Global ETD Search
Search theses and dissertations gathered from participating repositories worldwide. Every result links back to the library that holds it. No account is needed.
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Showing 1 to 8 of 8 for “"supramolecular system"”.
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Multivalent Supramolecular Systems
… tool in the design of synthetic molecular systems. The result of multiple binding events is not just a simple sum of individual contributions due to cooperative interactions between binding sites. The main part of this thesis deals with the study of chelate cooperativity in multivalent …
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Electrochemical CO2 reduction on Cucurbit[n]uril modified Gold
… to form a hybrid organic-inorganic model system capable of influencing the local chemical environment of gold as a heterogeneous CO2 reduction electrocatalyst. This supramolecular system was carefully investigated with an interdisciplinary approach to uncover the complex dynamics at the …
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Cucurbiturils, tetrahedral capsules, and porous systems: synthesis, functionalization, and applications
… principles developed by the founding fathers of supramolecular chemistry, the PhD program consists of four lines of research that develop in a multidisciplinary plan starting from alternative and more environmentally friendly synthesis methodologies. During the first year a new synthetic strategy …
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The synthesis and characterization of a new kind of tagged Ru-Pt bimetallic DNA binding agent
… this project was to design a new kind of tagged supramolecular structural motif. These systems are modular in design and able to bind to DNA. The motif can be represented as TAG-LA-BL-BAS (TAG = NMR active phosphine ligand, LA = light absorber, BL = bridging ligand and BAS = bioactive site). The …
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Charakterisierung des Ladungstransfers von immobilisiertem Cytochrom c
… because it is a relatively well characterized system. Cyt c was immobilized to goldelectrodes via a self assembled monolayer (SAM) ofa carboxylic terminated thiol. In order to contact a single molecule twoapproaches from molecular electronics were pursued. In a vertical adjustmentCyt c was …
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Synthesis and Electrochemical Properties of {[(bpy)₂Ru(dpp)]₂RhCl₂}(PF₆)₅: A Light Absorber - Electron Collector - Light Absorber Triad AND Development and Evaluation of Integrated Molecular Modeling, Synthesis, and Characterization Laboratory Experiments for the Undergraduate Chemistry Curriculum
… first research goal was to develop and study a supramolecular system coupling two light absorber units to a central metal site capable of collecting two electrons; this has been accomplished. The complex {[(bpy)2Ru(dpp)]2RhCl2}(PF6)5 was synthesized and characterized using electrochemistry and …
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Synthesis, Self-Assembly and Photophysical Properties of Multichromophoric Systems
Supramolecular chemistry offers a great toolbox of non-covalent interactions to organize chromophoric and multichromophoric systems into functional aggregates of precise size and order via a bottom-up approach. These interactions can be utilized to improve the photophysical properties and processes …
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Computational and Statistical Approaches to Study Complex Molecular Systems and Their Emergent Properties
L'abstract è presente nell'allegato / the abstract is in the attachment