… on the reaction of the new Na/Mn alkyl-amido base [(TMEDA)Na(TMP)(CH₂SiMe₃)Mn(TMP)] (16) with a series of organic substrates. Firstly we investigated the reaction of the polymeric dialkyl manganese(II) compound [Mn(CH₂SiMe₃)₂]∞ (1) with a range of Lewis base donors, amines and ketones. The new …
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Group 11 'Ate Bases: Towards an Understanding of Solid- and Solution-State Structures
… are an important class of bimetallic base, which can chemo- and regioselectively metalate aromatic compounds, via directed ortho cupration (DoCu). This thesis begins with an introduction to aspects of the chemistry of organolithium compounds, group 11 organometallic compounds and their …